journal article·2022-02

Design of hierarchical core-shell ZnFe2O4@MnO2@RGO composite with heterogeneous interfaces for enhanced microwave absorption

Zhao Lu, Yan Wang, Xiaochuang Di, Runrun Cheng, Longqi Yang, Peihu Gao

Ceramics International· Volume 48· Issue 4
Publisher page

Abstract

Abstract In order to overcome the problems caused by electromagnetic pollution, the design and development of high-performance microwave absorbers is urgently required. In this work, a hierarchical ZnFe2O4@MnO2@RGO composite was successfully fabricated via a facile and rapid hydrothermal method. Its unique core-shell structure and synergistic effect between multiple components are beneficial for electromagnetic wave absorption. The morphology, elemental composition, microstructure and microwave absorption characteristics were systematically studied. With a filler loading of 20 wt%, the composite presents a minimum reflection loss (RLmin) of −46.7 dB and an effective absorption bandwidth (EAB) as wide as 5.2 GHz at a thickness of 2.5 mm. The superior absorption ability profits from a special microstructure, good impedance matching, multiple attenuation features, interfacial polarization, and the synergistic effect of dielectric and magnetic loss. Consequently, this work lays a foundation for the design of high-performance electromagnetic wave absorbers with multicomponent heterogeneous structures.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Electromagnetic wave absorption materials · Advanced Antenna and Metasurface Technologies · Metamaterials and Metasurfaces Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (61)

