journal article·2022-12Open access

Modified cathode-electrolyte interphase toward high-performance batteries

Nan Zhang, Bo Wang, Fan Jin, Yong Chen, Yunpeng Jiang, Changyuan Bao, Jiyu Tian, Jingyang Wang, Ruoyu Xu, Yaohua Li, Qiang Lv, Huaizheng Ren, Dianlong Wang, Huakun Liu, Shixue Dou, Xiang Hong

Cell Reports Physical Science· Volume 3· Issue 12

Abstract

A stable and uniform cathode-electrolyte interphase (CEI) is extremely important for rechargeable batteries with high energy densities and long life cycles. The CEI greatly influences the electrochemical reactions at the interphase while stabilizing the cathode’s structure. Because of the complexity of the interfacial reaction, an overall picture of CEI evolution and effective analysis methods is absent in the field. Herein, the formation and evolution mechanism of the CEI in rechargeable batteries are reviewed based on the CEI studies. Diverse advanced characterization methods for the interfacial reaction are also summarized. Subsequently, modified strategies to enhance the stability of the CEI are introduced, such as CEI-forming additives in electrolytes, localized high-concentration electrolytes, artificial CEIs, and solid-state electrolyte engineering. Finally, challenges and future directions for the CEI are proposed. We hope this review sheds light on future research on CEI layers.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Advancements in Battery Materials · Advanced Battery Materials and Technologies · Advanced Battery Technologies Research

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (100+)

