journal article·2022-03

Aminosilicate modified zinc oxide Nanorod-GO nanocomposite for DSSC photoanodes

M. Kandasamy, S. Murugesan, M. Selvaraj, M. Mujahid Alam

Ceramics International· Volume 48· Issue 5
Publisher page

Abstract

Abstract Amine-functionalized ZnO nanorods@graphene oxide (ZnO-NR/NH2/GO) nanocomposites prepared by a facile solution route have been investigated through X-ray diffraction, diffuse reflectance spectra, Raman spectra, scanning electron microscopy and transmission electron microscopy. The amine-functionalized ZnO-NR/NH2/GO-2 nanocomposite exhibits very strong visible light absorption. Dye-sensitized solar cell (DSSC) made of ZnO-NR/NH2/GO-2 nanocomposite (with optimum 2 wt % GO) photoanode delivers a power conversion efficiency (PCE) of 3.76% which is much higher than the efficiency of unmodified ZnO-NR/GO photoanodes based DSSC (2.27%). The enhancement of PCE is primarily caused by the increased current density, attributed to the incorporation of aminosilicate and GO on the surface of ZnO-NRs which facilitates rapid transfer of electron from conduction band of ZnO to conducting surface of FTO. This diminished recombination of photogenerated electrons and holes improve the electron transfer at the photoanode/electrolyte interfaces.
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Research context

OpenAlex topics: Advanced Photocatalysis Techniques · TiO2 Photocatalysis and Solar Cells · ZnO doping and properties

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

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