Novel carbon coated core-shell heterostructure NiCo2O4@NiO grown on carbon cloth as flexible lithium-ion battery anodes

Binding-free NiCo2O4@[email protected]/cc electrode was prepared by hydrothermal method, annealing method and physical vapor deposition. In this composite, NiCo2O4@NiO was strongly grown on carbon cloth and formed a core-shell heterostructure, which can facilitate the transport of ions. What's more, the conductivity was dramatically improved after coating NiO nanofalkes. Additionally, carbon coating can inhibit volume expansion, improve material conductivity and structural stability. The free-standing electrode material showed an initial capacity of 1885 mAh g−1 at a current density of 100 mA g−1, after 100 cycles, the reversible capacity stabilized around 1051 mAh g−1 with Coulomb efficiency of 99.9%. At a high rate of 1600 mA g−1, the capacity exhibited about 721 mAh g−1, indicating that the NiCo2O4@[email protected]/cc composite is an outstanding material as the anode electrode material for flexible lithium-ion batteries with broad application prospect.