Show source-provided references
1. Interphases in sodium-ion batteries10.1002/aenm.201703082 ↗
2. Challenges and strategies to advance high-energy nickel-rich layered lithium transition metal oxide cathodes for harsh operation10.1002/adfm.202004748 ↗
3. Boosting electrochemical kinetics of S cathodes for room temperature Na/S batteries10.1016/j.matt.2021.03.004 ↗
4. Suppressing lithium dendrites within inorganic solid-state electrolytes10.1016/j.xcrp.2021.100706 ↗
5. Fluorinated carbonate electrolyte with superior oxidative stability enables long-term cycle stability of Na2/3Ni1/3Mn2/3O2 cathodes in sodium-ion batteries10.1002/aenm.202170034 ↗
6. Toward critical electrode/electrolyte interfaces in rechargeable batteries10.1002/adfm.201909887 ↗
7. High voltage stable polyoxalate catholyte with cathode coating for all-solid-state Li-metal/NMC622 batteries10.1002/aenm.202002416 ↗
8. Solid electrolyte interphases on sodium metal anodes10.1002/adfm.202004891 ↗
9. The electrochemical behavior of alkali and alkaline earth metals in nonaqueous battery systems—the solid electrolyte interphase model10.1149/1.2128859 ↗
10. Inhibition of transition metals dissolution in the cobalt-free cathode with ultrathin robust interphase in concentrated electrolyte10.1038/s41467-020-17396-x ↗
11. Tailoring electrolyte dehydrogenation with trace additives: stabilizing the LiCoO2 cathode beyond 4.6 V10.1021/acsenergylett.2c01433 ↗
12. Surface and subsurface reactions of lithium transition metal oxide cathode materials: an overview of the fundamental origins and remedying approaches10.1002/aenm.201802057 ↗
13. A Growing appreciation for the role of LiF in the solid electrolyte interphase10.1002/aenm.202100046 ↗
14. The cathode–electrolyte interface in the Li-ion battery10.1016/j.electacta.2004.03.049 ↗
15. Surface film formation on electrodes in a LiCoO2/graphite cell: a step by step XPS study10.1016/j.jpowsour.2007.06.033 ↗
16. Synergetic effects of inorganic components in solid electrolyte interphase on high cycle efficiency of lithium ion batteries10.1021/acs.nanolett.5b05283 ↗
17. New lithium salt forms interphases suppressing both Li dendrite and polysulfide shuttling10.1002/aenm.201903937 ↗
18. In situ TEM visualization of LiF nanosheet formation on the cathode-electrolyte interphase (CEI) in liquid-electrolyte lithium-ion batteries10.1016/j.matt.2022.01.015 ↗
19. Challenges and recent advances in high capacity li-rich cathode materials for high energy density lithium-ion batteries10.1002/adma.202005937 ↗
20. Review of recent development of in situ/operando characterization techniques for lithium battery research10.1002/adma.201806620 ↗
21. Enabling a durable electrochemical interface via an artificial amorphous cathode electrolyte interphase for hybrid solid/liquid lithium-metal batteries10.1002/ange.201916301 ↗
22. Constructing robust cathode/electrolyte interphase for ultrastable 4.6 V LiCoO2 under -25 °C10.1021/acsami.2c02818 ↗
23. Controllable cathode–electrolyte interface of Li[Ni0.8Co0.1Mn0.1]O2 for lithium ion batteries: a review10.1002/aenm.201901597 ↗
24. A comprehensive analysis of the interphasial and structural evolution over long-term cycling of ultrahigh-nickel cathodes in lithium-ion batteries10.1002/aenm.201902731 ↗
25. Surface/interface structure degradation of Ni-rich layered oxide cathodes toward lithium-ion batteries: fundamental mechanisms and remedying strategies10.1002/admi.201901749 ↗
26. Highly elastic binder for improved cyclability of nickel-rich layered cathode materials in lithium-ion batteries10.1002/aenm.202001069 ↗
27. Interfacial design for 4.6 V high-voltage single-crystalline LiCoO2 cathode10.1002/adma.201870345 ↗
28. Dissolution of cathode-electrolyte interphase deposited on LiNi0.5Mn1.5O4 for lithium-ion batteries10.1016/j.jpowsour.2021.230051 ↗
29. AC impedance analysis of polycrystalline insertion electrodes - application to Li1-xCoO210.1149/1.2114158 ↗
30. Review of selected electrode–solution interactions which determine the performance of Li and Li ion batteries10.1016/S0378-7753(00)00431-6 ↗
31. The Li-ion rechargeable battery: a perspective10.1021/ja3091438 ↗
32. Unexpected improved performance of ALD coated LiCoO2/Graphite Li-ion batteries10.1002/aenm.201200370 ↗
