journal article·2017-01

Microwave-assisted synthesis of Ce-doped ZnO/CNT composite with enhanced photo-catalytic activity

Md. Elias, Md. Khairul Amin, Shakhawat H. Firoz, Md. Asjad Hossain, Sonia Akter, Md. Awlad Hossain, Md. Nizam Uddin, Iqbal Ahmed Siddiquey

Ceramics International· Volume 43· Issue 1
Publisher page

Abstract

Abstract This manuscript reports a successful additive free and fast energy-efficient microwave-assisted synthesis of nanocrystalline Ce-doped ZnO/CNT composite without calcinations. The structure and morphology of nanocrystalline Ce-doped ZnO/CNT was investigated by X-ray Diffraction (XRD), Field Emission Scanning Electron Microscope (FESEM), Fourier Transform Infrared Spectroscopy (FT-IR), UV–visible and Photoluminescence (PL) spectroscopy. The XRD results indicate that all of the samples are free of any impurity phase and crystallize only in the hexagonal structure. The synthesized Ce-doped ZnO/CNT composite achieved 96.4% photo-catalytic efficiency for methylene blue (MB) dye degradation under UV irradiation whereas the efficiency was only 34.6% for pure ZnO nanoparticles. Ce doping and insertion of CNTs into ZnO matrix enhanced the photo-catalytic activity of the composite by reducing the charge recombination. The experimental photodegradation data were well fitted to first-order, parabolic diffusion and modified Freundlich models. The results suggest that Ce-doped ZnO/CNT composite prepared by microwave irradiation method has a potential application in photo-catalysis which leads to the removal of harmful organic pollutant from the environment.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Advanced Photocatalysis Techniques · ZnO doping and properties · TiO2 Photocatalysis and Solar Cells

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (53)

