journal article·2023-07

Synthesis, optical, structural, physical, and experimental gamma-ray transmission properties of high-density lead-boro-tellurite glasses: A multi-phases investigation towards providing a behavioral symmetry through Lead(II) oxide

Recep Kurtulus, Taner Kavas, Esra Kavaz, Ghada ALMisned, H.O. Tekin

Ceramics International· Volume 49· Issue 14
Publisher page

Abstract

We report the synthesis and multiple material properties of newly designed high-density lead-boro-tellurite glass system. The glass formulation as zPbO + [(100-z)(0.2B2O3 + 0.8TeO2)], where z: 10, 15, 20, and 25 mol%, were synthesized using a traditional melting technique around 625 to 725 degrees C. After successfully preparing the glass samples coded BT20-Pb10, BT20-Pb15, BT20-Pb20, and BT20-Pb25, some physical, structural, and optical an-alyses were included to serve up a broad understanding. BT20-Pb10, had a density of 5.4125 g/cm3, whilst BT20-Pb25 possessed a density of 6.0756 g/cm3. According to the XRD method, all samples except for BT20-Pb25 had an amorphous structure without any sharp peaks. Furthermore, the transmission percentage was in a decreasing trend parallel to the increasing PbO concentration. This phenomenon also influenced on energy bandgap values to reduce from 2.70 to 2.45 eV for BT20-Pb10 to BT20-Pb25 samples, respectively. In addition to the material characterizations, we studied experimental and theoretical radiation shielding properties. Using experimental methods, the photon absorption properties of the manufactured glasses were studied, and we found out that the BT20-Pb25 sample exhibited the highest MAC values among the compared glasses. Based on MAC findings, other essential parameters, such as HVL and Zeff, were found to be in enhancing way as PbO increased in the glass network. In the context of benchmarking of findings with theoretical and experimental results, it was clearly demonstrated that precise harmony reigns when all eight energy values are taken into account. To sum up, BT20-Pb25 may be regarded as a potential shielding glass for various applications in radiation fields owing to its significant material properties and shielding performance against energetic photons.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Radiation Shielding Materials Analysis · Nuclear materials and radiation effects · Glass properties and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (43)