33. Understanding the rate capability of high-energy-density Li-rich layered Li1.2Ni0.15Co0.1Mn0.55O2 cathode materials10.1002/aenm.201300950 ↗
34. Dynamic behaviour of interphases and its implication on high-energy-density cathode materials in lithium-ion batteries10.1038/ncomms14589 ↗
35. A carbonate-free, sulfone-based electrolyte for high-voltage Li-ion batteries10.1016/j.mattod.2018.02.005 ↗
36. Enabling high-voltage lithium-metal batteries under practical conditions10.1016/j.joule.2019.05.006 ↗
37. Film formation at positive electrodes in lithium-ion batteries10.1149/1.1836114 ↗
38. Review on electrode–electrolyte solution interactions, related to cathode materials for Li-ion batteries10.1016/j.jpowsour.2006.10.025 ↗
39. CO2 gas evolution on cathode materials for lithium-ion batteries10.1149/1.2712138 ↗
40. Anode-originated SEI migration contributes to formation of cathode-electrolyte interphase layer10.1016/j.jpowsour.2017.09.050 ↗
41. Dynamic evolution of cathode electrolyte interphase (CEI) on high voltage LiCoO2 cathode and its interaction with Li anode10.1016/j.ensm.2018.02.016 ↗
42. The impact of electrolyte oxidation products in LiNi0.5Mn1.5O4/Li4Ti5O12 cells10.1149/2.051309jes ↗
43. Designing advanced in situ electrode/electrolyte interphases for wide temperature operation of 4.5 V Li||LiCoO2 batteries10.1002/adma.202004898 ↗
44. Insight into prolonged cycling life of 4 V all-solid-state polymer batteries by a high-voltage stable binder10.1002/aenm.202002455 ↗
45. Analyzing energy materials by cryogenic electron microscopy10.1002/adma.201908293 ↗
46. Unusual stability of acetonitrile-based superconcentrated electrolytes for fast-charging lithium-ion batteries10.1021/ja412807w ↗
47. Lithium nitrate regulated sulfone electrolytes for lithium metal batteries10.1002/anie.202009575 ↗
48. Advanced electrolytes for fast-charging high-voltage lithium-ion batteries in wide-temperature range10.1002/aenm.202070098 ↗
49. Stabilizing ultrahigh-nickel layered oxide cathodes for high-voltage lithium metal batteries10.1016/j.mattod.2021.01.013 ↗
50. Electroanalytical methods and their hyphenated techniques for novel ion battery anode research10.1039/D0EE01184C ↗
51. High-voltage liquid electrolytes for Li batteries: progress and perspectives10.1039/D1CS00450F ↗
52. Probing process kinetics in batteries with electrochemical impedance spectroscopy10.1038/s43246-022-00284-w ↗
53. Identification and quantification of ageing mechanisms in Li-ion batteries by electrochemical impedance spectroscopy10.1016/j.electacta.2022.140801 ↗
54. Application of electrochemical impedance spectroscopy to commercial Li-ion cells: a review10.1016/j.jpowsour.2020.228742 ↗
55. Tuning charge-discharge induced unit cell breathing in layer-structured cathode materials for lithium-ion batteries10.1038/ncomms6381 ↗
56. Extending the service life of high-ni layered oxides by tuning the electrode–electrolyte interphase10.1002/aenm.201801957 ↗
57. Trace doping of multiple elements enables stable battery cycling of LiCoO2 at 4.6 V10.1038/s41560-019-0409-z ↗
58. First in situ observation of the LiCoO2 electrode/electrolyte interface by total-reflection X-ray absorption spectroscopy10.1002/anie.201203910 ↗
59. Visualization and quantification of electrochemical and mechanical degradation in Li ion batteries10.1126/science.1241882 ↗
60. Characterization of dynamic morphological changes of tin anode electrode during (de)lithiation processes using in operando synchrotron transmission X-ray microscopy10.1016/j.electacta.2019.05.056 ↗
61. In-built ultraconformal interphases enable high-safety practical lithium batteries10.1016/j.ensm.2021.09.007 ↗
62. An air-stable high-nickel cathode with reinforced electrochemical performance enabled by convertible amorphous Li2CO3 modification10.1002/adma.202108947 ↗
63. In situ visualized cathode electrolyte interphase on LiCoO2 in high voltage cycling10.1021/acsami.7b03024 ↗
64. Evolution of solid electrolyte interface on TiO2 electrodes in an aqueous Li-ion battery studied using scanning electrochemical microscopy10.1021/acs.jpcc.9b01412 ↗
65. Operando investigation into dynamic evolution of cathode-electrolyte interfaces in a Li-ion battery10.1021/acs.nanolett.9b00179 ↗
66. Engineering an insoluble cathode electrolyte interphase enabling high performance NCM811//graphite pouch cell at 60 °C10.1002/aenm.202201631 ↗