Show source-provided references
1. Metal-Organic framework-based PB@MoS2 core-shell microcubes with high efficiency and broad bandwidth for microwave absorption performance10.1021/acssuschemeng.9b00191 ↗
2. Graphene multilayered sheets assembled by porous Bi2Fe4O9 microspheres and the excellent electromagnetic wave absorption properties10.1016/j.cej.2017.11.150 ↗
3. Multifunctional bulk hybrid foam for infrared stealth, thermal insulation and microwave absorption10.1021/acsami.0c09202 ↗
4. Carbon-based MOF derivatives: emerging efficient electromagnetic wave absorption agents10.1007/s40820-021-00658-8 ↗
5. Core-shell FeCo@carbon nanoparticles encapsulated in polydopamine-derived carbon nanocages for efficient microwave absorption10.1016/j.carbon.2019.01.082 ↗
6. Heterostructure design of Ni/C/porous carbon nanosheet composite for enhancing the electromagnetic wave absorption10.1016/j.carbon.2021.04.050 ↗
7. Metal-organic polymer coordination materials derived Co/N- doped porous carbon composites for frequency-selective microwave absorption10.1016/j.compositesb.2020.108406 ↗
8. Excellent electromagnetic wave absorption properties of the ternary composite ZnFe2O4@PANI-rGO optimized by introducing covalent bonds10.1016/j.compscitech.2021.108801 ↗
9. Synthesis of core-shell ZnFe2O4@SiO2 hollow microspheres/reduced graphene oxides for a high-performance EM wave absorber10.1016/j.ceramint.2016.09.035 ↗
10. Selective synthesis and properties of monodisperse Zn ferrite hollow nanospheres and nanosheets10.1021/jp800997z ↗
11. Coupling hollow Fe3O4-Fe nanoparticles with graphene sheets for high-performance electromagnetic wave absorbing material10.1021/acsami.5b12789 ↗
12. Modulation of electromagnetic wave absorption by carbon shell thickness in carbon encapsulated magnetite nanospindles-poly (vinylidene fluoride) composites10.1016/j.carbon.2015.09.036 ↗
13. A facile fabrication and highly tunable microwave absorption of 3D Flower-like Co3O4-rGO hybrid-architectures10.1016/j.cej.2018.01.152 ↗
14. Enhanced microwave absorption performances of polyaniline/graphene aerogel by covalent bonding10.1016/j.compositesb.2019.04.008 ↗
15. Magnetic core-shell MnFe2O4@TiO2 nanoparticles decorated on reduced graphene oxide as a novel adsorbent for the removal of ciprofloxacin and Cu(II) from water10.1016/j.apsusc.2020.148400 ↗
16. MoS2 spheres decorated on hollow porous ZnO microspheres with strong wideband microwave absorption10.1016/j.cej.2019.122625 ↗
17. Multimaterial 3D-printing of graphene/Li0.35Zn0.3Fe2.35O4 and graphene/carbonyl iron composites with superior microwave absorption properties and adjustable bandwidth10.1016/j.carbon.2020.05.071 ↗
18. Nanoscaled self-alignment of Fe3O4 nanodiscs in ultrathin rGO film with engineered conductivity for electromagnetic interference shielding10.1039/C6NR04539A ↗
19. Hierarchical Fe3O4@carbon@MnO2 hybrid for electromagnetic wave absorber10.1016/j.jcis.2019.06.058 ↗
20. Synthesis of hierarchical ZnFe2O4@SiO2@RGO core- shell microspheres for enhanced electromagnetic wave absorption10.1021/acsami.7b03330 ↗
21. Constructing uniform Fe3O4@C@MnO2 microspheres with yolk-shell interior toward enhancement in microwave absorption10.1016/j.jallcom.2019.152795 ↗
22. Heterostructured CoFe@C@MnO2 nanocubes for efficient microwave absorption10.1016/j.cej.2019.123039 ↗
23. 1D flower-like Fe3O4@SiO2@MnO2 nanochains inducing RGO self-assembly into aerogels for high-efficient microwave absorption10.1016/j.matdes.2019.108462 ↗
24. Honeycomb-like NiCo2O4@MnO2 nanosheets array/3D porous expanded graphite hybrids for high-performance microwave absorber with hydrophobic and flame-retardant functions10.1016/j.cej.2021.129547 ↗
25. CoNi@SiO2@TiO2 and CoNi@air@TiO2 microspheres with strong wideband microwave absorption10.1002/adma.201503149 ↗
26. Facile design of 3D hierarchical NiFe2O4/N-GN/ZnO composite as a high performance electromagnetic wave absorber10.1016/j.cej.2019.121942 ↗
27. A high-performance voltammetric methodology for the ultra-sensitive detection of riboflavin in food matrices based on graphene oxide-covered hollow MnO2 spheres10.1016/j.foodchem.2021.129368 ↗
28. Engineering phase transformation of MoS2/RGO by N-doping as an excellent microwave absorber10.1021/acsami.0c01998 ↗
29. Graphene oxide/carbon nanotubes/CoxFe3-xO4 ternary nanocomposites: controllable synthesis and their excellent microwave absorption capabilities10.1016/j.jallcom.2019.151996 ↗
30. Synthesis of lightweight N-doped graphene foams with open reticular structure for high-efficiency electromagnetic wave absorption10.1016/j.cej.2019.02.193 ↗
31. Facile synthesis of Mn3O4 hollow polyhedron wrapped by multiwalled carbon nanotubes as a high-efficiency microwave absorber10.1016/j.ceramint.2019.09.124 ↗
