journal article·2012-01

Enhancement of Qm in CuO-doped compositionally optimized Li/Ta-modified (Na,K)NbO3 lead-free piezoceramics

Zong-Yang Shen, Ying Xu, Jing-Feng Li

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Abstract

Abstract The effects of CuO on electrical properties of compositionally optimized Li/Ta-modified (Na,K)NbO3 (LT-KNN) piezoceramics were studied to develop LT-KNN with high mechanical quality factor Qm and low dielectric loss tg δ as well as relatively high piezoelectric constant d33 for actuator applications. Both “hard” and “soft” effects were observed due to CuO addition, and the discussion related to high Li doping amount was presented to explain this phenomenon. By increasing CuO addition, the d33 gradually decreases while the Qm increases significantly. Particularly, tg δ at 1 kHz can be reduced from ∼2.7% for LT-KNN ceramics to ∼0.8% for CuO-added LT-KNN ceramics. When the CuO addition is lower than 1 mol%, both high Qm (∼323) and relatively high d33 (>180 pC/N) can be obtained, in addition to a relatively high dielectric constant ɛr ∼ 500.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Ferroelectric and Piezoelectric Materials · Acoustic Wave Resonator Technologies · Dielectric materials and actuators

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (14)

Show source-provided references
1. Lead-free piezoceramics10.1038/nature03028 ↗
2. Perspective on the development of lead-free piezoceramics10.1111/j.1551-2916.2009.03061.x ↗
3. Combined effects of Li content and sintering temperature on polymorphic phase boundary and electrical properties of Li/Ta co-doped (Na,K)NbO3 lead-free piezoceramics10.1007/s00339-009-5358-0 ↗
4. Effects of K content on the dielectric, piezoelectric, and ferroelectric properties of 0.95(KxNa1−x)NbO3–0.05LiSbO3 lead-free ceramics10.1063/1.2830997 ↗
5. Piezoelectric and dielectric properties of (LiNaK)(NbTaSb)O3 ceramics with variation in poling temperature10.1143/JJAP.45.7444 ↗
6. Synthesis and characterization of (K0.5Na0.5)(Nb0.7Ta0.3)O3 piezoelectric ceramics sintered with sintering aid K5.4Cu1.3Ta10O2910.1143/JJAP.44.6618 ↗
7. Microstructure and piezoelectric properties of the CuO-added (K0.5Na0.5)(Nb0.97Sb0.03)O3 lead-free piezoelectric ceramics10.1063/1.2965197 ↗
8. Effect of CuO and MnO2 on sintering temperature, microstructure, and piezoelectric properties of 0.95(K0.5Na0.5)NbO3–0.05BaTiO3 ceramics10.1016/j.matlet.2008.03.062 ↗
9. Effect of CuO on the sintering temperature and piezoelectric properties of (Na0.5K0.5)NbO3 lead-free piezoelectric ceramics10.1111/j.1551-2916.2008.02408.x ↗
10. Processing and piezoelectric properties of (Na0.5K0.5)0.96Li0.04(Ta0.1Nb0.9)1−xCuxO3−3x/2 lead-free ceramics10.1111/j.1551-2916.2007.02206.x ↗
11. Enhancement of Qm by co-doping of Li and Cu to potassium sodium niobate lead-free ceramics10.1109/TUFFC.2008.743 ↗
12. Jaffe · 1971
13. Influence of CuO on the structure and piezoelectric properties of the alkaline niobate-based lead-free ceramics10.1111/j.1551-2916.2006.01465.x ↗
14. Dielectric and piezoelectric properties of Cu2+-doped alkali niobates10.1016/j.jeurceramsoc.2009.01.003 ↗