journal article·2011-09

High-temperature behavior of silicon oxycarbide glasses in air environment

Tianheng Xu, Qingsong Ma, Zhaohui Chen

Ceramics International· Volume 37· Issue 7
Publisher page

Abstract

Abstract Silicon oxycarbide glasses (SiOC) have been produced by siloxane resin under flowing argon at 1000 °C and then their evolutions in air from 800 to 1700 °C were investigated. Those glasses annealed at various temperatures were characterized by X-ray diffraction, 29 Si MAS NMR, Raman spectroscopy, and chemical element analysis. It can be found that oxidation reactions of the SiOC glasses occurred at above 1000 °C; carbothermal reduction was indiscernible at temperature below 1600 °C but almost finished at 1700 °C; and the decomposition of SiO x C 4− x network was complete at 1400 °C.
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Research context

OpenAlex topics: Advanced ceramic materials synthesis · Diamond and Carbon-based Materials Research · Glass properties and applications

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References (21)

Show source-provided references
1. Microstructural and mechanical characterization of sol gel-derived Si-O-C galsses10.1016/S0955-2219(01)00537-4 ↗
2. Synthesis and characterization of carbon-enriched silicon oxycarbides10.1016/j.jeurceramsoc.2004.07.019 ↗
3. Silicon oxycarbide glasses for blood-contact applications10.1016/j.actbio.2005.05.005 ↗
4. Silicon oxycarbide glasses10.1023/A:1008765829012 ↗
5. A review of the development of three generations of small diameter silicon carbide fibres10.1007/s10853-006-6566-z ↗
6. Overview of ARPA low-cost ceramic composites (LC3) program
7. High temperature stability of sol-gel-derived SiOC galsses10.1023/A:1008775830830 ↗
8. Oxidation resistant ceramic foam from a silicone preceramic polymer/polyurethane blend10.1016/S0955-2219(01)00220-5 ↗
9. Oxidation of nicalon SiC fibres10.1007/BF00609170 ↗
10. Silicon oxycarbide coatings on graphite fibers: chemistry, processing, and oxidation resistance10.1016/0921-5093(94)06522-5 ↗
11. Oxidation behavior of polymer derived SiCO powders10.1016/j.ceramint.2008.05.006 ↗
12. Raman spectrum of graphite10.1063/1.1674108 ↗
13. Raman spectroscopic characterization of some commercially available carbon black materials10.1016/0008-6223(95)00117-V ↗
14. Raman study of the chemical and thermal degradation of as-received and sol–gel embedded Nicalon and Hi-Nicalon SiC fibers used in ceramic matrix composites10.1002/(SICI)1097-4555(199704)28:4<219::AID-JRS88>3.0.CO;2-F ↗
15. Interpretation of Raman spectra of disordered and amorphous carbon10.1103/PhysRevB.61.14095 ↗
16. Raman spectroscopy of amorphous, nanostructured, diamond-like carbon and nanodiamond10.1098/rsta.2004.1452 ↗
17. Raman spectroscopy studies of the high-temperature evolution of the free carbon phase in polycarbosilane derived SiC ceramics10.1016/j.ceramint.2010.08.003 ↗
18. Systematic structural characterization of the high-temperature behavior of nearly stoichiometric silicon oxycarbide glasses10.1021/cm049847a ↗
19. Chemical characterization of Si-Al-C-O precursor and its pyrolysis10.1111/j.1151-2916.1991.tb07172.x ↗
20. Effect of reduced pressure on oxidation and thermal stability of polycarbosilane-derived SiC frbers10.1023/B:JMSC.0000004421.67094.2e ↗
21. Oxidation behaviour of ceramic fibres from the Si-C-N-O system and related sub-systems10.1016/S0955-2219(00)00101-1 ↗