journal article·2011-08Open access

Citric acid as anti-hydration additive for magnesia containing refractory castables

R. Salomão, V.C. Pandolfelli

Ceramics International· Volume 37· Issue 6

Abstract

Abstract Magnesia hydration is a key concern in refractory castable processing. The volumetric expansion that follows this reaction can result in cracks or even explosion during the first heating-up. Citric acid (CA) and other chelants can significantly reduce MgO hydration rate in aqueous suspensions by forming an insoluble magnesium citrate protective coating on the magnesia particles’ surface. In the present work, the performance of CA as an anti-hydration additive in refractory castables was evaluated by hydration tests, mechanical strength and apparent volumetric expansion (AVE) measurements and thermogravimetry. The results attained have shown that CA effectiveness depends strongly on the amount added and by the interaction with other raw materials in the composition, in particular calcium aluminate cement.
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Research context

OpenAlex topics: Layered Double Hydroxides Synthesis and Applications · Magnesium Oxide Properties and Applications · Advanced ceramic materials synthesis

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (21)

Show source-provided references
1. Hydration characteristics of magnesia
2. A, Yoshida, Magnesia raw materials with improved hydration resistance
3. Mechanisms of hydration /carbonation of basic refractories–Part I
4. A novel approach for magnesia hydration assessment in refractory castables10.1016/j.ceramint.2006.01.004 ↗
5. Dissolution and hydration kinetics of MgO10.1016/0376-4583(85)90080-9 ↗
6. The role of reactivity in syntheses and the properties of magnesium oxide10.1016/S0167-2738(97)00364-0 ↗
7. Ceramic hydration with expansion: the structure and reaction of water layers on magnesium oxide. A cyclic cluster study
8. The effect of magnesite calcination conditions on magnesia hydration10.1016/S0892-6875(00)00146-1 ↗
9. Temperature and common-ion effect on magnesium oxide (MgO) hydration10.1016/j.ceramint.2009.12.009 ↗
10. Effects of alumina cement grade and additives on alumina-magnesia castable containing aluminum lactate
11. Volume stabilization of high MgO cement: effect of curing conditions and fly ash addition10.1016/S0008-8846(98)00140-9 ↗
12. Effect of additives on the hydration resistance of materials synthesized from magnesia-calcia system10.1111/j.1151-2916.2000.tb01469.x ↗
13. A. Yoschida, T. Nemoto and A. Kaneyasu, Evaluation method for hydration resistance of magnesia fine powder and effect of B2O3 content in magnesia raw materials, Proceedings of UNITECR’ 2003 (2003) 21-30.10.5465/ambpp.2003.13792242 ↗
14. The protection of MgO film against hydration by using Al2O3 capping layer deposited by magnetron sputtering method10.1016/S0040-6090(03)00362-6 ↗
15. Microssilica addition as anti-hydration technique for magnesia in refractory castables
16. Magnesia sinter hydration-dehydration behavior in refractory castables10.1016/j.ceramint.2007.06.009 ↗
17. The role of hydraulic binders on magnesia containing refractory castables: Calcium aluminate cement and hydratable alumina10.1016/j.ceramint.2009.04.023 ↗
18. Chelants to inhibit magnesia (MgO) hydration10.1016/j.ceramint.2011.01.030 ↗
19. Effect of curing time on the properties of CAC bonded refractory castables10.1016/S0955-2219(03)00371-6 ↗
20. A review of the mechanism of set-retardation in Portland cement pastes containing organic admixtures10.1016/0008-8846(72)90057-9 ↗
21. The retardation action of sugars on cement hydration10.1016/0008-8846(83)90084-4 ↗