journal article·2019-11

Improving the performance of the Ba0.5Sr0.5Co0.8Fe0.2O3-δ cathode for proton-conducting SOFCs by microwave sintering

Wenyun Liu, Hongning Kou, Xianfen Wang, Lei Bi, X.S. Zhao

Ceramics International· Volume 45· Issue 16
Publisher page

Abstract

In this study, we prepared a BaSrCoFeO (BSCF) cathode layer for proton-conducting solid oxide fuel cells using microwave sintering. Unlike traditional sintering, which is carried out at 1000 °C for a few hours, the microwave sintering method allows the BSCF cathode layer to adhere well with the electrolyte layer after sintering at 900 °C for 10 min. This strategy helps the cathode layer maintain a microstructure favourable for cathode reactions and mitigate the potential diffusion of elements between it and the BaZrCeYO electrolyte, leading to improved cell resistance. The cell with the BSCF cathode layer sintered by the microwave method has a power output of 0.96 W cm at 700 °C, while the power output for the cell with a conventionally sintered cathode is 0.33 W cm.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Advancements in Solid Oxide Fuel Cells · Electronic and Structural Properties of Oxides · Chemical Looping and Thermochemical Processes

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (68)

Show source-provided references
1. Materials challenges toward proton-conducting oxide fuel cells: a critical review10.1039/b902343g ↗
2. Liquid-phase synthesis of SrCo0.9Nb0.1O3 cathode material for proton conducting solid oxide fuel cells10.1016/j.ceramint.2017.12.116 ↗
3. Steam electrolysis by solid oxide electrolysis cells (SOECs) with proton-conducting oxides10.1039/C4CS00194J ↗
4. Advanced materials for SOFC application: strategies for the development of highly conductive and stable solid oxide proton electrolytes10.1016/j.pmatsci.2015.08.001 ↗
5. The best composition of an Y-doped BaZrO3 electrolyte: selection criteria from transport properties, microstructure, and phase behavior10.1039/C8TA06280C ↗
6. Detrimental effect of sintering additives on conducting ceramics: yttrium-doped barium zirconate10.1002/cssc.201801837 ↗
7. Intermediate-temperature solid oxide electrolysis cells with thin proton-conducting electrolyte and a robust air electrode10.1039/C7TA05841A ↗
8. Demonstrating the potential of yttrium-doped barium zirconate electrolyte for high-performance fuel cells10.1038/ncomms14553 ↗
9. Chemically stable yttrium and tin Co-doped barium zirconate electrolyte for next generation high performance proton-conducting solid oxide fuel cells10.1002/aenm.201201062 ↗
10. Computational design of cobalt-free mixed proton-electron conductors for solid oxide electrochemical cells10.1039/C7TA00338B ↗
11. First-principles design of new electrodes for proton-conducting solid-oxide electrochemical cells: a-site doped Sr2Fe1.5Mo0.5O6 perovskite10.1021/acs.chemmater.5b03262 ↗
12. Effects of H2O and CO2 on electrochemical behaviors of BSCF cathode for proton conducting IT-SOFC10.1149/2.0611702jes ↗
13. Exceptional power density and stability at intermediate temperatures in protonic ceramic fuel cells10.1038/s41560-017-0085-9 ↗
14. Cathode processes and materials for solid oxide fuel cells with proton conductors as electrolytes10.1039/c0jm00350f ↗
15. High-performance composite cathodes with tailored mixed conductivity for intermediate temperature solid oxide fuel cells using proton conducting electrolytes10.1039/c1ee02361f ↗
16. Nanostructuring the electronic conducting La0.8Sr0.2MnO3 cathode for high-performance in proton-conducting solid oxide fuel cells below 600 degrees C10.1007/s40843-017-9125-1 ↗
17. Tailoring the cathode-electrolyte interface with nanoparticles for boosting the solid oxide fuel cell performance of chemically stable proton-conducting electrolytes10.1002/smll.201801231 ↗
