journal article·2017-12Open access

Magnetic properties and Mössbauer spectroscopy of Cu-Mn substituted BaFe12O19 hexaferrites

A. Baykal, H. Güngüneş, H. Sözeri, Md. Amir, I. Auwal, S. Asiri, S.E. Shirsath, A. Demir Korkmaz

Ceramics International· Volume 43· Issue 17

Abstract

Abstract In this study, bimetallic (Cu-Mn) substituted M-type Ba 1-2x Mn x Cu x Fe 12 O 19 (0.0 ≤ x ≤ 0.1) hexaferrites were fabricated via sol-gel auto-combustion route. The effect of bimetallic substitution on structure, morphology and magnetism of BaFe 12 O 19 was studied. Scanning Electron Microscopy confirm images reveal the nanosize of the prepared products with flake morphology. X-ray powder diffraction analysis confirmed their complete conversion to BaFe 12 O 19 hexagonal crystal phase. The results from the magnetic investigations conducted by Vibrating Sample Magnetometer (VSM) and 57 Fe Mossbauer suggested that the saturation magnetization ( M s ) and the coercive field of Ba 1-2x Mn x Cu x Fe 12 O 19 hexaferrites decrease as the concentration of Cu and Mn increases. The cation distribution calculation showed that the occupancy of Fe 3+ ions is increased at 12k and 2b sites with the increase in Cu and Mn substitution.
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Research context

OpenAlex topics: Magnetic Properties and Synthesis of Ferrites · Electromagnetic wave absorption materials · Multiferroics and related materials

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