journal article·2019-06

Microstructure, mechanical properties and toughening mechanisms of graphene reinforced Al2O3-WC-TiC composite ceramic tool material

Xuchao Wang, Jun Zhao, Enzhao Cui, Shiping Song, Hao Liu, Weitian Song

Ceramics International· Volume 45· Issue 8
Publisher page

Abstract

Abstract The low fracture toughness of Al2O3-based ceramics limited their practical application in cutting tools. In this work, graphene was chosen to reinforce Al2O3-WC-TiC composite ceramic tool materials by hot pressing. Microstructure, mechanical properties and toughening mechanisms of the composite ceramic tool materials were investigated. The results indicated that the more refined and denser composite microstructures were obtained with the introduction of graphene. The optimal flexural strength, Vickers hardness, indentation fracture toughness were 646.31 ± 20.78 MPa, 24.64 ± 0.42 GPa, 9.42 ± 0.40 MPa m1/2, respectively, at 0.5 vol% of graphene content, which were significantly improved compared to ceramic tool material without graphene. The main toughening mechanisms originated from weak interfaces induced by graphene, and rugged fractured surface, grain refinement, graphene pull-out, crack deflection, crack bridging, micro-crack and surface peeling were responsible for the increase of fracture toughness values.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Advanced materials and composites · Advanced ceramic materials synthesis · Orthopaedic implants and arthroplasty

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (47)