Show source-provided references
1. The role of PbF2 on the gamma-ray photon, charged particles, and neutron shielding prowess of novel lead fluoro bismuth borate glasses
2. Optical and nuclear radiation protection characteristics of lithium bismo-borate glasses: role of ZrO2 substitution10.1016/j.radphyschem.2021.109428 ↗
3. Nuclear radiation shielding characteristics and physical, optical, mechanical, and thermal properties of lithium-borotellurite glass doped with Rb2O10.1016/j.pnucene.2021.103961 ↗
4. Synthesis and structural, optical, physical properties of Gadolinium (III) oxide reinforced TeO2–B2O3–(20-x)Li2O-xGd2O3 glass system10.1016/j.jallcom.2021.160302 ↗
5. Boron nitride nanosheet-reinforced WNiCoFeCr high-entropy alloys: the role of B4C on the structural, physical, mechanical, and radiological shielding properties10.1007/s00339-022-05813-5 ↗
6. Recycling potential of cathode ray tubes (CRTs) waste glasses based on Bi2O3 addition strategies10.1016/j.wasman.2022.04.033 ↗
7. Evaluation of bioactive borosilicate added Ag glasses in terms of radiation shielding, structural, optical, and electrical properties10.1007/s12633-022-01925-y ↗
8. Construction of MAPbBr3/EP composites with blocking path for high-performance gamma-rays shielding10.1016/j.jallcom.2022.166744 ↗
9. X-ray shielding parameters of lanthanum oxide added waste soda-lime glass10.1002/xrs.3210 ↗
10. Evaluation of gamma-rays attenuation competences for waste soda-lime glass containing MoO3: experimental study, XCOM computations, and MCNP-5 results10.1016/j.jnoncrysol.2020.120572 ↗
11. Comparative assessment of fast and thermal neutrons and gamma radiation protection qualities combined with mechanical factors of different borate-based glass systems10.1016/j.rinp.2022.105527 ↗
12. Varshneya · 2019
13. Shelby · 2005
14. Defect formation of gamma irradiated MoO3-doped borophosphate glasses10.1016/j.saa.2013.05.023 ↗
15. Influence of Sm2O3 content on photon and fast neutron interaction parameters of zinc-tellurite glasses10.1016/j.radphyschem.2021.109914 ↗
16. Precipitation of silver nanoparticles in borate glasses by 1064 nm Nd:YAG nanosecond laser pulses: characterization and dielectric studies10.1007/s11664-019-07736-z ↗
17. Fabrication, physical, mechanical properties, gamma-rays, and neutron shielding abilities of sodium bario-fluoride boro-vanadate glasses: experimental, theoretical, and simulation studies10.1007/s00339-022-05750-3 ↗
18. Physical, elastic-mechanical and radiation shielding properties of antimony borate–lithium in the form B2O3-CaO-Li2O-Sb2O3: experimental, theoretical and simulation approaches10.1007/s00339-022-05949-4 ↗
19. A comprehensive examination of zinc-boro-vanadate glass reinforced with Ag2O in physical, optical, mechanical, and radiation shielding aspects.pdf
20. Effect of CdO addition on photon, electron, and neutron attenuation properties of boro-tellurite glasses10.1016/j.ceramint.2020.10.168 ↗
21. Transparent alumino lithium borate glass-ceramics: synthesis, structure and gamma-ray shielding attitude10.1007/s10904-020-01862-6 ↗
22. The role of titania on gamma and neutron attenuation competence of sodium lead borosilicate glasses10.1007/s41779-022-00749-8 ↗
23. Barium - lead - borosilicate glass containing lanthanum oxide : fabrication , physical properties , and photon shielding characteristics
24. Physical, structural, mechanical and radiation shielding features of waste pharmaceutical glasses doped with Bi2O310.1016/j.ijleo.2022.169108 ↗
25. Understanding the role of Bi2O3 in the P2O5–CaO–Na2O–K2O glass system in terms of physical, structural and radiation shielding properties
26. Influence of combining Al2O3, La2O3, Gd2O3, and Dy2O3 with barium borosilicate glass-ceramics: a case study of gamma radiation interaction parameters10.1016/j.jmrt.2022.05.095 ↗
27. Fabrication, FTIR, physical characteristics and photon shielding efficacy of CeO2/sand reinforced borate glasses: experimental and simulation studies10.1016/j.radphyschem.2021.109837 ↗
28. Heavy metal borate glasses: potential use for radiation shielding10.1016/j.jallcom.2017.08.237 ↗
29. Effect of PbO on the elastic and radiation shielding properties of B2O3–Bi2O3–Al2O3–CuO glasses
30. The role of PbO/Bi2O3 insertion on the shielding characteristics of novel borate glasses10.1016/j.ceramint.2020.04.018 ↗
31. Enhancement of linear optical and dielectric properties as well as gamma-ray protection capacities of PbO reinforced in TeO2–WO3 glasses: comparative study10.1007/s00339-022-05931-0 ↗
32. Mott · 1979
33. Amorphous and Liquid Semiconductors · 1974
34. Optical and radiation shielding features for some phospho-silicate glasses
35. Thombare · Glasses Study Physical Properties of Sodiumborophosphate · 2016 · 6 · 8482
36. Physical, structural, optical and gamma ray shielding behavior of (20+x) PbO – 10 BaO – 10 Na2O – 10 MgO – (50-x) B2O3 glasses10.1016/j.physb.2018.10.001 ↗
37. Influence of PbO content on the gamma ray shielding properties of lead boro-telluro-phosphate glasses10.1016/j.radphyschem.2021.109516 ↗
38. UV-Visible and IR spectroscopic studies of gamma irradiated transition metal doped lead silicate glasses10.1007/s12633-009-9029-8 ↗
39. Ultraviolet and infrared absorption spectra of Cr2O3 doped – sodium metaphosphate, lead metaphosphate and zinc metaphosphate glasses and effects of gamma irradiation: a comparative study10.1016/j.saa.2013.05.093 ↗
40. Comparative study of silicate glasses containing Bi2O 3, PbO and BaO: radiation shielding and optical properties10.1016/j.anucene.2011.01.031 ↗
41. Optical and gamma ray shielding behavior of PbO-B2O3-CuO-CaO glasses10.1016/j.jmrt.2022.03.120 ↗
42. Gamma rays interactions with WO3-doped lead borate glasses10.1016/j.matchemphys.2012.03.032 ↗
43. EpiXS: a Windows-based program for photon attenuation, dosimetry and shielding based on EPICS2017 (ENDF/B-VIII) and EPDL97 (ENDF/B-VI.8)10.1016/j.radphyschem.2020.109331 ↗