Synthesis of coral-shaped yttrium-aluminium-iron garnets by solution-combustion method

Aluminium substituted yttrium-iron garnet (Y 3 Al x Fe 5-x O 12 , x = 0, 1, 2, 3, 4 and 5) powders were synthesized by the solution combustion route followed by calcination at 1000 °C for 6 h. According to the X-ray diffraction (XRD) results, the as-prepared samples were amorphous. Calcination of the samples at 1000 °C for 6 h results in the formation of phase pure ( Ia 3 d ) garnet structure. The morphology of the samples (for all compositions) were found to be coral-network-like. The Rietveld refinement of the XRD patterns and the Mossbauer spectroscopy confirmed that Y 3+ ions occupy the dodecahedral site, whereas Al 3+ and Fe 3+ ions are distributed in the tetrahedral and octahedral sites of the bcc ( Ia 3 d ) structure of the garnet phase. The Al 3+ ions have a preference to occupy the octahedral site. The lattice parameter decreases with increase in Al 3+ content due to the small size of the Al 3+ cations. For the yttrium-iron-garnet (YIG) sample (x = 0), a saturation magnetization (M S ) value of ~ 29 emu/g was obtained, which decreases to ~ 7 emu/g for the sample with x = 2. Further addition of Al makes the garnets paramagnetic. The coral network shape of our garnet samples renders them useful for various applications in catalysis.