Incommensurately modulated sodium polyiodide crystal structure discloses unconventional 1D iodine chains
Bibliographic record
Abstract
No abstract is available for this record. The assistant can identify its topic from the title, but cannot infer the study’s results.
Source: Not provided · Quality: missing
Research context
OpenAlex topics: Inorganic Chemistry and Materials · Crystallography and molecular interactions · Inorganic Fluorides and Related Compounds
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (96)
Show source-provided references
1. Gay-Lussac, J. L. Mémoire sur l’iode; 1815.
2. VI. Some Experiments and Observations on a New Substance Which Becomes a Violet Coloured Gas by Heat10.1098/rstl.1814.0007 ↗
3. Synthesis, Structure, and Bonding in Polyiodide and Metal Iodide−Iodine Systems10.1021/cr0204101 ↗
4. Words in Supramolecular Chemistry: The Ineffable Advances of Polyiodide Chemistry10.1039/D0DT04091F ↗
5. Rethinking Polyiodides: The Role of Electron-Deficient Multicenter Bonds10.1039/D4CC02832E ↗
6. Quantum Chemical Similarities of Bonding in Polyiodides and Phase-Change Materials10.1021/acs.inorgchem.3c03104 ↗
7. Genesis of Complex Polyiodide Networks: Insights on the Blue Box/I−/I2 Ternary System10.3390/cryst10050387 ↗
8. Mémoire Sur Les Combinaisons de l’Iode Avec Les Substances Végétales et Animales
9. The Other Double Helix—The Fascinating Chemistry of Starch10.1021/ed077p988 ↗
10. Infinite Polyiodide Chains in the Pyrroloperylene–Iodine Complex: Insights into the Starch–Iodine and Perylene–Iodine Complexes10.1002/anie.201601585 ↗
11. Inside Back Cover: Infinite Polyiodide Chains in the Pyrroloperylene–Iodine Complex: Insights into the Starch–Iodine and Perylene–Iodine Complexes (Angew. Chem. Int. Ed. 28/2016)10.1002/anie.201604535 ↗
12. The Cambridge Structural Database10.1107/S2052520616003954 ↗
13. Topography of Cyclodextrin Inclusion Complexes: Part II. The Iodine-Cyclohexa-Amylose Tetrahydrate Complex; Its Molecular Geometry and Cage-Type Crystal Structure10.1016/S0008-6215(00)86186-8 ↗
14. Molecular Metals Based on 1,2,7,8-Tetrahydrodicyclopenta[Cd:Lm]Perylene and Iodine, (CPP)2(I3)1-.Delta10.1021/cm00048a017 ↗
15. 3,4,9,10 - Tetrathioperylene - I1.28, a New Highly Conducting, Incommensurate Organic Charge Transfer Salt10.1016/0038-1098(81)90972-8 ↗
16. The Iodine/Iodide/Starch Supramolecular Complex10.3390/molecules29030641 ↗
17. The Starch-Iodine-Iodide Interaction. Part I. Spectrophotometric Investigations110.1021/ja01501a004 ↗
18. Rzepa · 2024
19. Polymeric Tris(Μ2-Acetone-κ2O:O)Sodium Polyiodide at 120 K10.1107/S0108270103006395 ↗
20. Ionic complexes of thiourea
21. Ionic complexes of thiourea
22. Coordination compounds of metals with ligands containing bulky oxygen-containing substituents
23. Redetermination of Catena-Poly[[Sodium(I)-Tri-μ-Dimethyl-formamide-κ6O:O] Iodide] at 140 K10.1107/S1600536807007052 ↗
24. The Configuration of Starch in the Starch—Iodine Complex. III. X-Ray Diffraction Studies of the Starch—Iodine Complex110.1021/ja01249a016 ↗
25. Barger · 1930
26. On the Nature of the Starch—Iodine Complex110.1021/ja01240a031 ↗
27. Herapathite10.1126/science.1173605 ↗
