Effect of Li2O on the crystallization behavior of CaO-Al2O3-SiO2-Li2O-Ce2O3 mold slags
Source abstract
Abstract
Abstract The effect of Li2O on the crystallization properties of CaO-Al2O3-SiO2-Li2O-Ce2O3 slags was investigated. With increasing the Li2O content, LiAlO2 and CaCeAlO4 were the main crystalline phases. LiAlO2 formed for the charge compensating of Li+ ions to [AlO45−]-tetrahedrons, and CaCeAlO4 formed as a result of the charge balance of Ce3+ ions, Ca2+ ions, and [AlO69−]-octahedrons. Increasing the content of Li2O to 10%, the crystallization temperature was the highest, and the incubation time was the shortest. The crystallization ability was strong due to the three factors of strengthening the interaction between ions and ion groups, decreasing the polymerization degree, and increasing the melting temperature. Further increasing the content of Li2O, the crystallization performance was obviously suppressed, because the melting temperature and the force between the cations and the anion groups decreased.
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Research context
OpenAlex topics: Metallurgical Processes and Thermodynamics · Iron and Steelmaking Processes · Bauxite Residue and Utilization
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
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