Development of novel magnetic-dielectric ceramics for enhancement of reflection loss in X band

Abstract The purpose of this research was to develop BaFe 9.5 Al 1.5 CrO 19 -xCaCu 3 Ti 4 O 12 nanocomposites (x=10%, 20%, 30%, 40%, 50%) and investigate their structural and magnetic features. The substituted barium hexaferrite (BaFe 9.5 Al 1.5 CrO 19 ) nanoparticles and calcium copper titanate (CaCu 3 Ti 4 O 12 ) particles were synthesized by the auto-combustion sol-gel method. The structural, chemical composition and morphology of CaCu 3 Ti 4 O 12 (CCTO) and the nanocomposites were investigated by X-ray diffraction, Fourier transform infrared spectroscopy and scanning electron microscopy, respectively. The magnetic and microwave properties of nanocomposites were also investigated by vibrating sample magnetometer and vector network analyzer, respectively. The results confirmed that 1100 °C is the optimum synthesis temperature for CCTO, the mean particles size of the CCTO particles changing from 220 nm (at 850 °C) to 2.18 µm (1250 °C). The SEM micrograph revealed that in all of the BaM-xCCTO nanocomposites (x=10%, 20%, 30%, 40%, 50%), the CCTO dielectric particles were attached to the substituted barium hexaferrite nanoparticles, indicating the effectiveness of the adopted synthesis method. Due to the presence of a dielectric phase in the nanocomposites the saturation magnetization decreases from 22 emu/g to 12 emu/g. The coercive field was a slightly larger than substituted barium hexaferrite and increased from 5.558 kOe for substituted barium hexaferrite to 5.813 kOe for BaM-50CCTO due to hindered motion of the domain walls by the dielectric phase and also to the collective behavior of agglomerated barium ferrite nanoparticles. The BaM-30CCTO nanocomposite shows the highest value of reflection loss compared to other nanocomposites. The reflection dip frequency of BaM-30CCTO nanocomposite was −48.85 dB at 10.93 GHz.