journal article·2019-11

Influence of annealing temperature on morphological and photocatalytic activity of sputter-coated CaCu3Ti4O12 thin film under ultraviolet light irradiation

Mohsen Ahmadipour, Mohammad Arjmand, Siti Nor Qurratu Aini Abd Aziz, Sin Ling Chiam, Zainal Arifin Ahmad, Swee-Yong Pung

Ceramics International· Volume 45· Issue 16
Publisher page

Abstract

Abstract CaCu3Ti4O12 (CCTO) thin films were deposited by radio frequency (RF) magnetron sputtering and subsequently annealed at 300, 400, 500, or 600 °C. The XRD analysis showed that the amorphous CCTO thin film transformed to more crystallite structure as the annealing temperature increased to 600 °C. Generally, the average crystallite size, grain size and roughness of the thin films increased with increasing annealing temperature. Photocatalytic activities of these thin films were evaluated by the effectiveness of Rhodamine B (RhB–C28H31ClN2O3) removal from solution under ultraviolet (UV) light illumination. In particular, the CCTO thin film annealed at 600 °C exhibited the highest photocatalytic activity, where it removed 67.4% of RhB dye in 4 h, at a rate constant of 0.217 min−1. This observation was ascribed to its higher crystallinity and larger grain size of CCTO thin film annealed at 600 °C.
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Research context

OpenAlex topics: Dielectric properties of ceramics · Advanced Photocatalysis Techniques

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