32. Facile fabrication of α-FeOOH nanorod/RGO composite: a robust photocatalyst for reduction of Cr(VI) under visible light irradiation10.1039/C4TA00931B ↗
33. Microwave absorption enhancement and loss mechanism of lamellar MnO2 nanosheets decorated reduced graphene oxide hybrid10.1007/s10854-018-0354-9 ↗
34. Facile synthesis of hollow ZnxFe3−xO4@Porous MnO2/rGO conductive network composites for tunable electromagnetic wave absorption10.1021/acs.iecr.8b04406 ↗
35. Rational construction of bowl-like MnO2 nanosheets with excellent electrochemical performance for supercapacitor electrodes10.1016/j.cej.2018.05.169 ↗
36. Fabrication of one-dimensional ZnFe2O4@carbon@ MoS2/FeS2 composites as electromagnetic wave absorber10.1016/j.jcis.2021.04.142 ↗
37. Wheat flour-derived nanoporous carbon@ZnFe2O4 hierarchical composite as an outstanding microwave absorber10.1016/j.carbon.2020.11.006 ↗
38. Mesoporous CoFe alloy@SiO2 nanocapsules with controllable Co/Fe atomic ratio for highly efficient tunable electromagnetic wave absorption10.1016/j.jallcom.2019.06.198 ↗
39. High-performance electromagnetic wave absorbing CNT/SiCf composites: synthesis, tuning, and mechanism10.1021/acsami.9b19281 ↗
40. Dielectric behavior of Fe3N@C composites with green synthesis and their remarkable electromagnetic wave absorption performance10.1016/j.jcis.2020.08.087 ↗
41. Novel binary cobalt nickel oxide hollowed-out spheres for electromagnetic absorption applications10.1016/j.cej.2019.122797 ↗
42. Synthesis of sandwich-like Co15Fe85@C/RGO multicomponent composites with tunable electromagnetic parameters and microwave absorption performance10.1039/D0NR04615A ↗
43. Carbon nanocages with N-doped carbon inner shell and Co/N-doped carbon outer shell as electromagnetic wave absorption materials10.1016/j.cej.2019.122653 ↗
44. Achieving super-broad effective absorption bandwidth with low filler loading for graphene aerogels/raspberry-like CoFe2O4 clusters by N doping10.1016/j.jcis.2021.01.069 ↗
45. 3D nest-like architecture of core-shell CoFe2O4@1T/2H-MoS2 composites with tunable microwave absorption performance10.1021/acsami.9b23489 ↗
46. MOF-derived nanoporous carbon/Co/Co3O4/CNTs/RGO composite with hierarchical structure as a high-efficiency electromagnetic wave absorber10.1016/j.jallcom.2020.156215 ↗
47. Synthesis of porous carbon embedded with NiCo/CoNiO2 hybrids composites for excellent electromagnetic wave absorption performance10.1016/j.jcis.2020.04.099 ↗
48. Synthesis and enhanced electromagnetic wave absorption performances of Fe3O4@C decorated walnut shell-derived porous carbon10.1016/j.carbon.2020.05.070 ↗
49. Design of carbon sphere/magnetic quantum dots with tunable phase compositions and boost dielectric loss behavior10.1016/j.cej.2017.09.174 ↗
50. Graphene nanohybrids: excellent electromagnetic properties for the absorbing and shielding of electromagnetic waves10.1039/C7TC05869A ↗
51. Sandwich-like cobalt/reduced graphene oxide/cobalt composite structure presenting synergetic electromagnetic loss effect10.1016/j.jcis.2019.11.045 ↗
52. Hierarchical Fe3O4/Fe@C@MoS2 core-shell nanofibers for efficient microwave absorption10.1016/j.carbon.2021.04.051 ↗
53. MOFs derived magnetic porous carbon microspheres constructed by core-shell Ni@C with high-performance microwave absorption10.1016/j.jmst.2021.02.011 ↗
54. Metal-organic-frameworks derived porous carbon- wrapped Ni composites with optimized impedance matching as excellent lightweight electromagnetic wave absorber10.1016/j.cej.2016.12.117 ↗
55. Rational construction of hierarchical Co@C@NPC nanocomposites derived from bimetallic hybrid ZIFs/biomass for boosting the microwave absorption10.1016/j.jcis.2021.01.013 ↗
56. Defect engineering in two common types of dielectric materials for electromagnetic absorption applications10.1002/adfm.201901236 ↗
57. Core-shell CoNi@graphitic carbon decorated on B,N- codoped hollow carbon polyhedrons toward lightweight and high-efficiency microwave attenuation10.1021/acsami.9b08525 ↗
58. MOF-Guest complex derived Cu/C nanocomposites with multiple heterogeneous interfaces for excellent electromagnetic waves absorption10.1016/j.compositesb.2021.108643 ↗
59. Facile fabrication of Ni embedded TiO2/C core-shell ternary nanofibers with multicomponent functional synergy for efficient electromagnetic wave absorption10.1016/j.compositesb.2020.108343 ↗
60. Lightweight and high-performance microwave absorber based on 2D WS2-RGO heterostructures10.1007/s40820-019-0270-4 ↗
61. Hollow engineering to Co@N-doped carbon nanocages via synergistic protecting-etching strategy for ultrahigh microwave absorption10.1002/adfm.202102812 ↗