Synthesis of MnO, Mn2O3 and Mn3O4 nanocrystal clusters by thermal decomposition of manganese glycerolate
Source abstract
Abstract
Abstract We successfully prepared MnO, Mn 2 O 3 and Mn 3 O 4 nanoparticles by thermal decomposition of manganese (II) glycerolate in air or inert atmosphere at various temperatures. The thermal behavior during decomposition was analyzed by simultaneous thermal analysis. The manganese precursor was analyzed by X-Ray diffraction, SEM, SEM-EDS and X-Ray photoelectron spectroscopy to evaluate exact composition. The particle size of the obtained nanoparticles was determined from XRD patterns using Scherrer equation and also by transmission electron microscopy. Thanks to the extremely low sizes, such nanoparticles can be used at large-scales for industrial use.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Catalytic Processes in Materials Science · Supercapacitor Materials and Fabrication · Transition Metal Oxide Nanomaterials
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (27)
Show source-provided references
1. Size-dependent magnetic properties of colloidal Mn3O4 and MnO nanoparticles10.1002/anie.200352400 ↗
2. Reverse microemulsion synthesis of nanostructured complex oxides for catalytic combustion10.1038/47450 ↗
3. A general strategy for nanocrystal synthesis10.1038/nature03968 ↗
4. Preparation and optical properties of highly crystalline, colloidal, and size-controlled indium oxide nanoparticles10.1002/adma.200304568 ↗
5. Facile synthesis of multipodal MnO nanocrystals and their catalytic performance10.1002/ejic.201400070 ↗
6. Synthesis of highly crystalline and monodisperse maghemite nanocrystallites without a size-selection process10.1021/ja016812s ↗
7. O-atom transport catalysis by neutral manganese oxide clusters in the gas phase: Reactions with CO, C2H4, NO2, and O210.1063/1.4819059 ↗
8. Aerobic oxidation of sulfides to sulfoxides catalyzed by gold/manganese oxides10.1246/bcsj.20130075 ↗
9. Liquid-phase aerobic oxidation of benzyl alcohol catalyzed by mechanochemically synthesized manganese oxide10.1007/s11434-013-5833-z ↗
10. New manganese catalyzed regiocontrolled synthesis of poly(2,5-dialkyl-1,4-phenylene oxide)s10.1002/app.29084 ↗
11. Pseudocapacitive behavior of manganese oxide in lithium-ion-doped butylmethylpyrrolidinium–dicyanamide ionic liquid investigated using in situ X-ray absorption spectroscopy10.1016/j.jpowsour.2013.07.088 ↗
12. Enhanced activity of chemically synthesized hybrid graphene oxide/Mn3O4 composite for high performance supercapacitors10.1016/j.electacta.2012.12.120 ↗
13. A novel chemical synthesis and characterization of Mn3O4 thin films for supercapacitor application10.1016/j.apsusc.2009.12.057 ↗
14. Preparation and Alkali-metal ion extraction/insertion reactions with nanofibrous manganese oxide having 2×4 tunnel structure10.1021/cm030344z ↗
15. Nanorods of manganese oxalate: a single source precursor to different manganese oxide nanoparticles (MnO, Mn2O3, Mn3O4)10.1039/b409010a ↗
16. MnO and NiO nanoparticles: synthesis and magnetic properties10.1039/B511920K ↗
17. Antiferromagnetic MnO nanoparticles with ferrimagnetic Mn3O4 shells: Doubly inverted core-shell system10.1103/PhysRevB.77.024403 ↗
18. Synthesis of CeO2 or α–Mn2O3 nanoparticles via sol–gel process and their optical properties10.1007/s10971-010-2356-9 ↗
19. The size-controlled synthesis of uniform Mn2O3 octahedra assembled from nanoparticles and their catalytic properties10.1088/0957-4484/22/1/015603 ↗
20. Crystalline cobalt, zinc, manganese, and iron alkoxides of glycerol10.1071/CH9701963 ↗
21. CoO and Co3O4 nanoparticles with a tunable particle size10.1016/j.ceramint.2014.04.082 ↗
22. Cationic substitution sites in Mn2+-doped ZnS nanoparticles10.1007/s11051-005-7525-3 ↗
23. Mittal · 2012
24. Towards graphene bromide: bromination of graphite oxide10.1039/C4NR01154F ↗
25. Phase transitions in MnO and FeO at low temperatures: A neutron powder diffraction study10.1016/j.jallcom.2005.04.155 ↗
26. Crystal structure refinement and reflectance measurements of hausmannite, Mn3O410.1007/BF01163155 ↗
27. Liquid-mix disorder in crystalline solids: ScMnO310.1006/jssc.1998.7918 ↗