Ti-based composite materials with enhanced thermal and mechanical properties
Source abstract
Abstract
Abstract Ti-based composite materials with remarkable mechanical properties and good thermal stability were obtained and studied with the purpose of employment for producing resistant and versatile components in the automotive industry. The raw materials having the overall Ti80Mn8Al6Sn3Zr2C1 composition were prepared by mechanosynthesis from powders of comprising elements; after thermal processing and by following four different sintering pathways, both in the argon flow, the four samples (S1–S4) reached a specific composition of metallic and ceramic phases. Thermal analysis and calorimetry showed that the composite materials adsorb considerable amounts of argon, these being related to the obtained composition and microstructure. The results of the thermal study were used when choosing the thermal treatment conditions for sintering; in order to select the optimal processing conditions within the four different regimes of sintering for the raw materials and the final sample with the best functional properties, a comprehensive study for determining the composition, structure and morphological features was carried out by means of X-ray diffraction, energy-dispersive X-ray spectroscopy and scanning electron microscopy. Two samples (S1 & S4) of the obtained composite materials have increased porosity due to the presence of titanium aluminium carbides (Ti3AlC & Ti3AlC2) that are known as highly porous ceramics, therefore absorbing more argon during the preparation process. The roughness and wear tests showed that the best results (smallest roughness: Ra = 1.11 μm and smallest wear: w = 2.472·10−4 mm3 N−1 m−1) belong to the S2 sample sintered in argon for 15 min at 1100 °C and further calcinated at 1050 °C for 75 min.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: MXene and MAX Phase Materials · Intermetallics and Advanced Alloy Properties · Advanced materials and composites
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (99)
Show source-provided references
1. Quantifying the properties of low-cost powder metallurgy titanium alloys10.1016/j.msea.2017.01.049 ↗
2. Leyens · 2003
3. Cold compaction and sintering of titanium and its alloys for near-net shape or preform fabrication
4. Properties and applications of titanium alloys: A brief review
5. Study of interfacial adhesion between nickel-titanium shape memory alloy and a polymer matrix by laser surface pattern10.3390/app10062172 ↗
6. Mechanism and technological opportunity of plasma electrolytic polishing of metals and alloys surfaces10.1016/j.apsadv.2020.100016 ↗
7. An introduction to titanium in consumer applications. Titanium for Consumer Applications
8. Ab initio and CALPHAD-type thermodynamic investigation of the Ti–Al–Zr system10.2298/JMMB181022039D ↗
9. Criveanu MC, Rotaru A. Methodologies for obtaining carburized steels by powder metallurgy. In The Book: Advanced Engineering Materials. Recent Depelopments for Medical, Technological and Industrial Applications. (A. Rotaru Ed.), ACADEMICA Greifswald Publishing House, Germany. ISBN 978-3-940237-38-5. .
10. Froes · 2010
11. Titanium for automotive applications: challenges and opportunities in materials and processing10.1007/s11837-012-0310-8 ↗
12. Ramakrishnan · 2013 · 493
13. Titanium in automotive production10.1002/adem.200310094 ↗
14. Watkins · 2015
15. Attributes, characteristics, and applications of titanium and its alloys10.1007/s11837-010-0071-1 ↗
16. A comparative study on the sintering and casting of a blended elemental Ti-6Al-4V alloy10.4028/www.scientific.net/MSF.828-829.421 ↗
17. Microstructural and electrochemical behaviour of aluminium alloy composites produced using different sintering techniques10.1590/1980-5373-mr-2017-0321 ↗
18. Attributes, characteristics and applications of titanium and its alloys10.1007/s11837-010-0071-1 ↗
19. Investigation on wear characteristics of a titanium alloy/steel tribo-pair
20. Compositional optimization of Al-Mn-X alloys and their tensile and corrosion properties10.2320/matertrans.F-M2015819 ↗