18. An in situ formed, dual-phase cathode with a highly active catalyst coating for protonic ceramic fuel cells10.1002/adfm.201704907 ↗
19. New, efficient, and reliable air electrode material for proton-conducting reversible solid oxide cells10.1021/acsami.7b16703 ↗
20. Application of silver in microtubular solid oxide fuel cells, Mater
21. A novel composite cathode for low-temperature SOFCs based on oxide proton conductors10.1002/adma.200702762 ↗
22. Microwave versus conventional sintering: a review of fundamentals, advantages and applications10.1016/j.jallcom.2010.01.068 ↗
23. Temperature profile and sinterability of self-heating porous NiO-(Ce, Sm)O2 composite during microwave irradiation10.2109/jcersj.114.106 ↗
24. Influence of microwave-assisted hydrothermal treatment on the properties of nickel oxide-zirconia based composites10.1016/j.ceramint.2016.02.165 ↗
25. Fabrication of high-performance proton-conducting electrolytes from microwave prepared ultrafine powders for solid oxide fuel cells10.1016/j.jpowsour.2018.11.051 ↗
26. Highly-conductive proton-conducting electrolyte membranes with a low sintering temperature for solid oxide fuel cells10.1016/j.memsci.2018.04.037 ↗
27. Fabrication of one-step co-fired proton-conducting solid oxide fuel cells with the assistance of microwave sintering10.1016/j.jeurceramsoc.2018.08.020 ↗
28. Enhanced oxygen reduction activity and solid oxide fuel cell performance with a nanoparticles-loaded cathode10.1021/nl5043566 ↗
29. Palladium-cobalt nanodots anchored on graphene: in-situ synthesis, and application as an anode catalyst for direct formic acid fuel cells10.1016/j.apsusc.2018.11.034 ↗
30. Insights into the role of poly(vinylpyrrolidone) in the synthesis of palladium nanoparticles and their electrocatalytic properties10.1021/acs.langmuir.8b04032 ↗
31. Tailoring cathode composite boosts the performance of proton-conducting SOFCs fabricated by a one-step co-firing method10.1016/j.jeurceramsoc.2018.02.022 ↗
32. Electrical characterization of La9.33Si2Ge4O26 oxyapatite for prospective intermediate-temperature solid oxide fuel cells10.1016/j.ceramint.2016.12.043 ↗
33. J. CO2-to-CO conversion on layered perovskite with in situ exsolved Co-Fe alloy nanoparticles: an active and stable cathode for solid oxide electrolysis cells10.1039/C6TA06365A ↗
34. A stable and thin BaCe0.7Nb0.1Gd0.2O3 membrane prepared by simple all-solid-state process for SOFC10.1016/j.jpowsour.2008.11.007 ↗
35. Sm0.5Sr0.5CoO3 infiltrated Ce0.9Gd0.1O2 composite cathodes for high performance protonic ceramic fuel cells10.1016/j.jpowsour.2016.09.146 ↗
36. Evaluation of Ba0.5Sr0.5Co0.8Fe0.2O3 as a potential cathode for an anode-supported proton-conducting solid-oxide fuel cell10.1016/j.jpowsour.2008.02.044 ↗
37. Cation non-stoichiometry in yttrium-doped barium zirconate: phase behavior, microstructure, and proton conductivity10.1039/c0jm02013c ↗
38. Barium- and strontium-enriched Ba0.5Sr0.5(1+x)Co0.8Fe0.2O3 oxides as high-performance cathodes for intermediate-temperature solid-oxide fuel cells10.1016/j.actamat.2008.02.002 ↗
39. Electrochemical properties of intermediate-temperature SOFCs based on proton conducting Sm-doped BaCeO3 electrolyte thin film10.1016/j.ssi.2005.11.020 ↗
40. Fabrication of anode supported direct ammonia solid oxide fuel cells based on proton conducting Y-doped BaCeO3 electrolyte
41. Zirconium doping effect on the performance of proton-conducting BaZryCe0.8-yY0.2O3 (0.0 <= y <= 0.8) for fuel cell applications10.1016/j.jpowsour.2009.03.044 ↗
42. A high electrochemical performance proton conductor electrolyte with CO2 tolerance10.1016/S1872-2067(08)60112-6 ↗
