journal article·2014-08

H2S gas sensing properties of CuO-functionalized WO3 nanowires

Suyoung Park, Sunghoon Park, Jihwan Jung, Taeseop Hong, Sangmin Lee, Hyoun Woo Kim, Chongmu Lee

Ceramics International· Volume 40· Issue 7
Publisher page

Abstract

Abstract This paper compares the H 2 S gas sensing properties of CuO-functionalized WO 3 nanowires with those of CuO-functionalized SnO 2 nanorods to see the relative contributions of the nanowire material (WO 3 or SnO 2 ) and functionalization material (CuO) to H 2 S gas sensing properties. Multiple networked CuO-functionalized WO 3 nanowire sensors showed electrical responses to H 2 S gas at 300 °C comparable to their CuO-functionalized SnO 2 nanorod counterparts. The CuO-functionalized WO 3 nanowires and CuO-functionalized SnO 2 nanorods exhibited responses of ~673% and ~798%, respectively, to 100 ppm H 2 S at 300 °C. The ratio of the response of CuO-functionalized WO 3 nanowires to H 2 S gas to that of pristine WO 3 nanowires was 3.65, whereas the ratio of the response of CuO-functionalized SnO 2 nanorods to H 2 S gas to that of pristine SnO 2 nanorods was 3.84. Differences in sensing mechanism between CuO-functionalized WO 3 nanowires and CuO-functionalized SnO 2 nanorods are also discussed.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Gas Sensing Nanomaterials and Sensors · Transition Metal Oxide Nanomaterials · ZnO doping and properties

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (30)

Show source-provided references
1. CuO nanoparticle decorated ZnO nanorod sensor for low-temperature H2S detection10.1016/j.msec.2012.05.042 ↗
2. CuO–SnO2 element for highly sensitive and selective detection of H2S10.1016/0925-4005(92)80216-K ↗
3. Gas sensing properties of nano-crystalline SnO2–CuO compounds10.1007/s12540-010-1012-9 ↗
4. Development of sensors based on CuO-doped SnO2 hollow spheres for ppb level H2S gas sensing10.1007/s10853-009-3645-y ↗
5. CuO-doped SnO2 thin films as hydrogen sulfide gas sensor10.1063/1.1584071 ↗
6. Synthesis and H2S sensing properties of CuO–SnO2 core/shell PNjunction nanorods
7. Ppb H2S gas sensing characteristics of Cu2O/CuO sub-microspheres at low-temperature10.1016/j.snb.2013.02.112 ↗
8. H2S gas sensing mechanism of SnO2 films with ultrathin CuO dotted islands10.1063/1.1490154 ↗
9. High sensitivity and selectivity of an SnO2 sensor to H2S at around 100°C10.1016/0925-4005(94)01535-P ↗
10. CuO–SnO2 element for highly sensitive and selective detection of H2S10.1016/0925-4005(92)80216-K ↗
11. H2S sensing mechanism of SnO2 films with ultrathin CuO dotted islands10.1063/1.1490154 ↗
12. Enhanced H2S sensing characteristics of SnO2 nanowires functionalized with CuO10.1016/j.snb.2009.07.052 ↗
13. Microstructural effect on NO2 sensitivity of WO3 thin film gas sensors Part 1. Thin film devices, sensors and actuators10.1016/S0040-6090(96)08745-7 ↗
14. Growth of monoclinic WO3 nanowire array for highly sensitive NO2 detection10.1039/b816646c ↗
15. Ultrasensitive and highly selective gas sensors using three-dimensional tungsten oxide nanowire networks10.1063/1.2203932 ↗
16. Gas sensing properties of the mixed molybdenum tungsten oxide, W0.9Mo0.1O310.1039/b111118n ↗
17. High-sensitivity hydrocarbon sensors based on tungsten oxide nanowires10.1039/b607012b ↗
18. Study of physical and chemical processes of H2 sensing of Pt-coated WO3 nanowire films10.1021/jp106460w ↗
19. CO and NO2 gas sensitivity of nanocrystalline tin dioxide thin films doped with Pd, Ru and Rh10.1016/S0928-4931(02)00068-1 ↗
20. Chemical sensing and catalysis by one-dimensional metal-oxide nanostructures10.1146/annurev.matsci.34.040203.112141 ↗
21. Selectivity in semiconductor gas sensors10.1016/0250-6874(87)80061-6 ↗
22. CuO–SnO2 element for highly sensitive and selective detection of H2S10.1016/0925-4005(92)80216-K ↗
23. Electronic structure and chemical bonding in Mon− and MOn clusters (M=Mo, W; n=3–5): a photoelectron spectroscopy and ab initio study10.1021/ja046536s ↗
24. Appearance of bulk properties in small tungsten oxide clusters10.1063/1.1807374 ↗
25. Electronic excitations in cupric oxide10.1103/PhysRevB.56.12818 ↗
26. A photoelectrochemical determination of the position of the conduction and valence band edges of p-type CuO10.1063/1.330567 ↗
27. Surface states and barrier height of metal‐semiconductor systems10.1063/1.1702952 ↗
28. Influence of humidity on CO sensing with p-type CuO thick film gas sensors10.1016/j.snb.2010.10.046 ↗
29. Suspended CuO nanowires for ppb level H2S sensing in dry and humid atmosphere10.1016/j.snb.2013.06.044 ↗
30. H2S gas sensing properties of bare and Pd-functionalized CuO nanorods10.1016/j.snb.2011.11.006 ↗