21. Effect of iron content on β→α phase transformation behavior of Ti-5Al-xFe (x= 1, 2.5, 4) alloys during continuous cooling10.1016/j.jmrt.2019.02.020 ↗
22. Effect of manganese on the microstructure, mechanical properties and corrosion behavior of titanium alloys10.1016/j.matchemphys.2016.06.016 ↗
23. Mechanical properties and microstructure of Ti-Mn alloys produced via powder metallurgy for biomedical applications10.1016/j.jmbbm.2018.12.005 ↗
24. Microstructural evolution and mechanical properties of an advanced γ-TiAl based alloy processed by spark plasma sintering10.3390/ma12091523 ↗
25. Influence of alloy composition and thermal history on carbide precipitation in γ-based TiAl alloys10.1016/j.intermet.2017.05.006 ↗
26. Processing and mechanical property studies of orthorhombic titanium-aluminide-based alloys10.1016/S1290-0958(01)90085-1 ↗
27. Prasad · 2017
28. A comparison of Ti–Ni and Ti-Sn binary alloys processed using powder metallurgy10.1016/j.msea.2015.07.085 ↗
29. TiSiCN and TiAlVSiCN nanocomposite coatings deposited from Ti and Ti-6Al-4V targets10.1016/j.surfcoat.2017.10.009 ↗
30. The structure and mechanical properties of as-cast Zr–Ti alloys10.1016/j.jallcom.2009.08.105 ↗
31. Luz · 2013
32. Powder metallurgy of titanium – past, present, and future10.1080/09506608.2017.1366003 ↗
33. Froes · 2015
34. Lavender · 2010
35. Aspects about sintering behaviour of a titanium hydride powder based alloy used for automotive components10.4028/www.scientific.net/AMM.823.467 ↗
36. do Nascimento Filho · 2012
37. A powder metallurgy method for manufacturing Ti−6Al−4V with wrought-like microstructures and mechanical properties via hydrogen sintering and phase transformation (HSPT)10.1016/j.scriptamat.2015.05.032 ↗
38. Microstructures and mechanical behavior of a near α titanium alloy prepared by TiH2-based powder metallurgy
39. Industrial application of titanium hydride powder10.1016/j.mprp.2016.02.051 ↗
40. Comparison of sintering of titanium and titanium hydride powders10.1179/003258909X12450768327063 ↗
41. Deoxidization mechanism of hydrogen in TiH2 dehydrogenation process10.1016/j.ijhydene.2016.05.155 ↗
42. XPS study of the deoxidization behavior of hydrogen in TiH2 powders10.1016/j.powtec.2016.09.005 ↗
43. Dehydrogenation and sintering of TiH2: an in situ study10.1007/s11661-017-4043-8 ↗
44. Surface characterizations of TiH2 powders before and after dehydrogenation10.1016/j.apsusc.2017.03.077 ↗
45. Dehydrogenation of TiH210.1016/S0921-5093(03)00117-5 ↗
46. Bulk titanium for structural and biomedical applications obtaining by spark plasma sintering (SPS) from titanium hydride powder10.1007/s10973-012-2824-2 ↗
47. Kinetics of thermal decomposition of titanium hydride powder using in situ high temperature X-ray diffraction (HTXRD)10.1590/S1516-14392005000300012 ↗
48. Oxidation stability of various Ti-alloys10.1007/s10973-017-6154-2 ↗
49. Fabrication of Ti3SiC2 powders using TiH2 as the source of Ti10.1016/j.ceramint.2011.12.037 ↗
50. Insights into intragranular precipitation and toughening effect of W in (Ti, W)C solid solution with TiH2 as the inducer10.1016/j.ceramint.2019.07.045 ↗
51. Effect of silver content on the wear and mechanical properties of powder metallurgical Ti-5Al-2.5Fe-xAg alloys10.2298/JMMB190319056Y ↗
52. Investigations on microstructure and mechanical properties of Mg-5wt.%Cu-TiB2 composites produced via powder metallurgy route10.2298/JMMB190315047S ↗
53. Tartrazine: physical, thermal and biophysical properties of the most widely employed synthetic yellow food-coloring azo dye10.1007/s10973-018-7663-3 ↗
54. Physical and thermophysical properties of a commercial Ni–Ti shape memory alloy strip10.1007/s10973-019-08615-9 ↗
55. physical, thermal and biophysical properties of the food azo dye10.1007/s10973-018-7766-x ↗
56. Jin · 2015 · vol. 3
57. Advances in manufacturing technology XXX
58. Quality improvement of end milled slots using titanium nitride coated tools
59. Kinetics of thermal decomposition of titanium hydride powder using in situ hightemperature X-ray diffraction (HTXRD)10.1590/S1516-14392005000300012 ↗
60. Kinetic study on nonisothermal dehydrogenation of TiH2 powders10.1016/j.ijhydene.2009.01.095 ↗
61. First-principles investigation of metalhydride phase stability: the Ti–H system10.1103/PhysRevB.76.064207 ↗
