journal article·2022-11Open access

Effect of combined lean additions of isomorphous and eutectoid beta stabilisers on the properties of titanium

L. Bolzoni, M. Paul, F. Yang

Abstract

Reduction of the manufacturing cost of titanium and the development of new alloys are crucial to effectively harvest the benefits derived by the use of titanium in industrial applications. Therefore, we considered the creation of new Ti-2X-2Z alloys via the combined lean additions of isomorphous (i.e. Nb) and eutectoid (i.e. Cu, Mn, and Fe) beta stabilisers, and systematically analysed their effect on the manufacturability and mechanical response of titanium produced via powder metallurgy. It is found that the addition of the alloying elements reduces the compressibility of the powder blend but enhances the densification. The microstructure of titanium is transformed into a Widmanstätten structure composed of α grain boundaries and α+β lamellae where the stronger the beta stabilisers the more refined the microstructural features, and no intermetallic phases are precipitated despite the use of eutectoid stabilisers. Consequently, the combined addition of isomorphous and eutectoid beta stabilisers has a significant effect on the mechanical response with the material becoming stronger, harder and less tough with the increment of the potency of the added beta stabilisers; however, the Ti-2X-2Z alloys share similar strengthening mechanisms. A more accurate theoretical equation for developing titanium alloys through the molybdenum equivalent parameter should be developed.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Titanium Alloys Microstructure and Properties · Advanced materials and composites · Intermetallics and Advanced Alloy Properties

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (63)

