journal article·2014-09

Kinetic study on lithium-aluminosilicate (LAS) glass-ceramics containing MgO and ZnO

Lola Lilensten, Qiang Fu, Bryan R. Wheaton, Allen J. Credle, Ronald L. Stewart, Jeffrey T. Kohli

Ceramics International· Volume 40· Issue 8
Publisher page

Abstract

Abstract Magnesium oxide and zinc oxide are widely used to reduce batch cost and increase the working range for the production of commercial Li 2 O–Al 2 O 3 –SiO 2 (lithium aluminosilicate), LAS, glass-ceramics. However, little work is done on the crystallization kinetics of the glass-ceramic containing MgO and ZnO. In this work, an investigation was conducted to study the crystallization kinetics using non-isothermal and isothermal methods by differential scanning calorimetry (DSC) and high temperature X-ray diffraction (HTXRD), respectively. Both non-isothermal and isothermal methods confirm a bulk crystallization mechanism in the glass-ceramic. Activation energy values of 373 and 442 kJ/mol were determined using a modified Kissinger model and the Johnson–Mehl–Avrami–Kohnogorov (JMAK) model, respectively.
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Research context

OpenAlex topics: Glass properties and applications · Thermal and Kinetic Analysis · Clay minerals and soil interactions

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