journal article·2025-05Open access

Electrocatalytic oxidation of hydrothermal liquefaction-derived aqueous phase for on-site wastewater treatment and H2 production

Swanand Bhatwadekar, Bhanupriya Boruah, Nickolas W. Riedel, Nathanael D. Royer, Thomas Helmer Pedersen, Juan A. Lopez-Ruiz

Cell Reports Physical Science· Volume 6· Issue 5

Abstract

Electrocatalytic oxidation (ECO) is a promising method for generating molecular hydrogen (H 2 ) while simultaneously treating the aqueous phase (AP) from hydrothermal liquefaction (HTL) of biomass-derived feedstocks such as algae, food waste, sludge, and wood. This study highlights the impact of HTL-AP composition on ECO performance, mainly activity, stability, and efficiency in a batch and flow electrolyzer. We demonstrated current efficiency (CE) for chemical oxygen demand (COD) removal ranges from 14% to 85% in the flow electrolyzer with electrode stability increasing from 20 to ≥2,800 h. Decreasing the applied potential enhances the CE. High ammonium content can accelerate deactivation, yet chloride ions appear to aid oxidation of organic compounds and enhanced anode stability. A preliminary energy and H 2 balance for an HTL sewage sludge plant shows that the HTL-AP contains sufficient COD to produce all the H 2 needs for bio-oil hydrotreating, with a 26% surplus available for other uses.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Electrocatalysts for Energy Conversion · Advanced oxidation water treatment · Fuel Cells and Related Materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

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