journal article·2016-05

Microstructure and electrical properties of Nb and Mn co-doped CaBi 4 Ti 4 O 15 high temperature piezoceramics obtained by two-step sintering

Zong-Yang Shen, Wen-Qin Luo, Yanxue Tang, Shujun Zhang, Yueming Li

Ceramics International· Volume 42· Issue 6
Publisher page

Abstract

Abstract Bismuth layer structural ceramics with a composition of CaBi4Ti3.95Nb0.05O15+0.2 wt% MnO2 (CBTN–Mn) were prepared by a two-step sintering (TSS) approach. The effect of sintering process on the microstructure and its relationship with the electrical properties of the CBTN–Mn ceramics was investigated. A dense microstructure with small and homogeneous grains was obtained under an optimized two-step sintering condition, leading to a strongly enhanced piezoelectric constant (d33=27 pC/N). In addition, this ceramic also possesses high Curie temperature (Tc=790 °C), low dielectric loss (tan δ=0.2%) and high dc resistivity (ρ=5.5×106 Ω cm at 500 °C), indicating its potential for high temperature piezoelectric sensing applications.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Ferroelectric and Piezoelectric Materials · Acoustic Wave Resonator Technologies · Microwave Dielectric Ceramics Synthesis

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (22)

Show source-provided references
1. Piezoelectric materials for high temperature sensors10.1111/j.1551-2916.2011.04792.x ↗
2. A lead-free high-curie-point ferroelectric ceramic, CaBi2Nb2O910.1002/adma.200401860 ↗
3. Aurivillius-type ceramics, a class of high temperature piezoelectric materials: drawbacks, advantages and trends10.1016/j.progsolidstchem.2009.06.001 ↗
4. Crystal chemistry of mixed bismuth oxides with layer-type structure10.1111/j.1151-2916.1962.tb11113.x ↗
5. A family of ferroelectric bismuth compounds10.1016/0022-3697(62)90526-7 ↗
6. Structural basis of ferroelectricity in the bismuth titanate family10.1016/0025-5408(71)90082-1 ↗
7. A method for finding the curie temperature and measuring the temperature dependence of the dielectric susceptibility of ferroelectrics and antiferroelectrics with high electrical conductivity
8. A-site (MCe) substitution effects on the structures and properties of CaBi4Ti4O15 ceramics10.1143/JJAP.39.6339 ↗
9. The effect of (Li,Ce) and (K,Ce) doping in Aurivillius phase material CaBi4Ti4O1510.1016/j.materresbull.2004.04.020 ↗
10. Enhanced piezoelectric properties of Nb and Mn Co-doped CaBi4Ti4O15 high temperature piezoceramics10.1016/j.materresbull.2014.11.055 ↗
11. Sintering dense nanocrystalline ceramics without final-stage grain growth10.1038/35004548 ↗
12. Sintering behavior, dielectric and piezoelectric properties of sodium potassium niobate-based ceramics prepared by single step and two-step sintering10.1016/j.ceramint.2014.08.054 ↗
13. Publication and Proposed Revision of ANSI/IEEE Standard 176-1987 “ANSI/IEEE Standard on Piezoelectricity”, Ultrasonics, Ferroelectrics and Frequency Control, IEEE Transactions on 43 (1996) 717.10.1109/TUFFC.1996.535477 ↗
14. Electrical properties of CaBi4Ti4O15–Bi4Ti3O12 piezoelectric ceramics10.1016/j.ceramint.2015.04.044 ↗
15. High temperature properties of manganese modified CaBi4Ti4O15 ferroelectric ceramics10.1016/j.ssc.2006.08.007 ↗
16. Electrical anisotropy in the hot-forged CaBi4Ti4O15 ceramics10.1016/j.solidstatesciences.2009.02.025 ↗
17. Lanthanum distribution and dielectric properties of Bi3−xLaxTiNbO9 bismuth layer-structured ceramics10.1016/j.scriptamat.2006.07.014 ↗
18. Textured Ca0.85(Li,Ce)0.15Bi4Ti4O15 ceramics for high temperature piezoelectric applications10.1016/j.materresbull.2012.05.009 ↗
19. Effects of A-site (NaCe) substitution with Na-deficiency on structures and properties of CaBi4Ti4O15-based high-curie-temperature ceramics10.1143/JJAP.40.6501 ↗
20. Electromechanical properties of A-site (LiCe)-modified sodium bismuth titanate (Na0.5Bi4.5Ti4O15) piezoelectric ceramics at elevated temperature10.1063/1.3117219 ↗
21. Microstructure, electrical conductivity, and piezoelectric properties of bismuth titanate10.1111/j.1151-2916.1996.tb08086.x ↗
22. B-site donor and acceptor doped Aurivillius phase Bi3NbTiO9 ceramics10.1016/j.jeurceramsoc.2005.07.056 ↗