Preparation and Characterization of Magnetic Rigid Polyurethane Foam Reinforced with Dipodal Silane Iron Oxide Nanoparticles Fe ₃ O ₄ @APTS/GPTS

In this study, a new class of magnetic rigid polyurethane foams (PUFs) has been fabricated by one-shot process. Dipodal silane-coated magnetic nanoparticles (DScMNPs) was used as the magnetic nanoparticle and synthesized by functionalization of iron oxide nanoparticles by the prepared dipodal silane based on 3-aminopropyltriethoxysilane (APTS) and γ-glycidoxypropyltrimetoxysilane (GPTS) via sol-gel method. The synthesized DScMNPs were used up to 8.0% in the rigid polyurethane foam formulation and prepared foams were characterized. The chemical structure of DScMNPs was confirmed by proton nuclear magnetic resonance spectroscopy ( ¹ H NMR), Fourier transform infrared spectroscopy (FTIR) and transmission electron microscopy (TEM), respectively. Morphological, thermal and mechanical properties of the PU nanocomposites were studied by scanning electron microscopy (SEM), thermogravimetric analysis (TGA) and dynamic mechanical analysis (DMA). Vibrating sample magnetometery (VSM) was also showed that the synthesized PU nanocomposites are super paramagnetic.