journal article·2023-07Open access

(La0.2Dy0.2Nd0.2Sm0.2Eu0.2)2GdTaO7: a promising candidate oxides for high-temperature coating applications

Haoming Zhang, Hongsong Zhang, Shuaixia Liu, Xianping Zhang, Xiaoge Chen, Hong Wang, Yinghui Wang, Huanlin Duan, Yongfei Xue

Abstract

In the paper, the (La0.2Dy0.2Nd0.2Sm0.2Eu0.2)2GdTaO7 oxide was prepared employing sol-gel and solid-reaction method. Its crystal-structure, microstructure, element-distribution, mechanical and thermophysical properties are investigated. The analytical conclusions reveal that this high-entropy oxide shows single pyrochlore structure, dense microstructure, and even element distribution. Owing to the strong phonon scattering originated from high-entropy effect and numerous oxygen vacancies, it has low thermal conductivity and ranges from 1.41 to1.27 W/m. K. Its coefficient of thermal expansion is less than those of rare-earth cerium oxides and greater than that of 7YSZ. The Young’s modulus of this high-entropy oxide is in the same order with 7YSZ, its Vickers hardness and fracture-toughness are lower than those of 7YSZ. This high-entropy oxide is also of excellent lattice-stability up to 1200°C.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: High-Temperature Coating Behaviors · Nuclear materials and radiation effects · Nuclear Materials and Properties

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (49)

