journal article·2021-08

The spheroidization process of micron-scaled α-Al2O3 powder in hydrothermal method

Haiyang Chen, Bin Li, Xue Yang, Guangqi Li, Hongqiang Chen, Junhong Chen, Bo Ren

Ceramics International· Volume 47· Issue 16
Publisher page

Abstract

Abstract Understanding the spheroidization process of micron-scaled α-Al2O3 powder in hydrothermal method is of great importance but still not completely revealed. The results demonstrated that SO42− played a significant role in the formation of spherical powder, while the bubble generated from the reaction of urea didn't work in the spheroidization process. The spheroidization process was summed up as two steps. The first was that SO42− limited the hydrolysis of Al3+ and reacted with Al3+ and OH- to form Al4(OH)10SO4, which nucleated and agglomerated into granular precipitates. The second was Ostwald ripening, which gave the spherical precursors a double-layered structure. When the spherical precursors obtained 120 °C were sintered at 1200 °C, α-Al2O3 were got and the spherical morphology still maintained with a large number of nano-sized pores. We anticipate the spherical α-Al2O3 with nano-sized pores can be applied in adsorption and filtration industries.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Advanced ceramic materials synthesis · Mesoporous Materials and Catalysis · Magnesium Oxide Properties and Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (37)

Show source-provided references
1. gamma-Al2O3 supported Pd@CeO2 core@shell nanospheres: salting-out assisted growth and self-assembly, and their catalytic performance in CO oxidation
2. Facile synthesis of monodisperse α-alumina nanoparticles via an isolation-medium-assisted calcination method10.1007/s00339-014-8368-5 ↗
3. Crystallization, mechanical, and fracture behaviors of spherical alumina-filled polypropylene nanocomposites10.1002/polb.20654 ↗
4. Size-controlled synthesis of monodispersed mesoporous α-Alumina spheres by a template-free forced hydrolysis method10.1039/c1dt10418g ↗
5. Fabrications of spherical alumina particles by controlling process parameters in a transferred arc plasma system10.1016/j.ceramint.2020.05.205 ↗
6. Alumina ceramics with uniform grains prepared from Al2O3 nanospheres10.1016/j.jallcom.2016.07.122 ↗
7. Solid particle erosion of epoxy matrix composites reinforced by Al2O3 spheres10.1016/j.triboint.2019.04.010 ↗
8. Effect of Al2O3 hollow sphere on properties of resin bond diamond disc in sapphire grinding
9. Preparation of highly dispersive solid microspherical α-Al2O3 powder with a hydrophobic surface for stereolithography-based 3D printing technology10.1016/j.ceramint.2019.09.167 ↗
10. Property enhancement of 3D-printed alumina ceramics using vacuum infiltration10.1016/j.jmatprotec.2014.01.019 ↗
11. Effect of the particle size and the debinding process on the density of alumina ceramics fabricated by 3D printing based on stereolithography10.1016/j.ceramint.2016.08.024 ↗
12. Sol-gel infiltration of complex cellular indirect 3D printed alumina10.1016/j.jeurceramsoc.2018.04.023 ↗
13. Influence of high-energy ball milling and additives on the formation of sphere-like α-Al2O3 powder by high-temperature calcination10.1515/znb-2018-0080 ↗
14. Preparation of monodisperse, spherical alumina powders from alkoxides10.1111/j.1151-2916.1991.tb08294.x ↗
15. Size-controlled synthesis of alumina nanoparticles from aluminum alkoxides10.1016/j.materresbull.2005.04.031 ↗
16. Preparation of submicron spherical alumina powders by alcohol brine hydrolysis
17. A simple procedure to prepare spherical α-alumina powders10.1016/j.materresbull.2008.09.018 ↗
18. Role of a surface active agent in the sol-emulsion-gel synthesis of spherical alumina powders10.1023/A:1008745210805 ↗
19. Sol-gel synthesis of silicalite/γ-alumina granules10.1021/ie000562r ↗
20. Synthesis of spherical α-alumina and its effect on the performances of phase change materials based on sodium acetate trihydrate10.1088/2053-1591/ab4b8f ↗
21. Alumina powders from aluminium nitrate-urea and aluminium sulphate-urea reactions -The role of the precursor anion and process conditions on characteristics10.1016/0272-8842(95)00139-5 ↗
22. CTAB-directed synthesis of mesoporous γ-alumina promoted by hydroxy carboxylate: the interplay of tartrate and CTAB10.1016/j.solidstatesciences.2010.12.003 ↗
23. Effect of process factors on properties of high dispersion spherical α-Al2O3 particles prepared by hydrothermal method10.1016/j.ceramint.2019.07.215 ↗
24. Preparation of spherical aluminum hydroxide particles by homogeneous precipitation method and its thermal decomposition behavior
25. Facile size-controlled synthesis of well-dispersed spherical amorphous alumina nanoparticles via homogeneous precipitation10.1016/j.ceramint.2016.02.081 ↗
26. Preparation of ultrafine α-Al2O3 powder by homogenous precipitation
27. Study on the hydrolysis of metal ions XI. The Aluminum ion, Al3+
28. A new model for the synthesis of hollow particles via the bubble templating method10.1021/cg900456t ↗
29. ZnSe semiconductor hollow microspheres10.1002/ange.200250695 ↗
30. Anion-induced metal binding in amorphous aluminium hydroxide10.1016/0166-6622(84)80239-5 ↗
31. Cheminform abstract: Raman and IR spectroscopic investigations on aluminum salt solutions. Part 2. Sulfato-complex formation in aluminum sulfate solutions and hydrated melts
32. Hydrated aluminium sulfate precipitation by enzyme-catalysed urea decomposition10.1016/S0955-2219(99)00202-2 ↗
33. Synthesis of high-surface-area alumina aerogels without the use of alkoxide precursors10.1021/cm048800m ↗
34. Synthesis of boehmite hollow core/shell and hollow microspheres via sodium tartrate-mediated phase transformation and their enhanced adsorption performance in water treatment
35. A novel method for synthesizing well-defined boehmite hollow microspheres10.1016/j.jcis.2017.05.021 ↗
36. Sulfate adsorbed on hydrous alumina, ligands displaced, and changes in surface charge10.2136/sssaj1978.03615995004200010009x ↗
37. Different nanostructures of boehmite fabricated by hydrothermal process: effects of pH and anions10.1039/b900447p ↗