journal article·2015-12

Role of fuel and fuel-to-oxidizer ratio in combustion synthesis of nano-crystalline nickel oxide powders

Shreyash Hadke, Madhu Telugu Kalimila, Shashwat Rathkanthiwar, Shivani Gour, Reshma Sonkusare, Atul Ballal

Ceramics International· Volume 41· Issue 10
Publisher page

Abstract

Nanocrystalline nickel oxide (NiO) powders are synthesized using combustion technique, with nickel nitrate hexahydrate as the oxidizer, and glycine and urea as fuels. Effect of fuel-to-oxidizer (F/O) ratio on the powder characteristics such as the shape, particle size, agglomeration, crystallite size, composition, residual carbon content, and sinterability is studied. It is found that, powder characteristics are a strong function of the type of fuel, and the F/O ratio. Compared to powders synthesized using glycine as the fuel, powders synthesized using area had a more spherical shape, smaller and harder agglomerates, smaller crystallite size, less content of metallic Ni, higher residual carbon content, and higher sinterability.
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Research context

OpenAlex topics: Transition Metal Oxide Nanomaterials · Gas Sensing Nanomaterials and Sensors · Pigment Synthesis and Properties

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References (28)

Show source-provided references
1. Size dependence of structural metastability in semiconductor nanocrystals10.1126/science.276.5311.398 ↗
2. Fabrication of novel hierarchical β-Ni(OH)2 and NiO microspheres via an easy hydrothermal process10.1021/jp809013g ↗
3. Properties and microstructure of NiO/SDC materials for SOFC anode applications10.1016/S1001-0521(07)60169-7 ↗
4. Size effect of nickel oxide for lithium ion battery anode10.1016/j.jpowsour.2013.12.037 ↗
5. An electrochemical route for making porous nickel oxide electrochemical capacitors10.1149/1.1837859 ↗
6. Synthesis of nickel and nickel oxide nanoparticles via heat-treatment of simple octanoate precursor10.1016/j.jallcom.2010.01.063 ↗
7. A novel precursor in preparation and characterization of nickel oxide nanoparticles via thermal decomposition approach10.1016/j.jallcom.2009.11.153 ↗
8. Microwave-assisted and liquid oxidation combination techniques for the preparation of nickel oxide nanoparticles10.1016/j.jallcom.2006.10.114 ↗
9. Synthesis of NiO–ZrO2 powders for solid oxide fuel cells10.1016/S0272-8842(03)00031-2 ↗
10. Facile synthesis and hierarchical assembly of hollow nickel oxide architectures bearing enhanced photocatalytic properties10.1021/jp804921g ↗
11. Microwave-mediated synthesis for improved morphology and pseudocapacitance performance of nickel oxide, Appl10.1021/am200294k ↗
12. Nickel and nickel oxide nanoparticles prepared from nickel nitrate hexahydrate by a low pressure spray pyrolysis10.1016/j.mseb.2004.03.024 ↗
13. Nanocrystalline thoria powders via glycine-nitrate combustion10.1016/S0022-3115(00)00717-0 ↗
14. Glycine-nitrate combustion synthesis of oxide ceramic powders10.1016/0167-577X(90)90003-5 ↗
15. Ultrafine ceria powders via glycine-nitrate combustion10.1016/S0025-5408(01)00762-0 ↗
16. Role of glycine-to-nitrate ratio in influencing the powder characteristics of La(Ca)CrO310.1016/j.materresbull.2007.06.021 ↗
17. Combustion synthesis of gadolinia-doped ceria using glycine and urea fuels10.1016/j.jallcom.2007.11.028 ↗
18. Phase and microstructural evolution of heat treated nanocrystalline powders in Al2O3–MgO binary system10.1016/S0965-9773(99)00330-X ↗
19. Quantitative effects of fuel on the synthesis of Ni/NiO particles using a microwave-induced solution combustion synthesis in air atmosphere10.1016/j.matlet.2005.03.021 ↗
20. Glycine-nitrate combustion synthesis of oxide ceramic powders10.1016/0167-577X(90)90003-5 ↗
21. Combustion synthesis and nanomaterials10.1016/j.cossms.2008.12.002 ↗
22. Energetic materials in ceramics synthesis10.1557/PROC-296-361 ↗
23. A new approach to thermochemical calculations of condensed fuel-oxidizer mixtures10.1016/0010-2180(81)90111-5 ↗
24. Some aspects in self-propagating high-temperature synthesis10.1016/S0272-8842(03)00119-6 ↗
25. Greenwood · 1984
26. Haynes · 2014
27. Patnaik · 2003
28. Green · 2007