journal article·2022-04Open access

Investigation of frequency-dependent dielectric properties of ZnO nanorods grown on Si wafer: In/ZnO/p-Si heterostructure

A. Al-Khafaji, N. Soylu-Koc, S. P. Altintas, M. Dogruer, C. Altug, M. Gokcen, A. Varilci

Abstract

We report the result of an in-depth study of growth, structural properties and frequency-dependent dielectric function of ZnO nanorods (NRs) grown on p-Si as well as the In/ZnO/p-Si heterostructures. The NRs were produced by hydrothermal method on the Si substrate in a Teflon-lined stainless-steel cover at 90 degrees C. Scanning electron microscopy analysis indicates nanorod morphology while LeBail refinement of XRD data showed that the ZnO NRs crystallize in hexagonal wurtzile structure with (002) orientation (space group P6(3)mc). The dielectric properties of the In/ZnO/p-Si heterostructure were calculated with the help of experimental admittance measurements performed in the +/- 5 V voltage range and 1 kHz/1 MHz frequency range under ambient conditions. The real part of the complex relative permittivity (epsilon '), the imaginary part of complex relative permittivity (epsilon '') and loss tangent (tan delta) were obtained. Also, real (M ') and imaginary (M '') parts of the complex electric modulus (M*) were extracted. Frequency dependence in the epsilon ', epsilon '' and tan delta was attributed to the frequency dependence of the space charge polarization. The real part of electrical modulus was found to be nearly independent of frequency and voltage for positive voltages.
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Research context

OpenAlex topics: ZnO doping and properties · Acoustic Wave Resonator Technologies · Dielectric properties of ceramics

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References (45)

