journal article·2019-08

Effect of electrolyte on the supercapacitive behaviour of copper oxide/reduced graphene oxide nanocomposite

Sadhna Rai, Rabina Bhujel, Joydeep Biswas, Bibhu P. Swain

Ceramics International· Volume 45· Issue 11
Publisher page

Abstract

Abstract Cupric oxide/reduced graphene oxide (CuO/rGO) nanocomposites were synthesized through a chemical reduction method using hydrazine hydrate as the reducing agent. The morphology, elemental composition, and bonding network of the CuO/rGOnanocomposites were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, X-ray photoelectron spectroscopy (XPS) and Raman spectroscopy respectively. The XRD results reveal lattice spacing and lattice strain from 3.371 to 3.428 A and 1.05 × 10−3to 5.44 × 10−3 respectively, with the increasing ratio of rGO: CuO from 1:1 to 1:5. The cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS)and galvanostatic charge-discharge (GCD) studyofCuO/rGOas the electrode material showed excellent super-capacitive behavior in H2SO4 over Na2SO4 electrolytes. Moreover CuO/rGO nanocomposites exhibited better capacitance retention in H2SO4(75.69%) compared to Na2SO4(12.06%).
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Supercapacitor Materials and Fabrication · Advancements in Battery Materials · Graphene research and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (48)

