journal article·2014-08

Energy transfer and photoluminescence properties of Dy3+/Tb3+ co-doped oxyfluorosilicate glass–ceramics for solid-state white lighting

D. Ramachari, L. Rama Moorthy, C.K. Jayasankar

Ceramics International· Volume 40· Issue 7
Publisher page

Abstract

Singly doped Dy3+, Tb3+ and co-doped Dy3+/Tb3+ ions in oxyfluorosilicate glass–ceramics were prepared by conventional melt quenching technique to study their luminescence properties for the development of white light emitting diodes. The X-ray diffraction measurements confirmed the amorphous and KNbO3 crystalline nature of precursor glass and glass–ceramics, respectively. The effect of increasing the concentration of Tb3+ ions on the green emission from the 5D4 excited level has been investigated. The decay profiles of 4F9/2 excited level of Dy3+ ion were fitted to double exponential function and Inokuti-Hirayama (IH) model to determine the energy transfer rates from Dy3+ to Tb3+ ions. All the chromaticity (x, y) color co-ordinates determined from the emission spectra were found to be within the white light region of the CIE chromaticity color diagram.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Glass properties and applications · Luminescence Properties of Advanced Materials · Solid State Laser Technologies

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (32)

Show source-provided references
1. Enhanced cooperative quantum cutting in Tm3+, Yb3+ co-doped glass ceramics containing LaF3 nanocrystals10.1364/OE.16.008989 ↗
2. The shape of the 1.55μm emission band of the Er3+ -dopant in oxyfluoride nano-scaled glass–ceramics10.1209/epl/i2004-10314-3 ↗
3. Microstructure and luminescence of transparent glass ceramic containing Er3+:BaF2 nano-crystals10.1016/j.jssc.2005.11.010 ↗
4. Rare earth ions doped full-color luminescence glasses for white LED10.1016/j.jlumin.2006.10.028 ↗
5. Blue–White–Green tunable luminescence of Ce3+, Tb3+ Co-doped sodium silicate glasses for white LEDs10.1111/j.1551-2916.2011.04929.x ↗
6. Down-shifting by energy transfer in Dy3+–Tb3+ co-doped YF3-based sol–gel nano-glass–ceramics for photovoltaic applications10.1016/j.optmat.2010.10.040 ↗
7. White light generation from Dy 3+ -doped ZnO–B2O3–P2O5 glasses10.1063/1.3159899 ↗
8. Optical properties of Dy3+ ion in GGG laser crystal10.1088/0022-3727/43/7/075402 ↗
9. Enhancement of Tb3+ emission by non-radiative energy transfer from Dy3+ in silicate glass10.1016/j.physb.2008.10.039 ↗
10. Luminescence and energy transfer properties of Ca8Gd2(PO4)6O2:A (A=Ce3+/Eu2+/Tb3+/Dy3+/Mn2+) phosphors10.1039/c2jm34092e ↗
11. Efficient electroluminescence from rare earth doped MOS diodes10.1016/S0921-5107(00)00668-1 ↗
12. Radiative transfer of energy between rare-earth ions in glass10.1063/1.1753953 ↗
13. Intense visible fluorescence and energy transfer in Dy3+, Tb3+, Sm3+ and Eu3+ doped rare-earth borate glasses10.1016/j.jallcom.2004.07.068 ↗
14. Spectral investigations of Sm3+-doped oxyfluorosilicate glasses10.1016/j.materresbull.2013.05.081 ↗
15. Cullity · 1977
16. Phonon sideband spectrum and vibrational analysis of Eu3+-doped niobium oxyfluorosilicate glass10.1016/j.jlumin.2013.05.025 ↗
17. Spectral analysis of RE3+ (RE=Er, Nd, Pr and Ho): GeO2–B2O3–ZnO–LiF glasses10.1088/0953-8984/20/37/375104 ↗
18. Optical properties of Dy3+ -doped phosphate and fluorophosphates glasses10.1016/j.optmat.2008.06.019 ↗
19. Fabrication, patterning, and optical properties of nanocrystalline YVO4: A (A=Eu3+, Dy3+, Sm3+, Er3+) phosphor films via sol–gel soft lithography10.1021/cm011663y ↗
20. Increase in the Tb3+ green emission in SiO2–LaF3 nano-glass–ceramics by codoping with Dy3+ ions10.1063/1.3514552 ↗
21. Optical properties of Dy3+ doped yttrium-aluminium borate10.1088/0953-8984/16/3/022 ↗
22. Tuning of multicolor emissions in glass ceramics containing γ-Ga2O3 and β-YF3 nanocrystals10.1039/c2tc00658h ↗
23. Influence of energy transfer by the exchange mechanism on donor luminescence10.1063/1.1697063 ↗
24. Efficient Nd3+–Yb3+ energy transfer processes in high phonon energy phosphate glasses for 1.0µm Yb3+ laser10.1063/1.3580475 ↗
25. Lavin · 2006
26. A photometric investigation of ultra- efficient LEDs with high color rendering index and high luminous efficacy employing nanocrystal quantum dot luminophores10.1364/OE.18.000340 ↗
27. Correlated color temperature as an explicit function of chromaticity coordinates10.1002/col.5080170211 ↗
28. White light generation in Dy3+-doped oxyfluoride glass and transparent glass–ceramics containing CaF2 nanocrystals10.1364/OE.19.001836 ↗
29. Green–white–yellow tunable luminescence from Dy3+–Tb3+–Eu3+ doped transparent glass ceramics containing GdSr2F7 nanocrystals10.1007/s00339-013-7898-6 ↗
30. Eu-, Tb-, Dy-doped oxyfluoride silicate glasses for LED applications
31. Schubert · 2006
32. Polyspectral white light emission from Eu3+, Tb3+, Dy3+, Tm3+ codoped GdAl3(BO3)4 phosphors obtained by combustion synthesis10.1016/j.mseb.2008.11.024 ↗