Show source-provided references
1. Development of Al2O3-SiC composite tool for machining application10.1016/j.ceramint.2003.11.011 ↗
2. Mechanical properties and toughening mechanisms of graphene platelets reinforced Al2O3/TiC composite ceramic tool materials by microwave sintering10.1016/j.msea.2016.10.100 ↗
3. Wear performance of alumina-based ceramics - a review of the influence of microstructure on erosive wear10.1590/0366-69132015613571871 ↗
4. The effects of graphene reinforcement on the mechanical properties of Al2O3 ceramics rapidly sintered by high-frequency induction heating10.1016/j.ijrmhm.2014.10.011 ↗
5. Cutting performance and failure mechanisms of an Al2O3/WC/TiC micro- nano-composite ceramic tool10.1016/j.ijrmhm.2009.11.007 ↗
6. Study of the mechanical properties, strengthening and toughening mechanisms of Al2O3/TiC micro-nano-composite ceramic tool material10.1016/j.msea.2013.04.033 ↗
7. Microstructural nature of strengthening and toughening in Al2O3-SiC(p) nanocomposites10.1023/A:1004729015686 ↗
8. Microstructure design and preparation of Al2O3/TiC/TiN micro-nano-composite ceramic tool materials based on properties prediction with finite element method10.1016/j.ceramint.2017.12.109 ↗
9. Spark plasma sintering of fine-grained alumina ceramics reinforced with alumina whiskers10.1016/j.ceramint.2016.09.210 ↗
10. Fracture-toughness anisotropy and toughening mechanisms of a hot-pressed alumina reinforced with silicon-carbide whiskers10.1111/j.1151-2916.1993.tb05304.x ↗
11. Single-wall carbon nanotubes as attractive toughening agents in alumina-based nanocomposites10.1038/nmat793 ↗
12. Graphene as an electrochemical transfer layer10.1016/j.carbon.2018.09.056 ↗
13. Tensile strength of graphene nanoribbons: an experimental approach10.1016/j.matlet.2019.01.051 ↗
14. A roadmap for graphene10.1038/nature11458 ↗
15. The rise of graphene10.1038/nmat1849 ↗
16. Theory of thermal conductivity of graphene-polymer nanocomposites with interfacial Kapitza resistance and graphene-graphene contact resistance10.1016/j.carbon.2018.05.033 ↗
17. Toughening in graphene ceramic composites10.1021/nn200319d ↗
18. Mechanical properties of graphene platelet-reinforced alumina ceramic composites10.1016/j.ceramint.2013.01.041 ↗
19. Microstructure and fracture toughness of graphene nanosheets/alumina composites10.1016/j.ceramint.2014.05.107 ↗
20. Friction and wear behavior of microwave sintered Al2O3/TiC/GPLs ceramic sliding against bearing steel and their cutting performance in dry turning of hardened steel10.1016/j.ceramint.2017.07.231 ↗
21. Reinforcement of Al2O3/TiC ceramic tool material by multi-layer graphene10.1016/j.ceramint.2017.05.353 ↗
22. Microstructure and toughening mechanisms of Al2O3/(W, Ti)C/graphene composite ceramic tool material10.1016/j.ceramint.2018.04.185 ↗
23. Multilayer graphene reinforced functionally graded tungsten carbide nano-composites10.1016/j.matdes.2017.08.041 ↗
24. Mechanical properties of Al2O3-TiC-TiN ceramic tool materials10.1016/j.ceramint.2014.03.056 ↗
25. Microstructures and mechanical properties of B4C-TiB2-SiC composites fabricated by ball milling and hot pressing10.1016/j.jeurceramsoc.2018.02.020 ↗
26. Indentation fracture of WC-Co cermets10.1007/BF00555296 ↗
27. Fracture toughness and toughening mechanisms in graphene platelet reinforced Si3N4 composites10.1016/j.scriptamat.2012.02.009 ↗
28. Properties of 3Y-TZP zirconia ceramics with graphene addition obtained by spark plasma sintering10.1016/j.ceramint.2018.06.133 ↗
29. Characterization of hot-pressed graphene reinforced ZrB2-SiC composite10.1016/j.msea.2014.12.028 ↗
30. Spark plasma sintering of graphene reinforced silicon carbide ceramics10.1016/j.ceramint.2017.04.042 ↗
31. The effect of microstructure evolution on mechanical properties in novel alumina-montmorillonite composites10.1016/j.ijrmhm.2019.01.018 ↗
32. Enhancement of mechanical and electrical properties/cement composite due to improved dispersion of graphene by addition of silica fume10.1016/j.conbuildmat.2017.12.176 ↗
33. Graphene reinforced alumina nano-composites10.1016/j.carbon.2013.07.086 ↗
34. Enhanced fracture toughness of pressureless-sintered SiC ceramics by addition of graphene10.1016/j.jmst.2016.01.009 ↗
35. Efficient and large-scale synthesis of few-layered graphene using an arc-discharge method and conductivity studies of the resulting films10.1007/s12274-010-0027-3 ↗
36. Enhanced toughness of zirconia ceramics with graphene platelets consolidated by spark plasma sintering10.1111/ijac.12742 ↗
37. Toughening of silicon nitride ceramics by addition of multilayer graphene10.1016/j.ceramint.2018.11.176 ↗
38. Perspectives on carbon nanotubes and graphene Raman spectroscopy10.1021/nl904286r ↗
39. Simultaneous strengthening and toughening of reduced graphene oxide/alumina composites fabricated by molecular-level mixing process10.1016/j.carbon.2014.06.074 ↗
40. Fabrication and characterization of synergistic Al-SiC-GNPs hybrid composites10.1016/j.compositesb.2018.07.035 ↗
41. The reinforcing effect of graphene nano-platelets on the cryogenic mechanical properties of GNPs/Al2O3 composites10.1016/j.jallcom.2016.08.314 ↗
42. Microstructures and properties of silicon carbide- and graphene nanoplatelet-reinforced titanium diboride composites10.1016/j.jallcom.2017.09.244 ↗
43. Grain size dependence of fracture toughness for fine grained alumina10.1016/j.scriptamat.2011.03.032 ↗
44. Perspective on the development of high-toughness ceramics10.1111/j.1151-2916.1990.tb06493.x ↗
45. Microstructure and fracture toughness of Si3N4 + graphene platelet composites10.1016/j.jeurceramsoc.2012.04.022 ↗
46. Anisotropic elastic moduli and internal friction of graphene nanoplatelets/silicon nitride composites10.1016/j.compscitech.2012.12.003 ↗
47. Field assisted sintering of graphene reinforced zirconia ceramics10.1016/j.ceramint.2014.12.147 ↗