Show source-provided references
1. Executive overview: energy storage options for a sustainable energy future
2. Supercapacitor energy storage technology and its application in renewable energy power generation system
3. Porous mesocarbon microbeads with graphitic shells: constructing a high-rate, high-capacity cathode for hybrid supercapacitor10.1038/srep02477 ↗
4. Functionalized graphene-based nanocomposites for supercapacitor application10.1021/jp201673e ↗
5. High-performance flexible supercapacitors based on electrochemically tailored three-dimensional reduced graphene oxide networks10.1038/s41598-017-18593-3 ↗
6. Progress of electrochemical capacitor electrode materials: a review10.1016/j.ijhydene.2009.04.005 ↗
7. Fabrication of copper oxide multilayer nanosheets for supercapacitor application10.1016/j.jallcom.2009.11.149 ↗
8. Electrochemical, bonding network and electrical properties of reduced graphene oxide-Fe2O3 nanocomposite for supercapacitor electrodes applications10.1016/j.jallcom.2019.04.004 ↗
9. A symmetric RuO2/RuO2supercapacitor operating at 1.6 V by using a neutral aqueous electrolyte10.1149/2.023204esl ↗
10. Manganese oxide-based materials as electrochemical supercapacitor electrodes10.1039/C0CS00127A ↗
11. Investigation of cyclic voltammetry and impedance spectroscopy of thermally exfoliated biomass synthesized nickel decorated graphene10.1016/j.jpcs.2019.02.023 ↗
12. A one-step facile route synthesis of copper oxide/reduced graphene oxide nanocomposite for supercapacitor applications10.1080/17458080.2018.1542512 ↗
13. Nanostructured CuO/reduced grapheneoxidecomposite for hybrid supercapacitors10.1039/c4ra02107j ↗
14. Metal-free supercapacitor with aqueous electrolyte and low-cost carbon materials10.1038/srep39836 ↗
15. Enhancing capacitance of supercapacitor with bothorganic electrolyte and ionic liquid electrolyte ona biomass-derived carbon10.1039/C7RA01630A ↗
16. A review of electrolyte materials and compositions for electrochemical supercapacitors10.1039/C5CS00303B ↗
17. Facile synthesis of flowerlike LiFe5O8 microspheres for electrochemical supercapacitors10.1021/acs.inorgchem.7b02257 ↗
18. Green synthesis and electrochemical characterizationofrGO–CuOnanocomposites for supercapacitor applications10.1007/s11581-016-1923-7 ↗
19. A facile route to the synthesis of copper oxide/reduced graphene oxide nanocomposites and electrochemical detection of catechol organic pollutant10.1039/c2ce25509j ↗
20. Synthesis and electrochemical properties of coral-like LiFePO4 particles as supercapacitor electrodes10.1149/2.1481714jes ↗
21. Asymmetric supercapacitors based on HybridCuO@Reduced graphene Oxide@Sponge versus ReducedGrapheneOxide@Sponge electrodes10.1002/ente.201402170 ↗
22. Hierarchical LiFe5O8@PPy core-shell nanocomposites as electrode materials for supercapacitors10.1016/j.apsusc.2018.11.204 ↗
23. A binder-free hybrid of CuO-microspheres and rGONanosheets as an alternative material for next generation energy storage application
24. Preparation of graphitic oxide10.1021/ja01539a017 ↗
25. Preparation and characteristics of graphene oxide from the biomass carbon material using fir powder asPrecursor10.1080/1536383X.2015.1046595 ↗
26. Reduced graphene oxide with superior cycling stability and rate capability for sodium storage10.1016/j.carbon.2013.01.064 ↗
27. Non-enzymatic glucose biosensor based on copper oxide-reduced graphene oxide nanocomposites synthesized from water-isopropanolsolution10.1016/j.electacta.2014.03.030 ↗
28. The Scherrer formula for X-ray particle size determination10.1103/PhysRev.56.978 ↗
29. Williamson-Hall analysis in estimation of lattice strain in nanometer-sized ZnO particles10.1186/2251-7235-6-6 ↗
30. The diffraction of short electromagnetic waves by a crystal
31. Synthesis of copper oxide/reduced graphene oxide nanocomposite and its enhanced catalytic activity towards reduction of 4-nitrophenol10.1039/C5RA10551J ↗
32. An application of thermal analysis to household waste10.1520/JAI100523 ↗
33. Synthesis, characterization and tribologicalproperties of Cu/reduced graphene oxide composites10.1016/j.triboint.2015.02.028 ↗
34. Synthesis and characterizations of graphene–copper nanocomposites and their antifriction application10.1016/j.jiec.2013.09.029 ↗
35. Raman spectroscopy of graphene and graphite: disorder, electron–phononcoupling, doping, and nonadiabatic effects10.1016/j.ssc.2007.03.052 ↗
36. Improvement in structural and electrical properties of cuprous oxide-coated multiwalled carbon nanotubes10.1007/s12034-014-0092-4 ↗
37. Investigation of cyclic voltammetry, impedance spectroscopy and electrical properties of thermally exfoliated biomass-synthesized graphene
38. Empirical atomic sensitivity factors for quantitative analysis by electron spectroscopy for chemical analysis10.1002/sia.740030506 ↗
39. Facile synthesis of Cu2O/CuO/RGO nanocomposite and its superior cyclability in the supercapacitor10.1016/j.electacta.2014.11.171 ↗
40. Cu2O/Reduced graphene oxide composites for the photocatalytic conversion of CO210.1002/cssc.201301194 ↗
41. Construction of carbon-based two-dimensionalcrystalline nanostructure by chemical vapour deposition of benzene on Cu(111)10.1039/C4NR00017J ↗
42. Characterizing well-ordered CuOnanofibrils synthesized through gas-solid reactions10.1063/1.1690114 ↗
43. Fabrication of CuO-decorated reduced grapheneoxidenanosheets for supercapacitor applications10.1016/j.ceramint.2016.08.136 ↗
44. High voltage asymmetric supercapacitor based on MnO2 and graphene electrodes10.1016/j.jelechem.2012.10.024 ↗
45. Amorphous nickel hydroxide nanospheres with ultrahigh capacitance and energy density as electrochemical pseudocapacitor materials
46. A review of metal oxide composite electrode materials for electrochemical capacitors10.1142/S1793292014300023 ↗
47. Synthesis of Ni3V2O8@graphene oxide nanocomposite as an efficient electrode material for supercapacitor applications10.1007/s10008-017-3788-8 ↗
48. Effects of functional groups of graphene oxide on the electrochemical performance of lithium-ion batteries10.1039/C5RA17854A ↗