62. On the production of ultrafine titanium hydride powder at room temperature10.1016/S0925-8388(02)00794-6 ↗
63. Decomposition of metal hydrides in low temperatures and in high-temperature oxidation10.1016/0360-3199(93)90008-X ↗
64. Peculiarities of interatomic interaction in titanium hydrides with different content on hydrogen10.1016/S0360-3199(98)00056-1 ↗
65. Phase transformations in titanium hydrides10.1016/S0360-3199(96)00058-4 ↗
66. Electrical and thermal properties of titanium hydrides10.1016/j.jallcom.2005.10.032 ↗
67. Transformations in titanium dihydride phase10.1016/S0360-3199(98)00047-0 ↗
68. Trapping of hydrogen implanted into titanium10.1063/1.341557 ↗
69. Surface characterization of titanium hydride powder10.1016/j.vacuum.2011.07.054 ↗
70. Thermal decomposition of chemical hydrides
71. Structure and mechanical properties of Ti–6Al–4V with a replicated network of elongated pores10.1016/j.actamat.2010.09.069 ↗
72. Titanium
73. Omega phase in materials10.1016/0079-6425(82)90002-0 ↗
74. Phase relationships involving TiC and Ti3AlC (P phase) in Ti–Al–C system10.1179/026708300101508937 ↗
75. Morphology evolution of Ti3AlC carbide precipitates in high Nb containing TiAl alloys10.1016/j.actamat.2017.07.018 ↗
76. Reactive synthesis for porous Ti3AlC2 ceramics through TiH2, Al and graphite powders10.1016/j.ceramint.2013.11.136 ↗
77. Preparation of TiC-Ti3AlC composite coated graphite flakes and their improved oxidation resistance10.1016/j.ceramint.2018.09.029 ↗
78. Eaction mechanism for the synthesis of Ti3AlC2 through an intermediate carbide of Ti3AlC from elemental Ti, Al, and C powder mixture10.2109/jcersj2.118.37 ↗
79. Microstructural evolution during the formation of Ti3AlC210.1016/j.mseb.2010.01.006 ↗
80. Thermal properties and laser processing of hot-pressed materials from Ti–Al–C system10.1007/s10973-019-08107-w ↗
81. Frictional properties of Ti3AlC2 ceramic against different counterparts in deionized water and artificial seawater10.1016/j.ceramint.2015.11.153 ↗
82. Synthesis and microstructure of Ti3AlC2 by mechanically activated sintering of elemental powders10.1016/j.ceramint.2005.07.024 ↗
83. Microstructure and mechanical strength of Ti3AlC2 joints bonded using oxides as interlayer10.1016/j.ceramint.2019.05.282 ↗
84. Processing and characterization of porous Ti2AlC with controlled porosity and pore size10.1016/j.actamat.2012.07.052 ↗
85. Macro-porous Ti2AlC MAX-phase ceramics by the foam replication method10.1016/j.ceramint.2015.06.038 ↗
86. Effects of the Al content on pore structures of porous Ti3AlC2 ceramics by reactive synthesis10.1016/j.ceramint.2013.09.004 ↗
87. Performance evaluation of cBN-Ti3AlC2–Al composites fabricated by HTHP method10.1016/j.ceramint.2020.06.228 ↗
88. Corrosion resistance of Ti-6Al-4V and ASTM F75 alloys processed by electron beam melting10.1016/j.jmrt.2017.05.003 ↗
89. Nano-second UV laser processed micro-grooves on Ti6Al4V for biomedical applications10.1016/j.msec.2008.05.002 ↗
90. The mechanical properties and microstructure of high temperature Ti alloys with minor addition
91. Fabrication of Ti–Al–Cu new alloys by inductive sintering, characterization, and corrosion evaluation10.1016/j.jmrt.2019.07.040 ↗
92. Thermal characterization of titanium–titanium boride composites10.1007/s10973-019-08014-0 ↗
93. Laser treatment of Cp-Ti & Ti-Ni alloy coated with hydroxyapatite/silver nanoparticles for biomedical applications
94. Oxidation resistance of Ti-Al-Cr-Nb-based high-entropy alloys in air at 1073 K10.1007/s11665-019-04177-x ↗
95. Chen PC, Hsieh SJ, Chen CC, Zou J. The microstructure and capacitance characterizations of anodic titanium based alloy oxide nanotube. J. Nanomater.. Volume 2013, Article 157494, 9 pages.10.1155/2013/157494 ↗
96. Evaluation of a Ti–base alloy as steam cracking reactor material10.3390/ma12162550 ↗
97. AFM and SEM characterization of non-toxic vanadium-free Ti alloys used as biomaterials10.1016/S0169-4332(03)00746-3 ↗
98. The comparison of martensitic transformation sequences between aged Ti-50.6 and Ti-51.0 at.% Ni alloys by in-situ SEM observations
99. Goldstein · 200310.1007/978-1-4615-0215-9 ↗