Show source-provided references
1. Photocatalytic and antibacterial activity of B/N/Ag co-doped CNT-TiO2 composite films10.1007/s10847-015-0510-2 ↗
2. An experimental and first-principles study of the effect of B/N doping in TiO2 thin films for visible light photo-catalysis10.1016/j.jphotochem.2012.12.024 ↗
3. Effects of operational conditions of microwave-assisted synthesis on morphology and photocatalytic capability of zinc oxide10.1016/j.cej.2010.11.057 ↗
4. Synthesis and characterization of nano sized ZnO powders by direct precipitation method10.1016/j.cej.2008.07.047 ↗
5. Improved photocatalytic performance of Pd-doped ZnO10.1016/j.cap.2012.01.003 ↗
6. Visible light photocatalytic activity of Fe3+ doped ZnO nanoparticle prepared via sol-gel technique10.1016/j.chemosphere.2012.12.055 ↗
7. Application of ultrasonic irradiation method for preparation of ZnO nanostructures doped with Sb+3 ions as a highly efficient photocatalyst10.1016/j.apsusc.2013.03.118 ↗
8. A comparative study of reduced graphene oxide modified TiO2, ZnO and Ta2O5 in visible light photocatalytic/photochemical oxidation of methylene blue10.1016/j.apcatb.2013.03.027 ↗
9. Enhanced photocatalytic degradation of methylene blue by ZnO–reduced graphene oxide–carbon nanotube composites synthesized via microwave-assisted reaction10.1039/c2cy20023f ↗
10. Preparation of highly efficient Al-doped ZnO photocatalyst by combustion synthesis10.1016/j.cap.2012.11.008 ↗
11. Tungsten-doped ZnO nanocomposite: Synthesis, characterization, and highly active photocatalyst toward dye photodegradation10.1016/j.matchemphys.2013.02.044 ↗
12. Synthesis, characterization and enhanced photocatalytic degradation efficiency of Se doped ZnO nanoparticles using trypan blue as a model dye10.1016/j.apcata.2013.04.001 ↗
13. Preparation and photocatalytic activity of Cu-doped ZnO thin films prepared by the sol–gel method10.1016/j.apsusc.2012.05.021 ↗
14. A highly efficient Ag-ZnO photocatalyst: synthesis, properties, and mechanism10.1021/jp802729a ↗
15. Simple and large scale refluxing method for preparation of Ce-doped ZnO nanostructures as highly efficient photocatalyst10.1016/j.apsusc.2012.11.053 ↗
16. Highly efficient photocatalyst based on Ce doped ZnO nanorods: controllable synthesis and enhanced photocatalytic activity10.1016/j.cej.2013.06.004 ↗
17. Fabrication of NiCo2O4@CeO2 core@shell nanotubes with enhanced catalytic performances10.1039/C6CE01243D ↗
18. TiO2@h-CeO2: a composite yolk–shell microsphere with enhanced photodegradation activity10.1039/C6CY00466K ↗
19. Electrospinning of CeO2-ZnO composite nanofibers and their photocatalytic property10.1016/j.matlet.2011.01.075 ↗
20. Enhanced photoelectrochemical activity of Ce doped ZnO nanocomposite thin films under visible light10.1016/j.jelechem.2011.07.022 ↗
21. Enhancing blue luminescence from Ce-doped ZnO nanophosphor by Li doping10.1186/1556-276X-9-480 ↗
22. Synthesis of Ce co-doped Ag–ZnO photocatalyst with excellent performance for NBB dye degradation under natural sunlight illumination10.1039/c2cy20254a ↗
23. Zhao · 2009
24. Non-enzymatic Glucose Biosensor Based on Cu / SWNTs Composite Film Fabricated by One-step Electrodeposition
25. Multi-walled carbon nanotube-supported metal-doped ZnO nanoparticles and their photocatalytic property10.1007/s11051-012-1295-5 ↗
26. Electron storage in single wall carbon semiconductor – SWCNT suspensions10.1021/nn700036f ↗
27. A rapid, one pot microwave assisted synthesis of nanosize cuprous oxide10.1016/j.powtec.2012.11.006 ↗
28. Control of the photocatalytic activity of TiO2 nanoparticles by silica coating with polydiethoxysiloxane10.1016/j.dyepig.2007.01.020 ↗
29. A rapid method for the preparation of silica-coated ZrO2 nanoparticles by microwave irradiation10.1016/j.ceramint.2011.01.003 ↗
30. Tailoring the photocatalytic reaction rate of a nanostructured TiO 2 matrix using additional gas phase oxygen10.1186/2228-5326-3-16 ↗
31. Photodegradation of psychiatric pharmaceuticals in aquatic environments - kinetics and photodegradation products10.1016/j.watres.2011.09.008 ↗
32. Design of hybrid materials based on carbon nanotubes and polyoxometalates10.1016/j.optmat.2006.03.020 ↗
33. Solar photocatalytic degradation of 2,6-dinitro-p-cresol (DNPC) using multi-walled carbon nanotubes (MWCNTs)–TiO2 composite photocatalysts10.1016/j.chemosphere.2009.01.014 ↗
34. Sensors and Actuators B: chemical Ce-doped ZnO nanorods for the detection of hazardous chemical10.1016/j.snb.2012.06.001 ↗
35. Structural, functional and optical studies on Ce doped ZnO nanoparticles
36. Photoluminescence emission at room temperature in zinc oxide10.1016/j.materresbull.2013.09.049 ↗
37. Controllable synthesis of hierarchical ZnO nanodisks for highly photocatalytic activity10.1039/c1ce06013a ↗
38. TiO2-MWCNT rice grain-shaped nanocomposites-synthesis, characterization and photocatalysis10.1016/j.materresbull.2010.12.025 ↗
39. Uniform carbon-coated ZnO nanorods: microwave-assisted preparation, cytotoxicity, and photocatalytic activity10.1021/la803530h ↗
40. Effect of CeO2 doping on the structure, electrical conductivity and ethanol gas sensing properties of nanocrystalline ZnO sensors
41. Functional finishing of cotton fabrics using zinc oxide-soluble starch nanocomposites10.1088/0957-4484/17/20/008 ↗
42. Synthesis, characterization, PL properties, photocatalytic and antibacterial activities of nano multi-metal oxide NiO.CeO2.ZnO10.1016/j.saa.2014.09.100 ↗
43. Synthesis, structure and excitation wavelength dependent PL properties of novel nanocomposite La2O2CO3.CuO.ZnO10.1016/j.saa.2014.05.015 ↗
44. Synthesis, structure, PL and photocatalytic activities of La2O2CO3.CeO2. ZnO fabricated by co-precipitation method10.1016/j.saa.2014.10.114 ↗
45. One-step microwave synthesis of Ag/ZnO nanocomposites with enhanced photocatalytic performance10.1007/s10853-012-6676-8 ↗
46. Functionalization of tungsten oxide into MWCNT and its application for sunlight-induced degradation of rhodamine B10.1016/j.jcis.2011.06.081 ↗
47. Strong luminescence of solubilized carbon nanotubes10.1021/ja9942282 ↗
48. Enhanced photocatalytic degradation of methylene blue by ZnO-reduced graphene oxide composite synthesized via microwave-assisted reaction10.1016/j.jallcom.2011.08.045 ↗
49. Photocatalytic activity of nanocomposites of ZnO and multi-walled carbon nanotubes for dye degradation10.1080/01932690802498310 ↗
50. Facile synthesis of g-C3N4/ZnO composite with enhanced visible light photooxidation and photoreduction properties10.1016/j.cej.2012.08.033 ↗
51. Exploration of CeO2 nanoparticles as a chemi-sensor and photo-catalyst for environmental applications10.1016/j.scitotenv.2011.04.019 ↗
52. Ni, Co and Ni–Co codoping induced modification in shape, optical band gap and enhanced photocatalytic activity of CeO2 nanostructures for photodegradation of methylene blue dye under visible light irradiation10.1039/C5RA14184B ↗
53. Role of ZnO-CeO2 nanostructures as a photo-catalyst and chemi-sensor10.1016/S1005-0302(11)60113-8 ↗