Show source-provided references
1. Properties evaluation and failure behavior of plasma sprayed Y4Hf3O12 for thermal barrier coating applications10.1016/j.surfcoat.2022.129162 ↗
2. Study of toughening behavior of SiC whiskers on 8YSZ thermal barrier coatings10.1016/j.surfcoat.2023.129232 ↗
3. Molten-volcanic-ash-phobic thermal barrier coating based on biomimetic structure10.1002/advs.202205156 ↗
4. Understanding of degradation-resistant behavior of nanostructured thermal barrier coatings with bimodal structure10.1016/j.jmst.2018.09.054 ↗
5. Failure mechanisms, and structure tailoring of YSZ and new candidates for thermal barrier coatings: a systematic review
6. Mechanical properties of high-temperature-degraded yttria-stabilized zirconia10.1016/j.actamat.2014.01.017 ↗
7. CMAS corrosion behavior and protection method of thermal barrier coatings for aeroengine
8. High heat flux burner-rig testing of 8YSZ thermal barrier coatings: influence of the powder feedstock10.1016/j.jeurceramsoc.2022.07.049 ↗
9. Structural and thermal-mechanical properties of Ln3Ta5O15 (Ln=Ce, Pr, Nd, Sm, Eu, Gd, Tb) for thermal barrier coatings10.1016/j.commatsci.2022.111938 ↗
10. Effects of pellet surface roughness and pre-oxidation temperature on CMAS corrosion behavior of Ti2AlC10.1007/s40145-022-0588-0 ↗
11. Thermal expansion and fracture toughness of (RE0.9Sc0.1)2Zr2O7 (RE=La, Sm, Dy, Er) ceramics10.1016/j.ceramint.2015.08.151 ↗
12. Preparation and thermos-physical properties of La2AlTaO7 ceramic for thermal barrier coating application10.1016/j.matchemphys.2022.126465 ↗
13. Preparation and thermophysical properties of RE2CrTaO7 (Y, Sm, Dy, Yb) ceramics for thermal barrier coating applications10.1016/j.ceramint.2022.05.036 ↗
14. Potential thermal barrier coating materials: RE2FeTaO7 (RE=Y, Eu, Gd, Dy) compounds10.1016/j.jallcom.2020.157408 ↗
15. Thermal and oxygen transport properties of complex pyrochlore RE2InTaO7 for thermal barrier coating applications10.1016/j.jeurceramsoc.2020.06.027 ↗
16. Synthesis and thermophysical performances of (Nd1-xYbx)2AlTaO7 oxides for heat-insulation coating applications10.1016/j.ceramint.2020.07.149 ↗
17. Thermal conductivity and expansion coefficient of Ln2LaTaO7 (Ln=Er and Yb) oxides for thermal barrier coating applications10.1016/j.ceramint.2016.05.141 ↗
18. Thermal barrier coatings with high-entropy oxide as a top coat10.1016/j.ceramint.2021.09.219 ↗
19. High-entropy ceramics: present status, challenges, and a look forward10.1007/s40145-021-0477-y ↗
20. Multicomponent rare-earth cerate and zirconate ceramics for thermal barrier coating materials10.1016/j.jeurceramsoc.2020.10.005 ↗
21. Ultrafast high-temperature sintering of high-entropy (La0.2Nd0.2Sm0.2Eu0.2Gd0.2)2Hf2O7 ceramics with fluorite structure10.1016/j.ceramint.2022.09.041 ↗
22. High-entropy rare-earth zirconate ceramics with low thermal conductivity for advanced thermal-barrier coatings10.1007/s40145-022-0589-z ↗
23. High-entropy perovskite RETa3O9 ceramics for high-temperature environmental/thermal barrier coatings10.1007/s40145-021-0556-0 ↗
24. High-entropy (La0.2Nd0.2Sm0.2Eu0.2Gd0.2)2Ce2O7: a potential thermal barrier material with improved thermos-physical properties10.1007/s40145-021-0563-1 ↗
25. Thermal properties of (Zr0.2Ce0.2Hf0.2Y0.2RE0.2)O1.8 thermal barrier materials10.1016/j.ceramint.2022.08.122 ↗
26. High-entropy titanate pyrochlore as newly low-thermal conductivity ceramics10.1016/j.jeurceramsoc.2022.07.006 ↗
27. High entropy defective fluorite structured rare-earth niobates and tantalates for thermal barrier applications10.1007/s40145-020-0368-7 ↗
28. Influences of Al2O3 addition on the thermophysical properties of AlMO4 (M=Ta, Nb) ceramics10.1016/j.ceramint.2022.08.057 ↗
29. Structure and thermal properties of Al2O3-doped Gd3TaO7 as potential thermal barrier coating10.1016/j.jeurceramsoc.2019.02.002 ↗
30. Mechanical and thermal properties of simultaneously substituted pyrochlore compounds (Ca2Nb2O7)x(Gd2Zr2O7)1-x10.1016/j.jeurceramsoc.2014.10.009 ↗
31. Thermophysical and mechanical properties of Sm3TaO7/7 wt.% Y2O3-ZrO2 ceramics10.1016/j.ceramint.2022.08.091 ↗
32. Thermal conductivity of (Sm1-xLax)2Zr2O7 (x=0, 0.25, 0.5, 0.75 and 1) oxides for advanced thermal barrier coatings10.1016/S1002-0721(08)60223-9 ↗
33. Order-disorder transition in Nd2‒yGdyZr2O7 pyrochlore solid solution: an X‒ray diffraction and Raman spectroscopic study10.1016/j.jssc.2007.07.007 ↗
34. Spectroscopic investigations of the structural phase transition in Gd2(Ti1‒yZry)2O7 pyrochlores10.1021/jp014285t ↗
35. Rare‒earth titanates and stannates of pyrochlore structure; vibrational spectra and force fields10.1002/jrs.1250140202 ↗
36. Effect of host structure on the photo luminescence properties of Ln3TaO7: Eu3+ red phosphors10.1016/j.optmat.2015.12.028 ↗
37. Effect of phase structure evolution on thermal expansion and toughness of (Nd1‒xScx)2Zr2O7 (x = 0, 0.025, 0.05, 0.075, 0.1) ceramics10.1016/j.jmst.2016.03.015 ↗
38. 21-component compositionally complex ceramics: discovery of ultrahigh-entropy weberite and fergusonite phases and a pyrochlore weberite transition10.1007/s40145-022-0575-5 ↗
39. High entropy (La0.2Nd0.2Sm0.2Eu0.2Gd0.2)2Ce2O7: a potential thermal barrier material with improved thermo-physical properties10.1007/s40145-021-0563-1 ↗
40. Methods to reduce the thermal conductivity of EB-PVD TBCs10.1016/S0257-8972(01)01651-6 ↗
41. Role and determining factor of substitutional defects on thermal conductivity: a study of La2(Zr1-xBx)2O7 (B=Hf, Ce,0≤x≤0.5) pyrochlore solid solutions10.1016/j.actamat.2014.01.011 ↗
42. Preparation and thermophysical properties of Dy2Zr2O7 ceramic for thermal barrier coatings10.1016/j.matlet.2005.03.061 ↗
43. Size disorder as a descriptor for predicting reduced thermal conductivity in medium-and high-entropy pyrochlore oxides10.1016/j.scriptamat.2020.02.011 ↗
44. Role of disorder and anharmonicity in the thermal conductivity of silicon– germanium alloys: a first-principles study10.1103/PhysRevLett.106.045901 ↗
45. A perspective on challenges and opportunities in developing high entropy ultra high temperature ceramics10.1016/j.ceramint.2020.07.066 ↗
46. Effect of Ti substitution for Zr on the thermal expansion property of fluorite-type Gd2Zr2O710.1016/j.matdes.2009.01.030 ↗
47. Mechanical properties of high-temperature degraded yttria-stabilized zirconia10.1016/j.actamat.2014.01.017 ↗
48. Thermal barrier coatings for gas-turbine engine applications10.1126/science.1068609 ↗
49. Microstructure and thermal properties of a promising thermal barrier coating: YTaO410.1016/j.ceramint.2016.05.194 ↗