Show source-provided references
1. T. Yasuda, Y. Obata, M. Sato, Y. Segawa, Epitaxial growth of ZnO by sol–gel method. J. Korean Phys. Soc. 53, 2921–2924 (2008)10.3938/jkps.53.2921 ↗
2. M. Jouya, F. Taromian, S. Siami, Rapid growth of zinc oxide nanobars in presence of electric field by physical vapor deposition. J. Theor. Appl. Phys. 11, 291–299 (2017)10.1007/s40094-017-0270-z ↗
3. B. Akın, Ş Altındal, On the frequency and voltage-dependent main electrical parameters of the Au/ZnO/n-GaAs structures at room temperature by using various methods. Phys. B Condens. Matter 594, 412274 (2020)10.1016/j.physb.2020.412274 ↗
4. A. Nikravan, Y. Badali, Ş Altındal, I. Uslu, I. Orak, On the frequency and voltage-dependent profiles of the surface states and series resistance of Au/ZnO/n-Si structures in a wide range of frequency and voltage. J. Electron. Mater. 46, 5728–5736 (2017)10.1007/s11664-017-5613-7 ↗
5. A. Baez-Rodriguez, L. Zamora-Peredo, M.G. Soriano-Rosales, J. Hernandez-Torres, L. Garcia-Gonzalez, R.M. Calderon-Olvera, M. Garcia-Hipolito, J. Guzman-Mendoza, C. Falcony, ZnO nanocolumns synthesized by chemical bath process and spray pyrolysis: ultrasonic and mechanical dispersion of ZnO seeds and their effect on optical and morphological properties. J. Lumin. 218, 116830 (2020)10.1016/j.jlumin.2019.116830 ↗
6. G. Kaur, A. Mitra, K.L. Yadav, Pulsed laser deposited Al-doped ZnO thin films for optical applications. Prog Nat. Sci. Mater. 25, 12–21 (2015)10.1016/j.pnsc.2015.01.012 ↗
7. Y. Yan, K.S. Ahn, S. Shet, T. Deutsch, M. Huda, S.H. Wei, J. Turner, M.M. Al-Jassim, Band gap reduction of ZnO for photoelectrochemical splitting of water. So. Hydrogen Nanotechnol. 6650, 66500H–66500H1 (2007)10.1117/12.734950 ↗
8. M. Poloju, N. Jayababu, M.V. Ramana, Reddy, Improved gas sensing performance of Al doped ZnO/CuO nanocomposite based ammonia gas sensor. Mater. Sci. Eng. B Solid-State Mater. Adv. Technol. 227, 61–67 (2018)10.1016/j.mseb.2017.10.012 ↗
9. C. Huo, Y. Lu, H. Zeng, P. Cao, S. Han, W. Liu, F. Jia, Y. Zeng, X. Liu, W. Xu, D. Zhu, Facile approaches to prepare n-ZnO/(i-ZnO)/p-GaN heterojunction light-emitting diodes with white-light-electroluminescence. Appl. Phys. Express 12, 121004 (2019)10.7567/1882-0786/ab50de ↗
10. B.Y. Oh, M.C. Jeong, T.H. Moon, W. Lee, J.M. Myoung, J.Y. Hwang, D.S. Seo, Transparent conductive Al-doped ZnO films for liquid crystal displays. J. Appl. Phys. 99, 124505 (2006)10.1063/1.2206417 ↗
11. T. Li, H.M. Fan, J.M. Xue, J. Ding, Synthesis of highly-textured ZnO films on different substrates by hydrothermal route. Thin Solid Films 518, E114–E117 (2010)10.1016/j.tsf.2010.03.097 ↗
12. J. Yang, J. Zheng, H. Zhai, X. Yang, L. Yang, Y. Liu, J. Lang, M. Gao, Oriented growth of ZnO nanostructures on different substrates via a hydrothermal method. J. Alloys Compd. 489, 51–55 (2010)10.1016/j.jallcom.2009.08.159 ↗
13. E. Asikuzun, O. Ozturk, Comparison of theoretical and experimental microhardness of tetrahedral binary Zn1–xErxO semiconductor polycrystalline nanoparticles. Ceram. Int. 45, 4176–4183 (2019)10.1016/j.ceramint.2018.11.086 ↗
14. M. Mekhnache, A. Drici, L. Saad Hamideche, H. Benzarouk, A. Amara, L. Cattin, J.C. Bernède, M. Guerioune, Properties of ZnO thin films deposited on (glass, ITO and ZnO:Al) substrates. Superlattices Microstruct. 49, 510–518 (2011)10.1016/j.spmi.2011.02.002 ↗
15. Y. Liu, C. Xu, J. Lu, Z. Zhu, Q. Zhu, A.G. Manohari, Z. Shi, Template-free synthesis of porous ZnO/Ag microspheres as recyclable and ultra-sensitive SERS substrates. Appl. Surf. Sci. 427, 830–836 (2018)10.1016/j.apsusc.2017.07.229 ↗
16. V. Khomchenko, M. Sopinskyy, M. Mazin, V. Dan’ko, O. Lytvyn, Y. Piryatinskii, The violet luminescence band in ZnO and ZnO–Ag thin films. J. Lumin. 213, 519–524 (2019)10.1016/j.jlumin.2019.04.045 ↗
17. A.D. Mauro, M.E. Fragalà, V. Privitera, G. Impellizzeri, ZnO for application in photocatalysis: from thin films to nanostructures. Mater. Sci. Semiconduct. Process. 69, 44–51 (2017)10.1016/j.mssp.2017.03.029 ↗
18. V. Corral Flores, S. Braza, T.M. Christensen, A. Glushchenko, Synthesis of zinc oxide microrod arrays and their performance as piezo-generators. Mater. Technol. 33, 575–581 (2018)10.1080/10667857.2018.1481006 ↗
19. X.X. Zhang, S.Y. Wei, L.X. Zhang, E.L. Wang, Nano-ZnO film for field emission lighting tube. In: 24th International Vacuum Nanoelectronics Conference, (2011)
20. H. Kim, S. Choi, Growth of sheet-like ZnO nanostructures on ZnO nano rods using chemical bath deposition. Appl. Sci. Converg Technol. 27, 38–41 (2018)10.5757/ASCT.2018.27.2.38 ↗
21. B. Ismail, M. Abaab, B. Rezig, Structural and electrical properties of ZnO films prepared by screen printing technique. Thin Solid Films 383, 92–94 (2001)10.1016/S0040-6090(00)01787-9 ↗