43. Silver-modified Ba0.5Sr0.5Co0.8Fe0.2O3 as cathodes for a proton conducting solid-oxide fuel cell10.1016/j.ijhydene.2009.12.017 ↗
44. Novel Ba0.5Sr0.5(Co0.8Fe0.2)(1-x)TixO3 (x=0, 0.05, and 0.1) cathode materials for proton-conducting solid oxide fuel cells10.1016/j.ssi.2012.02.049 ↗
45. Effect of anode functional layer on the performance of proton-conducting solid oxide fuel cells (SOFCs)10.1016/j.elecom.2011.12.023 ↗
46. A performance study of solid oxide fuel cells with BaZr0.1Ce0.7Y0.2O3 electrolyte developed by spray-modified pressing method10.1002/fuce.201100109 ↗
47. Performance and stability of proton conducting solid oxide fuel cells based on yttrium-doped barium cerate-zirconate thin-film electrolyte10.1016/j.jpowsour.2012.11.094 ↗
48. G. Taillades, P. Pers, P. Batocchi, M. Taillades, Advanced electrodes for intermediate temperature proton conducting fuel cell, in: T. Kawada, S.C. Singhal (Eds.) Solid Oxide Fuel Cells 132013, 1289-1296.10.1149/05701.1289ecst ↗
49. Structure, sinterability, chemical stability and conductivity of proton-conducting BaZr0.6M0.2Y0.2O3 electrolyte membranes: the effect of the M dopant10.1016/j.memsci.2014.05.020 ↗
50. A stable and efficient cathode for fluorine-containing proton-conducting solid oxide fuel cells10.1002/cssc.201801193 ↗
51. Performance variability of Ba0.5Sr0.5Co0.8Fe0.2O3 cathode on proton-conducting electrolyte SOFCs with Ag and Au current collectors10.1007/s12598-017-0942-5 ↗
52. High performance of protonic solid oxide fuel cell with BaCo0.7Fe0.22Sc0.08O3 electrode10.1016/j.ijhydene.2017.08.107 ↗
53. Tailoring electrochemical property of layered perovskite cathode by Cu-doping for proton-conducting IT-SOFCs10.1002/fuce.201400141 ↗
54. Further optimization of barium cerate properties via co-doping strategy for potential application as proton-conducting solid oxide fuel cell electrolyte10.1016/j.jpowsour.2018.03.054 ↗
55. Thermal stress analysis of sulfur deactivated solid oxide fuel cells10.1016/j.jpowsour.2018.01.011 ↗
56. Tailoring Ba3Ca1.18Nb1.82O9 with NiO as electrolyte for proton-conducting solid oxide fuel cells10.1016/j.jpowsour.2017.10.091 ↗
57. Triple-conducting layered perovskites as cathode materials for proton-conducting solid oxide fuel cells10.1002/cssc.201402351 ↗
58. Readily processed protonic ceramic fuel cells with high performance at low temperatures10.1126/science.aab3987 ↗
59. Proton-conducting solid oxide fuel cell (SOFC) with Y-doped BaZrO3 electrolyte10.1016/j.elecom.2017.05.006 ↗
60. Enhanced electrochemical performance and stability of (La,Sr) MnO3-(Gd,Ce)O2 oxygen electrodes of solid oxide electrolysis cells by palladium infiltration10.1016/j.ijhydene.2011.10.015 ↗
61. Facile fabrication of stable PdCu clusters uniformly decorated on graphene as an efficient electrocatalyst for formic acid oxidation10.1016/j.ijhydene.2018.12.004 ↗
62. Strategies for improving the lithium-storage performance of 2D nanomaterials10.1093/nsr/nwx077 ↗
63. Solid oxide fuel cells with proton-conducting La0.99Ca0.01NbO4 electrolyte10.1016/j.electacta.2017.12.030 ↗
64. Strategies for designing metal oxide nanostructures10.1007/s40843-016-5117-0 ↗
65. Ba(Zr0.1Ce0.7Y0.2)O3-delta as an electrolyte for low-temperature solid-oxide fuel cells10.1002/adma.200601366 ↗
66. Chemically stable anode-supported solid oxide fuel cells based on Y-doped barium zirconate thin films having improved performance10.1016/j.elecom.2010.05.005 ↗
67. Progress in understanding and development of Ba0.5Sr0.5Co0.8Fe0.2O3-based cathodes for intermediate-temperature solid-oxide fuel cells: a review10.1016/j.jpowsour.2009.02.069 ↗
68. Cathode reaction models and performance analysis of Sm0.5Sr0.5CoO3-BaCe0.8Sm0.2O3 composite cathode for solid oxide fuel cells with proton conducting electrolyte10.1016/j.jpowsour.2009.04.053 ↗