journal article·2020-08

Effects of Ca2+-Sr2+ doping on the infrared emissivity of LaCrO3

Ling Liu, Shuyu Zhang, Zhuang Ma, Shizhen Zhu

Ceramics International· Volume 46· Issue 12
Publisher page

Abstract

Abstract LaCrO3 shows excellent thermal stability and good emissivity, and can be used as a potential thermal protection material for hypersonic vehicle. In this study, LaCrO3 and Ca2+-Sr2+ doped LaCrO3 were prepared by solid state reaction at 1400 °C for 2 h. The microstructures of the samples and effects of Ca2+-Sr2+ doping on the infrared emissivity of LaCrO3 were studied by XRD, XPS, FT-IR, and UV–VIS–NIR spectrophotometer. The results show that after doping Ca2+ and Sr2+ ions, the infrared emissivity of all samples has significantly improved at 2.5–10 μm, from 0.61 (minimum value) to above 0.90. In the range of 10–14 μm, the emissivity of pure LaCrO3 and La0.8CaxSr0.2-xCrO3 samples shows a similar trend and all remains above 0.97. Therefore, doping Ca2+ and Sr2+ can significantly increase the emissivity of LaCrO3 at 2.5–10 μm, which makes it have a wider application prospect in the field of high temperature thermal protection.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Transition Metal Oxide Nanomaterials · Optical properties and cooling technologies in crystalline materials · Luminescence Properties of Advanced Materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (21)

Show source-provided references
1. Research of a combined power and cooling system based on fuel rotating cooling air turbine and organic Rankine cycle on hypersonic aircraft10.1016/j.energy.2019.116183 ↗
2. High emissivity MoSi2–ZrO2–borosilicate glass multiphase coating with SiB6 addition for fibrous ZrO2 ceramic10.1016/j.ceramint.2016.02.020 ↗
3. High-temperature deformation measurement of the heated front surface of hypersonic aircraft component at 1200 °C using digital image correlation10.1016/j.optlaseng.2019.06.006 ↗
4. Effect of boron on enhancing infrared emissivity of Ni-Cr system coating10.1016/j.infrared.2017.11.031 ↗
5. Microstructure, thermal shock resistance and thermal emissivity of plasma sprayed LaMAl11O19 (M=Mg, Fe) coatings for metallic thermal protection systems10.1016/j.apsusc.2013.01.070 ↗
6. Preparation and investigation of MoSi2/SiC coating with high infrared emissivity at high temperature10.1016/j.surfcoat.2018.12.036 ↗
7. Quantitative evaluation of emission properties and thermal hysteresis in the mid-infrared for a single thin film of vanadium dioxide on a silicon substrate10.1016/j.ijthermalsci.2019.106061 ↗
8. Correlation between in situ structural and optical characterization of the semiconductor-to-metal phase transition of VO2 thin films on sapphire
9. Optical response of multilayer thermochromic VO2 -based structures10.1117/1.JNP.6.061601 ↗
10. Ce/Mn dual-doped LaAlO3 ceramics with enhanced far-infrared emission capability synthesized via a facile microwave sintering method10.1016/j.jallcom.2018.10.049 ↗
11. High emissivity coatings for high temperature application: progress and prospect10.1016/j.tsf.2009.03.175 ↗
12. Flame-spraying synthesis and infrared emission property of Ca2+/Cr3+ doped LaAlO3 microspheres10.1016/j.jeurceramsoc.2015.04.039 ↗
13. Structural, spectroscopic, and dielectric characterizations of Mn-doped 0.67BiFeO3-0.33BaTiO3 multiferroic ceramics10.1007/s40145-013-0068-7 ↗
14. Ca2+-doped LaCrO3: a novel energy-saving material with high infrared emissivity10.1111/jace.13161 ↗
15. Synthesis and microstructures of La1−xCaxCrO3 perovskite powders for optical properties10.1007/s10854-018-00623-z ↗
16. Frequency and temperature dependent electrical and dielectric properties of LaCrO3 and Ir doped LaCrO3 perovskite compounds10.1016/j.jallcom.2018.01.022 ↗
17. Energetics of La1−xAxCrO3−δ perovskites (A=Ca or Sr)10.1016/j.jssc.2004.11.028 ↗
18. The effect of microstructure on the middle and short waveband emissivity of CuO-doped CuxCo1-xFe2O4 spinel10.1016/j.jallcom.2019.02.119 ↗
19. Thermo-optical properties of LaMg1−xNixAl11O19 (0≤x≤1) hexaaluminates for metallic thermal protection system10.1016/j.matlet.2011.05.093 ↗
20. Effect of calcination temperature on the structural characteristics and catalytic activity for propene combustion of sol–gel derived lanthanum chromite perovskite10.1016/j.apcata.2007.05.015 ↗
21. Effect of Ca2+ and Mn2+ ions on the radiation properties of LaAlO310.1016/j.ceramint.2018.08.036 ↗