28. Synthesis and Structure of [Na4(DMSO)15] [(I3)3(I)]. Self-Assembly of Hexacoordinated Sodium10.1039/c1cc11898f ↗
29. A Role for Pd(IV) in Catalytic Enantioselective C–H Functionalization with Monoprotected Amino Acid Ligands under Mild Conditions10.1021/jacs.7b03716 ↗
30. “What Makes Every Work Perfect Is Cooking and Grinding”: The Ancient Roots of Mechanochemistry10.1039/D3MR00035D ↗
31. Embroidering Ionic Cocrystals with Polyiodide Threads: The Peculiar Outcome of the Mechanochemical Reaction between Alkali Iodides and Cyanuric Acid10.1021/acs.cgd.2c00202 ↗
32. Aperiodic Crystals and Superspace Concepts10.1107/S2052520614014917 ↗
33. Ted Janssen and Aperiodic Crystals10.1107/S2053273318016765 ↗
34. The Crystal Structure of Bis(Tetrathiotetracene) Triiodide, a One-Dimensional Organic Metal10.1107/S0567740877006992 ↗
35. Structure of Conducting Complexes Based on Cation-Radicals. II. Crystal and Molecular Structure of the 2:1 Complex of Tetraselenotetracene and Chlorine, TSeT2tc1-
36. Etude par la diffraction des rayons X et des neutrons du bis(tétrathiotétracène)–triiode (TTT2I3+δ): description des sous-réseaux ordonnés et désordonnés des atomes d’iode; évolution structurale en fonction de la température10.1107/S0567740882009406 ↗
37. Structural Studies of (Tetrathiotetracene)2(Iodide)3 at Room Temperature and Low Temperatures10.1063/1.441240 ↗
38. New Organic ‘Metals’: Naphthaceno[5,6-Cd:11,12-C′d′]Bis[1,2]Dithiolium Iodides10.1039/C39760000720 ↗
39. An Inorganic Starch–Iodine Model: The Inorganic–Organic Hybrid Compound {(C4H12N2)2[CuII4](I2)}n.10.1039/b820151j ↗
40. The Mechanism of Electrical Conductivity along Polyhalide Chains10.1016/0009-2614(86)87118-4 ↗
41. Grotthuss · von Mémoire sur la décomposition de l’eau et des corps qu’elle tient en dissolution à l’aide de l’électricité Galvanique par C.J.T. de Grotthuss · 1805
42. Iodide and Triiodide Anion Complexes Involving Anion–π Interactions with a Tetrazine-Based Receptor10.1039/C7DT00134G ↗
43. Grotthuss Transport of Iodide in EMIM/I3 Ionic Crystal10.1021/acs.jpcb.7b09292 ↗
44. The Structures of Two Forms of Tetraphenyldithiapyranylidene Polyiodide, One-Dimensional Organic Conductors10.1107/S0567740880006632 ↗
45. Chain Ordering in E2PI1.6 (5,10-Diethylphenazinium Iodide)10.1107/S0108768185001586 ↗
46. Polyiodides of Triethylenediamine: Single-Crystal Resonance Raman Spectra and x-Ray Structures10.1021/j100292a016 ↗
47. Crystallographic studies of one-dimensional polyiodide conductors. 2. Benzophenone polyiodide complexes10.1021/j100240a034 ↗
48. A Review of Fine Structures of Nanoporous Materials as Evidenced by Microscopic Methods10.1093/jmicro/dfs098 ↗
49. Structural and Transport Properties of the Incommensurate Organic Superconductor (MDT−ST)(I3)0.41710.1103/PhysRevB.71.172503 ↗
50. Fermi Surface of the Organic Superconductor (MDT−ST)(I3)0.417 Reconstructed by Incommensurate Potential10.1103/PhysRevB.73.024503 ↗
51. Helimagnetism in the Candidate Ferroelectric CrI210.1103/PhysRevB.109.144403 ↗
52. Rare iodine polymer discovery is key to starch-iodine mystery. 2025 UCSB College of Engineering. https://engineering.ucsb.edu/news/rare-iodine-polymer-discovery-key-starch-iodine-mystery (accessed 2025-05-05).