22. J.H. Zhang, G.Y. Zhao, Y.P. Li, T.T. Ai, C.B. Wu, J.Q. Jia, F.X. Yan, Y.W. Wang, Study on the electrical properties of nano ZnO/PET-ITO heterojunction prepared by hydrothermal method. J. Electron. Spectrosc. Relat. Phenom. 235, 68–72 (2019)10.1016/j.elspec.2019.04.006 ↗
23. A. Atilgan, A. Yildiz, U. Harmanci, M.T. Gulluoglu, Salimi, β-Ga2O3 nanoflakes/p-Si heterojunction self-powered photodiodes. Mater. Today Commun. 24, 101105 (2020)10.1016/j.mtcomm.2020.101105 ↗
24. M. Yıldırım, A. Kocyigit, Characterization of Al/In:ZnO/p-Si photodiodes for various In doped level to ZnO interfacial layers. J. Alloys Compd. 768, 1064–1075 (2018)10.1016/j.jallcom.2018.07.295 ↗
25. A. Yildiz, A.A. Alsaç, T. Serin, N. Serin, The change in the electrical transport mechanism from the grain boundary conduction to the nearest-neighbor hopping conduction in SnO2. J. Mater. Sci: Mater. Electron. 22, 872–875 (2011)
26. K. Ozel, A. Yildiz, SnO2/ZnO/p-Si and SnO2/TiO2/p-Si heterojunction UV photodiodes prepared using a hydrothermal method. Sens. Actuators A Phys. 315, 112351 (2020)10.1016/j.sna.2020.112351 ↗
27. X. Zhao, D. Huang, Y. He, W. Peng, G. Li, Demonstration of an n-ZnO/p-Si/n-Si heterojunction bipolar phototransistor for X-ray detection. Solid State Electron. 188, 108221 (2022)10.1016/j.sse.2021.108221 ↗
28. V. Petricek, M. Dusek, L. Palatinus, The Crystallographic Computing System (Institute of Physics, Praha, 2006)
29. S.B. Mullani, A.G. Dhodamani, A. Shellikeri, N.B. Mullani, A.K. Tawade, S.N. Tayade, J. Biscay, L. Dennany, S.D. Deleka, Structural refnement and electrochemical properties of one dimensional (ZnO NRs)1–x(CNs)x functional hybrids for serotonin sensing studies. Sci. Rep. 10, 15955 (2020)10.1038/s41598-020-72756-3 ↗
30. S.Y. Bae, H.W. Seo, H.C. Choi, J. Park, Heterostructures of ZnO nanorods with various one-dimensional nanostructures. J. Phys. Chem. B 108, 12318–12326 (2004)10.1021/jp048918q ↗
31. L. Guo, Y.L. Ji, H. Xu, P. Simon, Z. Wu, Regularly shaped, single-crystalline ZnO nanorods with wurtzite structure. J. Am. Chem. Soc. 124, 14864–14865 (2002)10.1021/ja027947g ↗
32. B. Panigrahy, M. Aslam, D. Bahadur, Aqueous synthesis of Mn-and Co-doped ZnO nanorods. J. Phys. Chem. C 114, 11758–11763 (2010)10.1021/jp102163b ↗
33. T.H. De Keiyser, J.I. Langford, E.J. Mittemeijer, A.B.P. Vogels, Use of the Voigt function in a single-line method for the analysis of X-ray diffraction line broadening. J. Appl. Cryst. 15, 314 (1982)
34. P.E. Tomaszewski, The uncertainty in the grain size calculation from X-ray diffraction data. Phase Transit. 86, 260–266 (2013)10.1080/01411594.2012.715301 ↗
35. C.A. Schneider, W.S. Rasband, K.W. Eliceiri, NIH Image to ImageJ: 25 years of image analysis. Nat. Methods 9, 671–675 (2012)10.1038/nmeth.2089 ↗
36. Y. Badali, Ş Altındal, I. Uslu, Dielectric properties, electrical modulus and current transport mechanisms of Au/ZnO/n-Si structures. Prog. Nat. Sci. Mater. Int. 28, 325–331326 (2018)10.1016/j.pnsc.2018.05.003 ↗
37. K.S. Cole, R.H. Cole, Dispersion and absorption in dielectrics I. Alternating current characteristics. J. Chem. Phys. 9, 341 (1941)10.1063/1.1750906 ↗
38. C.P. Smith, Dielectric behavior and structure (McGraw Hill, N.Y., 1955)
39. M. Gokcen, S. Bal, G. Yildirim, M. Gulen, A. Varilci, Morphological, microstructural and electrical examinations on ZnO film on p-Si wafer. J. Mater. Sci. Mater. Electron. 23, 1971–1979 (2012)10.1007/s10854-012-0690-0 ↗
40. A. Molak, M. Paluch, S. Pawlus, J. Klimontko, Z. Ujma, I. Gruszka, Electric modulus approach to the analysis of electric relaxation in highly conducting (Na0.75Bi0.25)(Mn0.25Nb0.75)O-3 ceramics. J. Phys. D Appl. Phys. 38, 1450–1460 (2005)10.1088/0022-3727/38/9/019 ↗
41. M. Gökçen, T. Tunç, Enhancement of dielectric characteristics of polyvinyl alcohol (PVA) interfacial layer in Au/PVA/n-Si structures by Bi2O3 disperse Int. J. Appl. Ceram. Technol. 10, E64–E69 (2013)10.1111/ijac.12009 ↗
42. R. Tripathi, A. Kumar, C. Bharti, T.P. Sinha, Dielectric relaxation of ZnO nanostructure synthesized by soft chemical method. Curr. Appl. Phys. 10, 676–681 (2010)10.1016/j.cap.2009.08.015 ↗
43. A.K. Bhunia, S.S. Pradhan, K. Bhunia et al., Study of the optical properties and frequency-dependent electrical modulus spectrum to the analysis of electric relaxation and conductivity effect in zinc oxide nanoparticles. J. Mater. Sci. Mater. Electron. 32, 22561–22578 (2021). https://doi.org/10.1007/s10854-021-06742-410.1007/s10854-021-06742-4 ↗
44. M. Soosen Samuel, J. Koshy, A. Chandran, K.C. George, Dielectric behavior and transport properties of ZnO nanorods. Phys. B Condens. Matter 406(15–16), 3023–3029 (2011)10.1016/j.physb.2011.04.070 ↗
45. L. Yao, S. Wu, Z. Pan, Y. Tan, F. Pi, R. Wang, J. Zhai, H.H.D. Chen, Enhancement of energy density in novel Ba0.67Sr0.33TiO3 nanorod array nanocomposites. Mater. Design 195, 109044 (2020)10.1016/j.matdes.2020.109044 ↗