journal article·2015-09

Green preparation of reduced graphene oxide using a natural reducing agent

Soon Weng Chong, Chin Wei Lai, Sharifah Bee Abdul Hamid

Ceramics International· Volume 41· Issue 8
Publisher page

Abstract

Abstract A simple and efficient method was introduced for the high-conversion preparation of graphene oxide (GO) from large graphite flakes (average flake size=100 μm) using a simplified Hummer׳s method. Natural reducing agents such as lemon juice and vinegar were compared with hydrazine (N 2 H 4 ) as potential reducing agents. Graphene was prepared by chemical reduction of GO because this method was low cost and could be used for large-scale graphene production. This one-pot graphene preparation was performed at room temperature. Different degrees of oxidation of graphite flakes were obtained by stirring graphite in a mixture of sulfuric acid and potassium permanganate at different oxidation times, and highly exfoliated GO sheets were produced. GO was subsequently reduced effectively by lemon juice, a new, green, and potential reducing agent with pH 2.3. This reduced GO exhibited a high electrical conductance of 24.6 μS attributed to its higher C/O ratio (≈8:2) compared with other samples.
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Research context

OpenAlex topics: Graphene research and applications · Graphene and Nanomaterials Applications · Supercapacitor Materials and Fabrication

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (29)

Show source-provided references
1. Kok Foo Kwan, 20–24 June 2010. 〈http://www.apcc21.org/eng/index.jsp〉.
2. Transparent carbon films as electrodes in organic solar cells10.1002/ange.200704909 ↗
3. Improved properties of dye-sensitized solar cells by incorporation of graphene into the photoelectrodes10.1016/j.electacta.2012.01.038 ↗
4. Graphene-compositing optimization of the properties of dye-sensitized solar cells10.1016/j.solener.2013.12.005 ↗
5. Chemical vapor deposition synthesis and Raman spectroscopic characterization of large-area graphene sheets10.1021/jp311757r ↗
6. Review of CVD synthesis of graphene10.1002/cvde.201300051 ↗
7. Graphene synthesis by chemical vapor deposition and transfer by a roll-to-roll process10.1016/j.carbon.2010.05.001 ↗
8. N. Krane, Preparation of Graphene, 2011.
9. Scotch-tape-like exfoliation of graphite assisted with elemental sulfur and graphene–sulfur composites for high-performance lithium–sulfur batteries10.1039/c3ee24324a ↗
10. Transfer-free electrical insulation of epitaxial graphene from its metal substrate10.1021/nl301614j ↗
11. Growing high-quality graphene from incredible solid materials
12. Preparation of colloidal dispersions of graphene sheets in organic solvents by using ball milling10.1155/2010/528235 ↗
13. Chemical methods for the production of graphenes10.1038/nnano.2009.58 ↗
14. CVD synthesis of mono-and few-layer graphene using alcohols at low hydrogen concentration and atmospheric pressure10.1016/j.cplett.2013.08.031 ↗
15. Electric field effect in atomically thin carbon films10.1126/science.1102896 ↗
16. Electronic confinement and coherence in patterned epitaxial graphene10.1126/science.1125925 ↗
17. Preparation of graphitic oxide10.1021/ja01539a017 ↗
18. An improved Hummers method for eco-friendly synthesis of graphene oxide10.1016/j.carbon.2013.07.055 ↗
19. Green reduction of graphene oxide by aqueous phytoextracts10.1016/j.carbon.2012.07.023 ↗
20. The chemistry of graphene oxide10.1039/B917103G ↗
21. Tromel · Angew. Chem. · 1987 · 99 · 103710.1002/ange.19870991009 ↗
22. E.W. Schmidt, Hydrazine and its Derivatives, 2001.
23. Hydrazine and thermal reduction of graphene oxide: reaction mechanisms, product structures, and reaction design10.1021/jp909284g ↗
24. Introduction to Raman scattering
25. Raman spectroscopy of graphene and carbon nanotubes10.1080/00018732.2011.582251 ↗
26. Raman spectrum of graphene and graphene layers10.1103/PhysRevLett.97.187401 ↗
27. I. Childres, L.A. Jauregui, W. Park, H. Cao, Y.P. Chen, Raman spectroscopy of graphene and related materials, Developments in Photon and Materials Research, 978–981.
28. Double resonant Raman scattering in graphite10.1103/PhysRevLett.85.5214 ↗
29. 〈http://www.graphenea.com/pages/graphene-properties#.VCw2u_mSykE〉.