journal article·2019-12

La2Hf2O7 ceramics as potential top-coat materials for thermal/environmental barrier coatings

Panpan Liang, Shujuan Dong, Jinyan Zeng, Jieyan Yuan, Jianing Jiang, Longhui Deng, Xin Zhou, Xueqiang Cao

Ceramics International· Volume 45· Issue 17
Publisher page

Abstract

Abstract La 2 Hf 2 O 7 (LH) ceramics with pyrochlore structure have excellent phase stability up to 1600 °C, and far superior sintering resistance as well as comparable mechanical properties to typical 8 wt% yttria-stabilized zirconia (8YSZ). More importantly, they have the coefficients of thermal expansion (CTEs) of 8.76 × 10 −6 K −1 , lower than that of 8YSZ (10.38 × 10 −6 K −1 ), and thermal conductivities of 1.34 W/m·K at 1000 °C, approximately 40% lower than that of 8YSZ (2.1–2.22 W/m·K). These comprehensive properties promote them as thermal insulation top-coats in thermal/environmental barrier coatings (T/EBCs) on ceramic-matrix composites (CMCs) or top-coats of double-ceramic-layered thermal barrier coatings (DCL-TBCs) on superalloys.
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Research context

OpenAlex topics: Nuclear materials and radiation effects · High-Temperature Coating Behaviors · Nuclear Materials and Properties

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