journal article·2026-06Open access

A scalable framework for air-entraining agent adsorption on fly ash: Intrinsic capacity and Ca-driven non-proportional uptake

Yujia Min, Prannoy Suraneni, Christopher Shearer, Doug Hooton, Lisa E. Burris

Abstract

To facilitate their continued use in concrete as sources become less standard, interactions between fly ash and air-entraining admixtures (AEA) must be better understood. For this study, adsorption tests were conducted using portland cement, fly ash, calcium salts, and a commercial AEA. Varying fly ash-to-solution ratio responses indicated that the removal of AEA from solution by fly ash was divided into non-proportional adsorption (NPA) and proportional adsorption (PA). NPA was found to be reversible, resulting in a three-phase equilibrium among NPA, PA, and AEA remaining in solution. A new method was developed to obtain adsorption capacities that are not affected by the fly ash-to-solution ratio used in the test and thus can help understand the AEA distribution in the system with high solid-to-solution ratios that adsorption tests cannot simulate, such as concrete mixtures. In addition, NPA was shown to be primarily related to complexation between AEA and calcium present in the mixture due to the presence of cement and fly ash.
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Research context

OpenAlex topics: Adsorption and biosorption for pollutant removal · Minerals Flotation and Separation Techniques · Coagulation and Flocculation Studies

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References (30)

Show source-provided references
1. A review on fly ash characteristics – towards promoting high volume utilization in developing sustainable concrete10.1016/j.jclepro.2017.01.114 ↗
2. Reactivity of coal fly ash used in cementitious binder systems: a state-of-the-art overview10.1016/j.fuel.2021.121031 ↗
3. Review, sampling, and evaluation of landfilled fly ash
4. Characterization of biomass and high carbon content coal ash for productive reuse applications10.1016/j.fuel.2013.08.030 ↗
5. Effects of unconventional fly ashes on cementitious paste properties10.1016/j.cemconcomp.2021.104291 ↗
6. Dodson · 2013
7. A review of the interference of carbon containing fly ash with air entrainment in concrete10.1016/j.pecs.2007.03.002 ↗
8. Surfactant adsorptivity of solid products from pulverized-coal combustion under controlled conditions10.1016/S0082-0784(98)80156-2 ↗
9. A new hypothesis for air loss in cement systems containing fly ash10.1016/j.cemconres.2021.106352 ↗
10. 2019
11. ASTM · 2019
12. Comparison of the loss-on-ignition and thermogravimetric analysis techniques in measuring unburned carbon in coal fly ash10.1021/ef0100496 ↗
13. Size distribution of unburned carbon in coal fly ash and its implications10.1016/S0016-2361(03)00255-2 ↗
14. Mechanisms of surfactant adsorption on non-polar, air-oxidized and ozone-treated carbon surfaces10.1016/S0008-6223(03)00053-8 ↗
15. An examination of fly ash carbon and its interactions with air entraining agent10.1016/S0008-8846(97)00008-2 ↗
16. The use of the foam index test to predict air-entraining admixture dosage in concrete containing fly ash: part II—development of a standard test method: apparatus and procedure
17. ASTM C1827-20 · 2020
18. Combined adsorption isotherms for measuring the adsorption capacity of fly ash in concrete10.1021/sc500043s ↗
19. Quantification of the adsorption capacity of fly ash10.1021/ie500484d ↗
20. Mechanisms of air entrainment in concrete10.1016/j.cemconres.2004.07.026 ↗
21. Air-entraining admixture partitioning and adsorption by fly ash in concrete10.1021/ie4018594 ↗
22. Direct adsorption isotherms of AEAs and fly ash: α-olefin sulfonate and combination admixtures10.1021/sc500697x ↗
23. The pore solution of blended cements: a review10.1617/s11527-015-0724-1 ↗
24. Effects of supplementary cementitious materials on pore-solution chemistry of blended cements
25. Investigation of air-entraining admixture dosage in fly ash concrete
26. Adsorption of surfactants on unburned carbon in fly ash and development of a standardized foam index test10.1016/S0008-8846(03)00232-1 ↗
27. The dissolution of fly ashes in undersaturated alkaline solutions10.1016/j.cemconres.2025.107967 ↗
28. Air entraining admixtures: mechanisms, evaluations, and interactions10.1016/j.cemconres.2021.106557 ↗
29. Measuring concrete air-entraining admixture adsorption on coal ash using three-phase equilibrium and fluorescence-based methods10.1016/j.cement.2024.100115 ↗
30. Air entrainment in cement and silica pastes