Show source-provided references
1. The technologies of titanium powder metallurgy
2. Assessment of the influence of Al-2Nb-2B master alloy on the grain refinement and properties of LM6 (A413) alloy10.1016/j.msea.2015.01.053 ↗
3. The ω phase transformation during the low temperature aging and low rate heating process of metastable β titanium alloys10.1016/j.matchemphys.2019.122125 ↗
4. Influence of vacuum hot-pressing temperature on the microstructure and mechanical properties of Ti-3Al-2.5V alloy obtained by blended elemental and master alloy addition powders10.1016/j.matchemphys.2012.10.010 ↗
5. Morinaga · 1988 · vol. III · 1601
6. Alloy design based on molecular orbital method10.2320/matertrans.M2015418 ↗
7. Beta titanium alloys and their role in the titanium industry
8. Structural stabilities of β-Ti alloys studied using a new Mo equivalent derived from [β/(α + β)] phase-boundary slopes10.1007/s11661-015-2923-3 ↗
9. Cytotoxicity of pure metals
10. Investigation of the factors influencing the tensile behaviour of PM Ti-3Al-2.5V alloy10.1016/j.msea.2014.05.017 ↗
11. Effect of Nb on the microstructure, mechanical properties, corrosion behavior, and cytotoxicity of Ti-Nb alloys10.3390/ma8095287 ↗
12. Structure-property relationship of cast Ti-Nb alloys10.1046/j.1365-2842.2002.00825.x ↗
13. Microstructure and dry wear properties of Ti-Nb alloys for dental prostheses10.1016/S1003-6326(10)60124-0 ↗
14. Mechanical properties and grindability of dental cast Ti-Nb alloys10.4012/dmj.22.328 ↗
15. Microstructure and mechanical behavior of metal injection molded Ti-Nb binary alloys as biomedical material10.1016/j.jmbbm.2013.08.013 ↗
16. Metallurgical properties and biomimetic HA deposition performance of Ti-Nb PIM alloys10.1016/j.jallcom.2018.02.274 ↗
17. Microstructure and mechanical properties of Ti-Nb alloys prepared by mechanical alloying and spark plasma sintering10.1007/s11665-019-04417-0 ↗
18. Wear resistance of experimental Ti-Cu alloys10.1016/S0142-9612(03)00157-1 ↗
19. Microstructure and properties of burn-resistant Ti-Al-Cu alloys10.1023/A:1004873501005 ↗
20. Mechanical properties and microstructures of cast Ti-Cu alloys10.1016/S0109-5641(02)00027-1 ↗
21. Optimization of mechanical properties, biocorrosion properties and antibacterial properties of as-cast Ti-Cu alloys10.1088/1748-6041/11/6/065001 ↗
22. Antibacterial Ti-Cu alloy with enhanced mechanical properties as implant applications10.1088/2053-1591/abc371 ↗
23. Effect of the existing form of Cu element on the mechanical properties, bio-corrosion and antibacterial properties of Ti-Cu alloys for biomedical application10.1016/j.msec.2016.08.033 ↗
24. Optimization of mechanical property, antibacterial property and corrosion resistance of Ti-Cu alloy for dental implant10.1016/j.jmst.2019.03.044 ↗
25. Effect of extrusion processing on the microstructure, mechanical properties, biocorrosion properties and antibacterial properties of Ti-Cu sintered alloys10.1016/j.msec.2016.07.051 ↗
26. Effect of Cu content on the antibacterial activity of titanium-copper sintered alloys10.1016/j.msec.2013.11.028 ↗
27. Low-cost powder metallurgy Ti-Cu alloys as a potential antibacterial material10.1016/j.jmbbm.2019.04.004 ↗
28. The effect of α+ β forging on the mechanical properties and microstructure of binary titanium alloys produced via a cost-effective powder metallurgy route10.1016/j.msea.2019.138496 ↗
29. Effect of cooling process on the alpha phase formation and mechanical properties of sintered Ti-Fe alloys10.1016/j.msea.2011.02.092 ↗
30. Hybrid microwave sintering of blended elemental Ti alloys10.1016/j.jmapro.2019.02.002 ↗
31. Thermomechanically processed powder metallurgy Ti-5Fe alloy: effect of microstructure, texture, Fe partitioning and residual porosity on tensile and fatigue behaviour10.1016/j.mtla.2021.101254 ↗
32. Thermomechanical processing of cost-affordable powder metallurgy Ti-5Fe alloys from the blended elemental approach: microstructure, tensile deformation behavior, and failure10.3390/met10111405 ↗
33. Improved mechanical, bio-corrosion properties and in vitro cell responses of Ti-Fe alloys as candidate dental implants10.1016/j.msec.2021.111917 ↗
34. Sintered Ti-Fe alloys with in situ synthesized TiC dispersoids10.1016/j.msea.2012.02.007 ↗
35. PM processing and characterisation of Ti-7Fe low cost titanium alloys10.1179/174329009X457063 ↗
36. Effect of Mn-content on the deformation behavior of binary Ti-Mn alloys10.4028/www.scientific.net/KEM.705.214 ↗
37. Mechanical properties, microstructures, and biocompatibility of low-cost β-type Ti-Mn alloys for biomedical applications
38. Fabrication of low-cost beta-type Ti-Mn alloys for biomedical applications by metal injection molding process and their mechanical properties10.1016/j.jmbbm.2016.02.035 ↗
39. Effect of manganese on the microstructure, mechanical properties and corrosion behavior of titanium alloys10.1016/j.matchemphys.2016.06.016 ↗
40. Mechanical properties and microstructures of dental cast Ti-6Nb-4Cu, Ti-18Nb-2Cu, and Ti-24Nb-1Cu alloys10.4012/dmj.2015-354 ↗
41. Localised corrosion behaviour of biomedical implant materials using electrochemical potentiokinetic reactivation and critical pitting potential methods, corrosion engineering
42. Construction of Ti-Nb-Ti2Cu pseudo-ternary phase diagram10.4012/dmj.2018-394 ↗
43. Microstructures and mechanical properties of Mn modified, Ti-Nb-based alloys10.1016/j.jallcom.2017.06.311 ↗
44. Microstructure, phase composition and mechanical properties of new, low cost Ti-Mn-Nb alloys for biomedical applications10.1016/j.jallcom.2019.02.116 ↗
45. Structure and mechanical properties of as-cast Ti-5Nb-xFe alloys10.1016/j.matchar.2010.05.003 ↗
46. Phase transition, microstructural evolution and mechanical properties of Ti-Nb-Fe alloys induced by Fe addition10.1016/j.matdes.2016.02.094 ↗
47. Influence of Nb on the β→α″ martensitic phase transformation and properties of the newly designed Ti-Fe-Nb alloys10.1016/j.msec.2015.11.072 ↗
48. Evaluation of mechanical and wear properties of TixNb7Fe alloys designed for biomedical applications10.1016/j.matdes.2016.09.029 ↗
49. Effect of rapid solidification on microstructure and elastic modulus of β Ti-xNb-3Fe alloys for implant applications10.1002/adem.201600370 ↗
50. Effect of Nb content on microstructures and mechanical properties of Ti-xNb-2Fe alloys10.1007/s11665-019-04250-5 ↗
51. Solute lean Ti-Nb-Fe alloys: an exploratory study10.1016/j.jmbbm.2016.09.024 ↗
52. Beta titanium alloys produced from titanium hydride: effect of alloying elements on titanium hydride decomposition10.3390/met10050682 ↗
53. Development of high modulus Ti-Fe-Cu alloys for biomedical applications10.2320/matertrans.M2012361 ↗
54. Ti-Based nanostructured low-alloy with high strength and ductility10.1016/j.msea.2012.04.097 ↗
55. Electrochemical behavior and biocompatibility of Ti-Fe-Cu alloy with high strength and ductility10.1016/j.jallcom.2016.11.213 ↗
56. Thixoforming of titanium: the microstructure and processability of semisolid Ti-Cu-Fe alloys10.1016/j.vacuum.2020.109567 ↗
57. Influence of Fe content of Ti-Mn-Fe alloys on phase constitution and heat treatment behavior10.4028/www.scientific.net/MSF.706-709.1893 ↗
58. Advancement in the pressureless sintering of CP titanium using high-frequency induction heating10.1007/s11661-019-05381-z ↗
59. A critical review of mechanical properties of powder metallurgy titanium
60. Ternary Ti alloys functionalised with antibacterial activity10.1038/s41598-020-79192-3 ↗
61. Physics and phenomenology of strain hardening: the FCC case10.1016/S0079-6425(02)00003-8 ↗
62. On the use of considere's criterion in tensile testing of materials which accumulate internal damage10.1016/S1359-6462(99)00159-1 ↗
63. Mechanical and biological properties of Ti-(0-25 wt%)Nb alloys for biomedical implants application10.1093/rb/rbz042 ↗