Photoluminescence and semiconducting behavior of Fe, Co, Ni and Cu implanted in heavy metal oxide glasses
Source abstract
Abstract
Transition metal ions (0.5 wt%) of Fe2O3, CoO, NiO or CuO doped heavy metal oxide glasses having chemical composition of 60PbO·20Bi2O3·20 MxOy mol% (where MxOy = B2O3 or SiO2 or P2O5) were prepared by conventional melt annealing method. Combined optical and photoluminescence properties have been measured and employed to evaluate the prepared glassy samples. From the absorption edge data, the values of the optical band gap Eopt, Urbach energy (ΔE) and refractive index were calculated to estimate semiconducting behavior. Photoluminescence and values of the optical energy gap were found to be dependent on the glass composition. The variations of the photoluminescence intensity, values of optical band gap, Urbach energy and refractive index gave an indication to use the prepared glasses for design of novel functional optical materials with higher optical performance.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Glass properties and applications · Luminescence Properties of Advanced Materials · Surface Roughness and Optical Measurements
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (39)
Show source-provided references
1. Optical band gap and IR spectra of glasses in the system [Nd2O3](x)–[CuO](35−x)–[P2O5](65)
2. Gamma rays interaction with bismuth borate glasses doped by transition metal ions10.1007/s10853-011-5445-4 ↗
3. Spectroscopic studies and luminescence spectra of dy2O3 doped lead phosphate glasses10.1007/s12633-012-9125-z ↗
4. Effect of optical basicity on broadband infrared fluorescence in bismuth-doped alkali metal germanate glasses10.1016/j.optmat.2008.10.039 ↗
5. Near infrared broadband emission of bismuth-doped aluminophosphate glass10.1364/OPEX.13.001628 ↗
6. A new family of lead–bismuthate glass with a large transmitting window10.1016/S0022-3093(00)00111-3 ↗
7. Optical investigation and electronic polarizability of Nd3+ doped soda-lime-silicate glasses10.3844/erjsp.2010.176.181 ↗
8. Mott · 1979 · 289
9. Sze · 2007
10. Colour generation and control in glass
11. The long-wavelength edge of photographic sensitivity and of the electronic absorption of solids10.1103/PhysRev.92.1324 ↗
12. Electronic oxide polarizability and optical basicity of simple oxides I10.1063/1.360962 ↗
13. Integration between optical and structural behavior of heavy metal oxide glasses doped with multiple glass formers10.1007/s12633-015-9342-3 ↗
14. Gamma ray interaction with copper-doped sodium phosphate glasses10.1007/s10853-007-2254-x ↗
15. UV–visible and infrared absorption spectra of gamma irradiated CuO-doped lithium phosphate, lead phosphate and zinc phosphate glasses: a comparative study10.1016/j.physb.2011.06.074 ↗
16. Effect of gamma radiation on ultraviolet, visible and infrared studies of NiO, Cr2O3 and Fe2O3-doped alkali borate glasses10.1016/j.jnoncrysol.2013.04.052 ↗
17. UV–visible and infrared spectra of gamma-irradiated transition metals-doped lead borate glasses10.1080/0371750X.2009.11082162 ↗
18. Optical characterization of some rare earth ions doped bismuth borate glasses and effect of gamma irradiation10.1016/j.molstruc.2012.03.041 ↗
19. Characterization of Fe3+ doped mixed alkali zinc borate glasses – physical and spectroscopic investigations10.1016/j.jnoncrysol.2013.01.023 ↗
20. Optical and FT infrared absorption spectra of 3d transition metal ions doped in NaF–CaF2–B2O3 glass and effects of gamma irradiation10.1155/2014/389543 ↗
21. Spectral analysis of Mn2+, Co2+ and Ni2+: B2O3–ZnO–PbO glasses10.1016/j.saa.2005.05.013 ↗
22. Local structure of Ni2+ ions in fluorochloro- and fluorobromo-zirconate glasses10.1063/1.478224 ↗
23. Ligand field theory and absorption spectra of transition metal ions in glasses
24. Synthesis and characterization of undoped and Fe(III) ions doped NaCaAlPO4F3 phosphor10.1016/j.jlumin.2013.07.052 ↗
25. Optical characterization of Mn2+, Ni2+ and Co2+ ions doped zinc lead borate glasses10.1016/j.jqsrt.2006.02.006 ↗
26. Absorption and photoluminescence characteristics of Co2+P:MgAl2O4 nanocrystals embedded in sol–gel derived SiO2-based glass10.1016/S0925-3467(03)00227-1 ↗
27. Influence of ligand coordination of cobalt ions on structural properties of ZnO–ZnF2–B2O3 glass system by means of spectroscopic studies10.1016/j.physb.2011.12.007 ↗
28. Energy levels and photoluminescence properties of nickel-doped bismuth ferrite10.1016/j.jallcom.2010.05.107 ↗
29. Optical and other spectroscopic studies of lead, zinc bismuth borate glasses doped with CuO10.1016/j.physb.2011.08.082 ↗
30. Effect of CuO addition on the optical and electrical properties of sodium zinc borophosphate glasses10.1016/j.physb.2011.04.063 ↗
31. Luminescence characteristics of Cu- and Eu-doped Li2B4O710.1016/j.radmeas.2004.01.011 ↗
32. Optical characterization of Cu2+ ion-doped zinc lead borate glasses10.1016/j.jqsrt.2005.04.006 ↗
33. SpectralstudiesonCu2+ ions in sodium–lead borophosphate glasses10.1016/j.physb.2012.09.010 ↗
34. A study of the optical bandgap energy and Urbach tail of spray-deposited CdS:In thin films10.1016/j.jmrt.2013.02.012 ↗
35. Bismuth oxide and bismuth oxide doped glasses for optical and photonic applications
36. A new study on bismuth doped oxide glasses10.1364/OE.20.015692 ↗
37. Luminescence of Ce doped MgAl2O4 prepared by the combustion method10.1016/j.physb.2013.10.060 ↗
38. Spectroscopic studies of transition metal doped sodium phosphate glasses10.1016/S0925-8388(03)00498-5 ↗
39. Luminescence efficiency growth in wide band gap semiconducting Bi2O3 doped Cd0.4Pb0.1B0.5 glasses and effect of γ-irradiation10.1016/j.molstruc.2014.08.022 ↗