Gradient dielectric constant sandwich-structured BaTiO3/PMMA nanocomposites with strengthened energy density and ultralow-energy loss

Abstract High energy storage density with low-energy loss polymer films are essential for high-performance electric devices. To avoid the high-energy loss of utilizing nonlinear polymer materials, a sandwich nanostructure comprising a linear polymer poly(methyl methacrylate) (PMMA) matrix embedded with a high dielectric constant BaTiO3 (BT) interlayer and poly(vinylidene fluoride) (PVDF) binder was constructed using a solution casting strategy. This structural design takes advantage of each component in the composite. The good dispersion of BT particles in the binder, which was incorporated between PMMA, enabled a high dielectric constant and fewer defects. Additionally, the excellent film formation ability of the PVDF binder guarantees the uniform thickness and stable structure of the BT mid-layer, and good miscibility between PVDF and PMMA enhanced the interaction between each layer. Interestingly, since the dielectric constant of PVDF was between BT fillers and PMMA, a dielectric gradient distribution mitigated the local electric field concentration, as proven by the simulation results. Consequently, a low-loss linear PMMA composite film exhibited satisfying breakdown strength and excellent discharged energy density, which were 25% and 460% higher than those of pristine PMMA, respectively.