53. Structural Aspects of Iodine-Containing Low-Dimensional Materials
54. Novel Cyclen-Polyiodide Complexes: A Reappraisal of I–I Covalent and Secondary Bond Limits10.1039/D2DT00185C ↗
55. The Borderless World of Chemical Bonding across the van Der Waals Crust and the Valence Region10.1039/D3SC02238B ↗
56. From polyanions to infinite chains: chemical bonding evolution in AX3 polyhalides under pressure10.1039/D5TC01566A ↗
57. Ye Olde Supramolecular Chemistry, Its Modern Rebranding and Overarching Trends in Chemistry10.1039/D3DT03686C ↗
58. Secondary Bonding and Hydrogen Bonding: Siblings under the Skin10.1039/C6CS00688D ↗
59. Infinite Supramolecular Pseudo-Polyrotaxane with Poly[3]Catenane Axle: Assembling Nanosized Rings from Mono- and Diatomic I− and I2 Tectons10.1039/C9CC08367G ↗
60. Stabilization of Polyiodide Networks with Cu(II) Complexes of Small Methylated Polyazacyclophanes: Shifting Directional Control from H-Bonds to I⋯I Interactions10.1039/D0QI00912A ↗
61. Assembly of Polyiodide Networks with Cu(II) Complexes of Pyridinol-Based Tetraaza Macrocycles10.1021/acs.inorgchem.1c02967 ↗
62. Unraveling the Bonding Complexity of Polyhalogen Anions: High-Pressure Synthesis of Unpredicted Sodium Chlorides Na2Cl3 and Na4Cl5 and Bromide Na4Br510.1021/jacsau.3c00090 ↗
63. Pressure-Induced Hypercoordination of Iodine and Dimerization of I2O6H in Strontium Di-Iodate Hydrogen-Iodate (Sr(IO3)2HIO3)10.1016/j.mtadv.2024.100495 ↗
64. Incipient Metals: Functional Materials with a Unique Bonding Mechanism10.1002/adma.201803777 ↗
65. Understanding the Structure and Properties of Sesqui-Chalcogenides (i.e., V2VI3 or Pn2Ch3 (Pn = Pnictogen, Ch = Chalcogen) Compounds) from a Bonding Perspective10.1002/adma.201904316 ↗
66. Chalcogenide Thermoelectrics Empowered by an Unconventional Bonding Mechanism
67. Vacancy-Mediated Three-Center Four-Electron Bonds in GeTe-Sb${ }2$Te${ }3$ Phase-Change Memory Alloys10.1103/PhysRevB.87.165206 ↗
68. Understanding Phase-Change Memory Alloys from a Chemical Perspective10.1038/srep13698 ↗
69. Chemical Bonding in Chalcogenides: The Concept of Multicenter Hyperbonding10.1002/adma.202000340 ↗
70. Hypervalency in Amorphous Chalcogenides10.1038/s41467-022-29054-5 ↗
71. Long-Range Forces in Rock-Salt-Type Tellurides and How They Mirror the Underlying Chemical Bonding10.1002/adma.202100163 ↗
72. The Orbital Origins of Chemical Bonding in Ge−Sb−Te Phase-Change Materials
73. Electron-Deficient Multicenter Bonding in Phase Change Materials: A Chance for Reconciliation10.3390/ma17122840 ↗
74. Metavalent Multicenter Bonding in Pnictogens and Chalcogens: Nature and Mechanism of Formation
75. Electron-Deficient Multicenter Bonding in Pnictogens and Chalcogens: Mechanism of Formation10.1039/D4TC00604F ↗
76. A Unified Theory of Electron-Rich and Electron-Deficient Multicenter Bonds in Molecules and Solids: A Change of Paradigms
77. A Unified Theory of Electron-Rich and Electron-Deficient Multicenter Bonds in Molecules and Solids: A Change of Paradigms10.1039/D4TC04441J ↗
78. The atom and the molecule10.1021/ja02261a002 ↗
79. The arrangement of electrons in atoms and molecules10.1021/ja02227a002 ↗
80. Unconventional Electron-Deficient Multicenter Bonds in AIO3 Perovskites10.1021/acs.chemmater.5c00877 ↗
81. Chemical bonding in dense AIVXVI and AV2XVI3 chalcogenides: electron-deficient multicenter bonds in electron-rich elements10.1039/D5TC02328A ↗
82. Hypervalent Bonding in One, Two, and Three Dimensions: Extending the Zintl–Klemm Concept to Nonclassical Electron-Rich Networks10.1002/1521-3773(20000717)39:14<2408::AID-ANIE2408>3.0.CO;2-U ↗
83. The Zintl-Klemm Concept – A Historical Survey10.1002/zaac.201400403 ↗
84. Photonic Quasicrystalline and Aperiodic Structures10.1016/j.physe.2010.02.020 ↗
85. Aperiodic Order Induced Enhancement of Weak Nonlocality in Multilayered Dielectric Metamaterials10.1103/PhysRevB.98.195128 ↗
86. The Starch-Iodine Reaction10.1021/j150236a002 ↗
87. Neue Ansichten über die Stärke10.1007/BF01489430 ↗
88. APEX4 (Bruker), 2021).
89. Bruker
90. SUPERFLIP – a Computer Program for the Solution of Crystal Structures by Charge Flipping in Arbitrary Dimensions10.1107/S0021889807029238 ↗
91. Crystal Structure Refinement with SHELXL10.1107/S2053229614024218 ↗
92. Jana2020 – a New Version of the Crystallographic Computing System Jana10.1515/zkri-2023-0005 ↗
93. Mercury 4.0: From Visualization to Analysis, Design and Prediction10.1107/S1600576719014092 ↗
94. Direct Evidence for a Carbon–Carbon One-Electron σ-Bond10.1038/s41586-024-07965-1 ↗
95. Molecular and Crystal Structure of 7-Fold V-Amylose Complexed with 2-Propanol10.1021/ma101794w ↗
96. Chapter 1 - Nanoscience and Nanotechnology