journal article·2019-11

Insights into intragranular precipitation and toughening effect of W in (Ti, W)C solid solution with TiH2 as the inducer

Peng Jia, Lei Chen, Yujin Wang, Zhanguo Liu, Jiahu Ouyang, Xinghong Zhang, Yu Zhou

Ceramics International· Volume 45· Issue 16
Publisher page

Abstract

Abstract (Ti, W)C–W composites have been successfully synthesized by in-situ precipitation of multiscale W-rich particles in (Ti, W)C solid solution incorporated with TiH 2 as inducer. The microstructure of (Ti, W)C–W composites is characterized by X-ray diffraction, scanning electron microscopy and transmission electron microscopy. The variations in lattice parameter of (Ti, W)C solid solution with increasing the sintering temperature are dependent upon the in-situ precipitation process of W-rich phase. The low temperature sintering route is beneficial to the precipitation of W-rich phase due to high concentration gradient in (Ti, W)C solid solution. The intragranular W-rich precipitates in the (Ti, W)C matrix exhibit semi-coherent interface and an orientation relationship of [111] W //[011] (Ti, W)C . The in-situ precipitation of multiscale W-rich particles have a positive influence on the fracture toughness, and the value of (Ti, W)C–W composite obtained at 1700 °C is 4.23 MPa m 1/2 .
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Research context

OpenAlex topics: Advanced materials and composites · Advanced ceramic materials synthesis · MXene and MAX Phase Materials

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