journal article·2016-09

Solvothermal synthesis of BiPO4 nanorods/MWCNT (1D-1D) composite for photocatalyst and supercapacitor applications

S. Vadivel, A.N. Naveen, J. Theerthagiri, J. Madhavan, T. Santhoshini Priya, N. Balasubramanian

Ceramics International· Volume 42· Issue 12
Publisher page

Abstract

Abstract A novel BiPO4/MWCNT (1D-1D) composite was synthesized by a simple one step solvothermal approach. The crystallanity, morphology, and photophysical properties of the samples were characterized by XRD, Raman, SEM, TEM, XPS, UV–vis spectroscopic techniques. The nanostructured BiPO4/MWCNT composite showed large surface area and the incorporation of MWCNT caused a red-shift of BiPO4 in (ultraviolet) UV region. A maximum specific capacitance of 504 F g−1 at a scan rate of 5 mV s−1 was obtained for BiPO4/MWCNT composite. BiPO4/MWCNT composite shows good capacity retention (94%) upon cycling over 1000 cycles. The BiPO4/MWCNT composite exhibits better photocatalytic activity than pure BiPO4 under UV light irradiation in view of degrading methyl orange (MO) as target pollutant. The degradation of MO could get 95% in BiPO4/MWCNT photocatalysts under optimum reaction conditions. The improved photoactivity of BiPO4/MWCNT could be attributed to effective separation of photoinduced hole-electron pairs between host BiPO4 and MWCNT. This study offers a new fabrication strategy to prepare BiPO4 based materials that can be used in energy storage devices and environmental applications.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Supercapacitor Materials and Fabrication · Advanced Photocatalysis Techniques · Conducting polymers and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (51)

