journal article·2014-04Open access

Scientific and technical aspects of blended cement matrices containing activated slate wastes

M. Frías, R. Vigil de la Villa, R. García, I. de Soto, C. Medina, M.I. Sánchez de Rojas

Abstract

The extraction of slate for use as a construction material generates large quantities of waste (between 75% and 90% in weight), which are dumped on landfill sites, with the ensuing technical, economic, environmental, and social problems. One possible way of reusing this raw waste is through its thermal activation to produce a new cementitious material for the manufacture of eco-efficient cements. An assessment is presented in this study of the chemical, mineralogical and pozzolanic properties of ash waste, activated at 1000 C over 2 h, as well as a study of the main technical properties of blended cements prepared with 10% and 20% slate ash. The results show the high pozzolanic activity of the slate ash, principally over the seven first days, forming CSH gels as a principal hydrated phase of the pozzolanic reaction, followed by randomly interstratified chlorite/smectite phases and monosulfoaluminate [C3A SO4Ca 12H2O]. These blended cements prepared with 10% and 20% activated slate waste comply with both the physical and the mechanical requirements of current European standards.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Concrete and Cement Materials Research · Recycling and utilization of industrial and municipal waste in materials production · Recycled Aggregate Concrete Performance

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (35)

Show source-provided references
1. Recent advances in the field of cement hydration and microstructure analysis10.1016/j.cemconres.2011.03.028 ↗
2. Assessment of pozzolanic activity of different calcined clays10.1016/j.cemconcomp.2013.01.002 ↗
3. Natural and artificial pozzolans in eco-efficient concrete
4. Pozzolanic reaction of a spent fluid catalytic cracking catalyst in FCC-cement mortars10.1007/s10973-006-7921-7 ↗
5. Morphology and properties in blended cements with ceramic wastes as a pozzolanic material10.1111/j.1551-2916.2006.01279.x ↗
6. Chemical assessment of the electric arc furnace slag as construction material: expansive compounds10.1016/j.cemconres.2004.01.029 ↗
7. Increase of reactivity of silica fume by sonication treatment10.1016/j.ultsonch.2012.01.011 ↗
8. A method developed to quantify lime and gypsum consumed by mineral additions10.1016/j.cemconcomp.2012.04.005 ↗
9. Characterization and properties of blended cement matrices containing activated bamboo leaf wastes10.1016/j.cemconcomp.2012.05.005 ↗
10. Metakaolin cementitious material: history, scours, production and composition-A comprehensive overview10.1016/j.conbuildmat.2012.12.001 ↗
11. Reuse of de-inking sludge from wastepaper recycling in cement mortar products10.1016/j.jenvman.2011.03.028 ↗
12. Scientific aspects of kaolinite based coal mining wastes in pozzolan/Ca(OH)2 system10.1111/j.1551-2916.2011.04985.x ↗
13. Properties and performances of concrete tiles containing waste fired clay materials10.1111/j.1551-2916.2007.01944.x ↗
14. Th effect of temperatura on the hydration rate and stability of the hydration phases of Mk-lime-water systems10.1016/j.cemconres.2009.06.010 ↗
15. Evolution of the pozzolanic activity of a thermally treated zeolite10.1007/s10853-012-7101-z ↗
16. La Crónica de León. ; 2012.
17. Engineering properties of concrete made with slate waste10.1680/coma.800062 ↗
18. Reacción del γ-aminopropiltrietoxisilano con partículas de Pizarra10.3989/cyv.2001.v40.i2.1070 ↗
19. The influence of slate waste activation conditions on mineralogical changes and pozzolanic behaviour10.1111/jace.12387 ↗
20. Borg IY, Smith DK. Calculated X ray powder patterns for silica minerals. Geol Soc Am 1969 [memoir 122].10.1130/MEM122-p1 ↗
21. Brindley GW, Brown G. Crystal structures of clay minerals and X ray identification. London: Mineralogical Society Monograph n° 5; 1980.10.1180/mono-5 ↗
22. UNE-EN 197-1. Cement Part 1: Composition, specifications and conformity criteria for common cements; 2011.
23. Determination of specific surface area by the laser diffraction technique. Comparison with the Blaine permeability method10.1016/0008-8846(91)90165-E ↗
24. Parkhurst · 1999
25. Blanc P, Lassin A, Piantone P. Thermoddem a database devoted to waste minerals. Orléans (France): BRGM; 2007. .
26. SUPCRT92: a software package for calculating the standard molal thermodynamic properties of minerals, gases, aqueous species, and reactions from 1 to 5000 bar and 0 to 1000°C10.1016/0098-3004(92)90029-Q ↗
27. UNE EN 196-3. Methods of testing cement. Part 3: Determination of setting time and soundness; 2005.
28. UNE EN 196-1. Methods of testing cement. Part 1: Determination of strength; 2005.
29. Use of recycled copper slag for blended cements10.1002/jctb.1830 ↗
30. Characterization of calcined paper sludge as an environmentally friendly source of MK for manufacture of cementitious materials10.1680/adcr.2008.20.1.23 ↗
31. Taylor HFW. In: Thomas Telford Services Ltd., editor. Cement Chemistry. London: Thomas Telford Publishing; 1997.
32. Rheological and calorimetric behaviour of cements with containing ceramic sanitary ware and construction/demolition waste10.1016/j.conbuildmat.2012.11.112 ↗
33. The influence of thermal activation of art paper sludge on the technical properties of blended Portland cements10.1016/j.cemconcomp.2012.11.005 ↗
34. Effect of activated coal mining wastes on the properties of blended cement10.1016/j.cemconcomp.2012.02.006 ↗
35. Research about the pozzolanic activity of waste materials from calcined Clay10.3989/mc.2001.v51.i261.379 ↗