journal article·2018-08

Yttrium doped cobalt ferrite nanoparticles: Study of dielectric relaxation and charge carrier dynamics

S. Chakrabarty, M. Pal, A. Dutta

Ceramics International· Volume 44· Issue 12
Publisher page

Abstract

Abstract We report the effect of yttrium (Y) doping on structural, optical properties and conductivity relaxation behavior of cobalt ferrite (CFO) nanoparticles prepared via citrate auto-ignition route. Microstructural analysis using XRD study confirms the growth of single phase nanocrystalline CFO, HRTEM images delineate faults in the crystal stacking sequence. UV–vis absorption spectra show a blue shift for optical band gaps of the doped samples. Impedance spectroscopy suggests that both grain and grain boundaries contribute to the conduction process. A universal power law dependence of the conductivity spectra has been observed. Scaling of the conductivity spectra resulted the conduction mechanism to be independent of composition and temperature. Stretched behavior of the dielectric response has been elucidated by Harviliak-Negami (H.N.) model based functions. Defects in the crystal structure played important role on the overall transport properties of the system.
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Research context

OpenAlex topics: Magnetic Properties and Synthesis of Ferrites · Multiferroics and related materials · Electromagnetic wave absorption materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (40)

Show source-provided references
1. Monodomain MgCuZn ferrite with equivalent permeability and permittivity for broad frequency band applications10.1016/j.ceramint.2017.01.129 ↗
2. Electrospun bismuth ferrite nanofibers for potential applications in ferroelectric photovoltaic devices10.1021/acsami.5b00069 ↗
3. Enhanced magnetic domain relaxation frequency and low power losses in Zn2+ substituted manganese ferrites potential for high frequency applications10.1016/j.jmmm.2016.07.011 ↗
4. Exploring the magnetic and structural properties of Nd-doped cobalt nano-ferrite for permanent magnet applications10.1016/j.ceramint.2017.07.209 ↗
5. Fe3O4 nanostructures: synthesis, growth mechanism, properties and applications10.1039/c0cc05862a ↗
6. Combination of cobalt ferrite and graphene: high-performance and recyclable visible-light photocatalysis10.1016/j.apcatb.2011.10.009 ↗
7. The role of cobalt ferrite magnetic nanoparticles in medical science10.1016/j.msec.2012.09.003 ↗
8. Magnetic and structural properties of nano sized Dy-doped cobalt ferrite synthesized by co-precipitation10.1016/j.jmmm.2014.01.016 ↗
9. Low temperature hydrothermal synthesis and characterization of Mn doped cobalt ferrite nanoparticles10.1016/j.ceramint.2012.01.001 ↗
10. Palladium(0) nanoparticles supported on silica-coated cobalt ferrite: a highly active, magnetically isolable and reusable catalyst for hydrolytic dehydrogenation of ammonia borane10.1016/j.apcatb.2013.09.023 ↗
11. Transition metal-substituted cobalt ferrite nanoparticles for biomedical applications10.1016/j.actbio.2012.10.037 ↗
12. Ascorbic acid-assisted synthesis of cobalt ferrite (CoFe2O4) hierarchical flower-like microspheres with enhanced lithium storage properties10.1016/j.jpowsour.2014.01.038 ↗
13. Structural, electric and magnetic properties of CoFe1.8RE0.2O4 (RE=Dy, Gd, La) bulk materials10.1016/j.jmmm.2012.12.048 ↗
14. Dielectric, complex impedance, and electrical transport properties of erbium (Er3+) ion-substituted nanocrystalline, cobalt-rich ferrite (Co1.1Fe1.9–xErxO4)10.1021/acs.jpcc.5b11188 ↗
15. Structural characteristics, electrical conduction and dielectric properties of gadolinium substituted cobalt ferrite10.1016/j.jallcom.2014.07.182 ↗
16. Effect of the rare-earth substitution on the structural, magnetic and adsorption properties in cobalt ferrite nanoparticles10.1016/j.ceramint.2015.11.100 ↗
17. Impact of Gd3+ substitution on the structural, magnetic and electrical properties of cobalt ferrite nanoparticles10.1039/C5RA14351A ↗
18. Study on the electromagnetic behavior evaluation of Y3+ doped cobalt nanocrystals synthesized via co-precipitation route10.1016/j.jmmm.2014.07.043 ↗
19. Yttrium-doped cobalt nanoferrites prepared by sol–gel combustion method and its characterization10.1166/jnn.2013.7250 ↗
20. Structural studies on the yttrium-doped cobalt ferrite powders synthesized by sol–gel combustion method10.1016/j.jmmm.2012.02.110 ↗
21. Structural characterization of manganese-substituted nanocrystalline zinc oxide using small-angle neutron scattering and high-resolution transmission electron microscopy10.1107/S002188980903475X ↗
22. Application of composition controlled nickel-alloyed iron sulfide pyrite nanocrystal thin films as the hole transport layer in cadmium telluride solar cells10.1039/C7TC00948H ↗
23. Functionally graded nanocrystalline silicon powders by mechanical alloying10.1016/j.matlet.2017.11.114 ↗
24. Nickel-doped cobalt ferrite nanoparticles: efficient catalysts for the reduction of nitroaromatic compounds and photo-oxidative degradation of toxic dyes10.1039/C4NR01730G ↗
25. Microstructure and blueshift in optical band gap of nanocrystalline AlxZn1−xO thin films10.1016/j.jlumin.2014.06.007 ↗
26. Gd3+ doped Mn-Zn soft ferrite nanoparticles: superparamagnetism and its correlation with other physical properties10.1016/j.jmmm.2017.01.081 ↗
27. Ionic conductivity and dielectric relaxation in Y doped La2Mo2O9 oxide-ion conductors10.1063/1.4897456 ↗
28. Analysis of the dc and ac properties of K2O-doped porous Ba0.5Sr0.5TiO3 ceramic humidity sensor10.1007/BF02385619 ↗
29. Structure and electrical properties of Co0. 5CdxFe2.5− xO4 ferrites10.1016/j.jallcom.2007.09.126 ↗
30. Jump-relaxation model yields Kohlrausch-Williams-Watts behavior10.1016/0167-2738(90)90321-H ↗
31. The 'universal'dielectric response10.1038/267673a0 ↗
32. Temperature dependence of the ac conductivity of Naβ-alumina10.1016/0038-1098(82)91103-6 ↗
33. Phase transitions in ferrimagnetic and ferroelectric ceramics by ac measurements10.1063/1.122360 ↗
34. Dielectric relaxation behavior and electrical conduction mechanism in polymer-ceramic composites based on Sr modified barium zirconium titanate ceramic10.1007/s10965-012-9898-1 ↗
35. Scaling of the conductivity spectra in ionic glasses: dependence on the structure10.1103/PhysRevLett.84.2188 ↗
36. A complex plane representation of dielectric and mechanical relaxation10.1016/0032-3861(67)90021-3 ↗
37. Interplay between the charge transport phenomena and the charge-transfer phase transition in RbxMn[Fe(CN)6]y·zH2O10.1021/jp8090478 ↗
38. Effect of calcination temperature on the structural and electrical properties of cobalt ferrite synthesized by combustion method10.1016/j.jallcom.2010.10.073 ↗
39. Electrical conductivity and thermoelectric power measurements of some lithium–titanium ferrites10.1063/1.336954 ↗
40. Dielectric properties of copper containing ferrites10.1002/pssa.2210230229 ↗