Show source-provided references
1. Solvothermal synthesis of SnO2/graphene nanocomposites for supercapacitor application10.1016/j.ceramint.2013.01.102 ↗
2. Facile large scale synthesis of Bi2S3 nanorods–graphene composite for photocatalytic photoelectrochemical and supercapacitor application10.1016/j.apsusc.2015.04.101 ↗
3. Metal oxide thin film based supercapacitors10.1016/j.cap.2010.12.001 ↗
4. Recent advancements in electrode materials for the high performance electrochemical supercapacitors: a review10.1016/S1452-3981(23)08076-8 ↗
5. Hexamethylenetetramine assisted hydrothermal synthesis of BiPO4 and its electrochemical properties for supercapacitors10.1016/j.jpcs.2015.06.007 ↗
6. Synthesis and luminescence properties of BiPO4:Ce, Tb nanorods10.1016/j.jlumin.2014.01.002 ↗
7. Effect of pH on the sonochemical synthesis of BiPO4 nanostructures and its electrochemical properties for pseudocapacitors10.1016/j.ultsonch.2014.06.014 ↗
8. TiO2 Photocatalyst for water treatment applications10.1016/j.jiec.2013.07.012 ↗
9. Application of advanced oxidation processes for TNT removal: a review10.1016/j.jhazmat.2010.02.042 ↗
10. The mechanism of azo-dyes adsorption on the titanium dioxide surface and their photocatalytic degradation over samples with various anatase/rutile ratios10.1016/j.cattod.2014.09.010 ↗
11. Photocatalytic and photoelectrochemical properties of in situ carbon hybridized BiPO4 films10.1016/j.apcata.2012.05.043 ↗
12. Novel low temperature synthesis and electrochemical characterization of mesoporous nickel cobaltite-reduced graphene oxide (RGO) composite for supercapacitor application10.1016/j.electacta.2015.05.072 ↗
13. Preparation, characterization of CdS-deposited graphene-carbon nanotubes hybrid photocatalysts with enhanced photocatalytic activity10.1016/j.matlet.2013.06.102 ↗
14. Carbon nanomaterials for high performance supercapacitors10.1016/j.mattod.2013.07.002 ↗
15. Substrate dependent photocatalytic performance of TiO2/MWCNT photocatalysts10.1016/j.apcata.2013.10.001 ↗
16. The simultaneous photocatalytic degradation of phenol and reduction of Cr (vi) by TiO2/CNTs10.1016/j.jiec.2011.11.060 ↗
17. Functionalization of tungsten oxide into MWCNT and its application for sunlight-induced degradation of Rhodamine B10.1016/j.jcis.2011.06.081 ↗
18. Investigation on physiochemical properties of Mn substituted spinel cobalt oxide for supercapacitor applications10.1016/j.electacta.2014.01.161 ↗
19. Carbon Nanotubes/TiO2 nanotubes composite photocatalysts for efficient degradation of methyl orange dye10.1016/j.partic.2012.07.008 ↗
20. One-Step preparation of CNTs/InVO4 hollow nanofibers by electro spinning and its photocatalytic performance under visible light10.1016/j.apsusc.2015.06.143 ↗
21. Microwave synthesis of BiPO4 nanostructures and their morphology-dependent photocatalytic performances10.1016/j.jcis.2011.07.090 ↗
22. The influence of operating parameters on heterogeneous photocatalytic mineralization of phenol over BiPO410.1016/j.cej.2014.02.028 ↗
23. Visible light photocatalytic degradation of thiophene using Ag-TiO2/multi-walled carbon nanotubes nanocomposite10.1016/j.ceramint.2013.11.132 ↗
24. Multiwalled carbon nanotube/TiO2 nanocomposite as a highly active photocatalyst for photodegradation of Reactive Black 5 Dye10.1016/S1872-2067(14)60210-2 ↗
25. Controlled synthesis, characterization and photocatalytic activity of BiPO4 nanostructures with different morphologies10.1088/2053-1591/1/2/025023 ↗
26. Fluorine mediated photocatalytic activity of BiPO410.1016/j.apcatb.2013.09.050 ↗
27. Characterization and photocatalytic performance of SnO2-CNT nanocomposites10.1016/j.apsusc.2015.09.044 ↗
28. In situ synthesis of CNTs/Fe–Ni/TiO2 nanocomposite by fluidized bed chemical vapor deposition and the synergistic effect in photocatalysis10.1016/j.partic.2013.04.002 ↗
29. Photocatalytic degradation of carbamazepine by tailored BiPO4: efficiency, intermediates and pathway10.1016/j.apcatb.2012.11.013 ↗
30. Nanocomposite of BiPO4 and reduced graphene oxide as an efficient photocatalyst for hydrogen evolution10.1016/j.ijhydene.2014.02.031 ↗
31. Biomimetic CNT@TiO2 composite with enhanced photocatalytic properties10.1016/j.cej.2015.06.067 ↗
32. Enhanced visible light photocatalytic activity and mechanism of BiPO4 nanorods modified with AgI nanoparticles10.1016/j.molcata.2014.11.005 ↗
33. Photocatalytic degradation of benzene in gas phase by nanostructured BiPO4 catalysts10.1016/j.pnsc.2012.11.007 ↗
34. Large scale preparing carbon nanotube/Zinc oxide hybrid and its application for highly reusable photocatalyst10.1016/j.cej.2012.03.008 ↗
35. Comparison of catalytic activities for photocatalytic and sonocatalytic degradation of methylene blue in present of anatase TiO2–CNT catalysts10.1016/j.ultsonch.2010.11.008 ↗
36. BiPO4/reduced graphene oxide composites photocatalyst with high photocatalytic activity10.1016/j.apsusc.2014.07.052 ↗
37. Novel high potential visible-light-active photocatalyst of CNT/Mo, S-codoped TiO2 hetero-nanostructure10.1016/j.apsusc.2014.08.123 ↗
38. Photocatalytic, sonocatalytic and sonophotocatalytic degradation of Rhodamine B using ZnO/CNTs composites photocatalysts10.1016/j.ultsonch.2013.08.014 ↗
39. visible-light-driven photocatalytic inactivation of E. coli by Ag/AgX-CNTs (X=Cl, Br, I) plasmonic photocatalysts: bacterial performance and deactivation mechanism Appl10.1016/j.apcatb.2014.04.033 ↗
40. Supercapacitor studies on NiO nanoflakes synthesized through a microwave route10.1021/am400012h ↗
41. Ag incorporated Mn3O4/AC nanocomposite based supercapacitor devices with high energy density and power density10.1039/C4DT02287D ↗
42. Nanostructured nickel doped Β-V2O5 thin films for supercapacitor applications10.1016/j.materresbull.2013.03.007 ↗
43. Design and synthesis of 3D hierarchical NiCO2S4@MnO2 core-shell nanosheet arrays for high-performance pseudocapacitors10.1039/C5RA05554G ↗
44. SWCNT/BiVO4 composites as anode materials for supercapacitor application10.1039/C4RA01273A ↗
45. A 1-D/2-D hybrid nanostructured manganese cobaltite–graphene nanocomposite for electrochemical energy storage10.1039/C5RA09288D ↗
46. porous NiO/C nanocomposites as electrode material for electrochemical supercapacitors10.1021/sc400152r ↗
47. Mechanism analysis of the capacitance contributions and ultra long cycling-stability of the isomorphous MnO2@MnO2 core/shell nanostructures for supercapacitors10.1039/C4TA06793B ↗
48. One pot synthesis of nickel foam supported self assembly of NiWO4 and CoWO4 nanostructures that act as high performance electrochemical capacitor electrodes10.1039/C5TA01598G ↗
49. CoMoO4·0.9H2O nanorods grown on reduced graphene oxide as advanced electrochemical pseudocapacitor materials
50. MnO2 nanoflower arrays with high rate capability for flexible supercapacitors10.1002/celc.201400006 ↗
51. Cyclic voltammetry study of Bi2O3 powder by means of a cavity microelectrode coupled with Raman microspectrometry10.1016/S0013-4686(00)00677-0 ↗