journal article·2022-11Open access

Concept of a hybrid compression-adsorption heat pump cycle

Jubair A. Shamim, Gunjan Auti, Hibiki Kimura, Shubo Fei, Wei-Lun Hsu, Hirofumi Daiguji, Arun Majumdar

Cell Reports Physical Science· Volume 3· Issue 11

Abstract

A heat pump can produce a large amount of thermal energy for low- to moderate-temperature heating and cooling from a small amount of energy input. Although vapor compression heat pumps (VCHPs) can achieve a high coefficient of performance (COP), the lack of eco-friendly fluorocarbon refrigerants is a serious problem. An adsorption heat pump is a heat-driven heat pump that does not use fluorocarbon refrigerants but is less compact and has higher installation costs. This perspective proposes a hybrid compression-adsorption heat pump (HCA-HP) cycle that circulates a mixture of CO2 and a porous metal-organic framework (MOF) in a VCHP system. Model calculations show that the MOF-CO2 HCA-HP cycle can release heat at 50% lower pressure than the transcritical CO2 HP cycle and that the COP can be improved by developing a pair of MOFs and gases with a step-shaped adsorption isotherm and a large heat of adsorption.
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Research context

OpenAlex topics: Phase Equilibria and Thermodynamics · Adsorption and Cooling Systems · Carbon Dioxide Capture Technologies

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References (40)

Show source-provided references
1. A review of domestic heat pumps10.1039/c2ee22653g ↗
2. To decarbonize industry, we must decarbonize heat10.1016/j.joule.2020.12.007 ↗
3. Lemmon · 2018
4. High temperature heat pumps: market overview, state of the art, research status, refrigerants, and application potentials10.1016/j.energy.2018.03.166 ↗
5. Limited options for low-global-warming-potential refrigerants10.1038/ncomms14476 ↗
6. The large contribution of projected HFC emissions to future climate forcing10.1073/pnas.0902817106 ↗
7. Realistic pathways to decarbonization of building energy systems10.1016/j.joule.2022.04.003 ↗
8. Recent advances in transcritical CO2 (R744) heat pump system: a review10.3390/en12030457 ↗
9. In-tube cooling heat transfer of supercritical carbon dioxide. Part 1. Experimental measurement10.1016/j.ijrefrig.2004.04.018 ↗
10. An experimental study of trans-critical CO2 water–water heat pump using compact tube-in-tube heat exchangers10.1016/j.enconman.2013.07.031 ↗
11. In-tube cooling heat transfer of supercritical carbon dioxide. Part 2. Comparison of numerical calculation with different turbulence models10.1016/j.ijrefrig.2004.04.017 ↗
12. Performance evaluation of a tube-in-tube CO2 gas cooler used in a heat pump water heater10.1016/j.expthermflusci.2014.01.007 ↗
13. Modelling the performance of a transcritical CO2 heat pump for high temperature heating10.1016/S0140-7007(01)00021-4 ↗
14. Fundamental process and system design issues in CO2 vapor compression systems10.1016/j.pecs.2003.09.002 ↗
15. An overview of developments in adsorption refrigeration systems towards a sustainable way of cooling10.1016/j.apenergy.2012.11.042 ↗
16. Adsorption heat pumps for heating applications: a review of current state, literature gaps and development challenges10.1016/j.rser.2018.09.026 ↗
17. Adsorption heat pumps for heating applications10.1016/j.rser.2019.109528 ↗
18. A review on adsorption heat pump: problems and solutions10.1016/j.rser.2007.06.005 ↗
19. Alumina-coated ordered mesoporous silica as an efficient and stable water adsorbent for adsorption heat pump10.1016/j.micromeso.2016.10.014 ↗
20. Metal–organic frameworks in adsorption-driven heat pumps: the potential of alcohols as working fluids10.1021/acs.langmuir.5b03272 ↗
21. Koyama · 2009
22. A review of metal-organic frameworks (MOFs) as energy-efficient desiccants for adsorption driven heat-transformation applications10.1016/j.apenergy.2020.115070 ↗
23. A review of solid desiccant dehumidifiers: current status and near-term development goals in the context of net zero energy buildings10.1016/j.rser.2020.110456 ↗
24. Adsorption-driven heat pumps: the potential of metal–organic frameworks10.1021/acs.chemrev.5b00059 ↗
25. MOFs for use in adsorption heat pump processes10.1002/ejic.201101056 ↗
26. Progress in adsorption-based CO 2 capture by metal–organic frameworks10.1039/C1CS15221A ↗
27. Can metal–organic framework materials play a useful role in large-scale carbon dioxide separations?10.1002/cssc.201000114 ↗
28. Carbon capture and conversion using metal–organic frameworks and MOF-based materials10.1039/C8CS00829A ↗
29. Limitations and high pressure behavior of MOF-5 for CO 2 capture10.1039/c3cp51768c ↗
30. Metal− organic frameworks with exceptionally high capacity for storage of carbon dioxide at room temperature10.1021/ja0570032 ↗
31. A comprehensive review and analysis on CO2 heat pump water heaters
32. Stephenson · 1987
33. Design and synthesis of an exceptionally stable and highly porous metal-organic framework10.1038/46248 ↗
34. A new equation of state for carbon dioxide covering the fluid region from the triple-point temperature to 1100 K at pressures up to 800 MPa10.1063/1.555991 ↗
35. Vapor compression heat pumps with pure Low-GWP refrigerants10.1016/j.rser.2020.110571 ↗
36. Cooperative insertion of CO2 in diamine-appended metal-organic frameworks10.1038/nature14327 ↗
37. A novel linear electromagnetic-drive oil-free refrigeration compressor using R134a10.1016/j.ijrefrig.2013.11.027 ↗
38. Oil free turbo-compressors for CO2 refrigeration applications10.1016/j.ijrefrig.2013.03.002 ↗
39. A chromium terephthalate-based solid with unusually large pore volumes and surface area10.1126/science.1116275 ↗
40. Kinetics of water vapor adsorption and desorption in MIL-101 metal–organic frameworks10.1021/acs.jpcc.8b08211 ↗