journal article·2021-12

Effects of fly ash, phosphoric acid, and nano-silica on the properties of magnesium oxychloride cement

Qing Huang, Weixin Zheng, Xueying Xiao, Jinmei Dong, Jing Wen, Chenggong Chang

Ceramics International· Volume 47· Issue 24
Publisher page

Abstract

Abstract This study investigates the effects of fly ash, phosphoric acid, nano-silica additives on the hydration process, setting time, compressive strength, water resistance, and thermal stability of magnesium oxychloride cement (MOC). MOC samples incorporating different combinations of additives are prepared, and their hydration products and microstructures are studied via X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), thermogravimetry-differential scanning calorimetry (TGA-DSC), and scanning electron microscopy (SEM). Results indicate that the addition of nano-silica to MOC containing fly ash and phosphoric acid reduces initial and final setting times, decreases the thermal stability, and increases compressive strength. Furthermore, the water resistance of modified MOC pastes is significantly improved through the combined use of additives. Hydration mechanisms arising in MOC are elucidated, and the remarkable enhancement of water resistance is attributed to secondary hydration of the 5 Mg(OH)2·MgCl2·8H2O (5·1·8 phase) and the formation of amorphous gel facilitated by nano-silica inclusion.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Magnesium Oxide Properties and Applications · Concrete and Cement Materials Research · Recycling and utilization of industrial and municipal waste in materials production

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

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