journal article·2021-10Open access

Dynamic tunability of phase-change material transition temperatures using ions for thermal energy storage

Jonathan Lau, Joseph K. Papp, Drew Lilley, Piyachai Khomein, Sumanjeet Kaur, Christopher Dames, Gao Liu, Ravi Prasher

Cell Reports Physical Science· Volume 2· Issue 10

Abstract

Thermal energy storage (TES) based on phase-change materials (PCMs) has many current and potential applications, such as climate control in buildings, thermal management for batteries and electronics, thermal textiles, and transportation of pharmaceuticals. Despite its promise, the adoption of TES has been limited, in part due to limited tunability of the transition temperature, which hinders TES performance for varying use temperatures. Transition temperature tuning of a material using an external stimulus, such as pressure or an electric field, typically requires very large stimuli. To circumvent this problem, here, we report on the dynamic transition temperature tunability of a PCM using ions. We achieve a transition temperature tunability up to 6°C in polyethylene glycol (PEG) by using the salt lithium oxalatodifluoroborate at a low voltage of 2.5 V, which may enable simpler and safer devices/system designs. We also explain the thermal properties of the salt/PCM solution using the Flory-Huggins theory.
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Research context

OpenAlex topics: Advanced Battery Materials and Technologies · Transition Metal Oxide Nanomaterials · Conducting polymers and applications

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