67. Dynamic behavior at the interface between lithium cobalt oxide and an organic electrolyte monitored by neutron reflectivity measurements10.1021/acs.jpcc.6b02523 ↗
68. Electrolytes polymerization-induced cathode-electrolyte-interphase for high voltage lithium-ion batteries10.1002/aenm.202101956 ↗
69. High-rate charging induced intermediate phases and structural changes of layer-structured cathode for lithium-ion batteries10.1002/aenm.201600597 ↗
70. How Can the Electrode Influence the Formation of the Solid Electrolyte Interface?10.1021/acsenergylett.1c01359 ↗
71. Evolution of redox couples in Li- and Mn-rich cathode materials and mitigation of voltage fade by reducing oxygen release10.1038/s41560-018-0207-z ↗
72. Ultra-high-voltage Ni-rich layered cathodes in practical Li metal batteries enabled by a sulfonamide-based electrolyte10.1038/s41560-021-00792-y ↗
73. Surface regulation enables high stability of single-crystal lithium-ion cathodes at high voltage10.1038/s41467-020-16824-2 ↗
74. Cathode-electrolyte interphase in lithium batteries revealed by cryogenic electron microscopy10.1016/j.matt.2020.10.021 ↗
75. Tailoring electrolytes to enable high-rate and super-stable Ni-rich NCM cathode materials for Li-ion batteries10.1016/j.nanoen.2021.106301 ↗
76. Direct determination of solid-electrolyte interphase thickness and composition as a function of state of charge on a silicon anode10.1021/acs.jpcc.5b06817 ↗
77. In situ determination of the liquid/solid interface thickness and composition for the Li ion cathode LiMn1.5Ni0.5O410.1021/am5032055 ↗
78. Ultrafast ion transport at a cathode–electrolyte interface and its strong dependence on salt solvation10.1038/s41560-020-0647-0 ↗
79. An overview on the advances of LiCoO2 cathodes for lithium-ion batteries10.1002/aenm.202000982 ↗
80. Challenges for rechargeable batteries10.1016/j.jpowsour.2010.11.074 ↗
81. Optimizing interphase structure to enhance electrochemical performance of high voltage LiNi0.5Mn1.5O4 cathode via anhydride additives10.1016/j.cej.2021.128422 ↗
82. Interphases, interfaces, and surfaces of active materials in rechargeable batteries and perovskite solar cells10.1002/adma.201905245 ↗
83. In situ construction of uniform and robust cathode–electrolyte interphase for Li-rich layered oxides10.1002/adfm.202009192 ↗
84. Interfacial model deciphering high-voltage electrolytes for high energy density, high safety, and fast-charging lithium-ion batteries10.1002/adma.202102964 ↗
85. The DFT-ReaxFF hybrid reactive dynamics method with application to the reductive decomposition reaction of the TFSI and DOL electrolyte at a lithium-metal anode surface10.1021/acs.jpclett.0c03720 ↗
86. All-temperature batteries enabled by fluorinated electrolytes with non-polar solvents10.1038/s41560-019-0474-3 ↗
87. Enhancement of the high-rate capability of solid-state lithium batteries by nanoscale interfacial modification10.1002/adma.200502604 ↗
88. Intermolecular chemistry in solid polymer electrolytes for high-energy-density lithium batteries10.1002/adma.201902029 ↗
89. Revealing electrolyte oxidation via carbonate dehydrogenation on Ni-based oxides in Li-ion batteries by in situ Fourier transform infrared spectroscopy10.1039/C9EE02543J ↗
90. Two electrolyte decomposition pathways at nickel-rich cathode surfaces in lithium-ion batteries10.1039/D1EE04053G ↗
91. High-voltage and high-safety nickel-rich layered cathode enabled by a self-reconstructive cathode/electrolyte interphase layer10.1016/j.ensm.2021.06.018 ↗
92. Replacing conventional battery electrolyte additives with dioxolone derivatives for high-energy-density lithium-ion batteries10.1038/s41467-021-21106-6 ↗
93. Interphase engineering by electrolyte additives for lithium-rich layered oxides: advances and perspectives10.1021/acsenergylett.1c00750 ↗
94. Electrolyte-additive-driven interfacial engineering for high-capacity electrodes in lithium-ion batteries: promise and challenges10.1021/acsenergylett.0c00468 ↗
95. Inhibiting solvent co-intercalation in a graphite anode by a localized high-concentration electrolyte in fast-charging batteries10.1002/ange.202009738 ↗
96. Tuning interphase chemistry to stabilize high-voltage LiCoO2 cathode material via spinel coating10.1002/anie.202207000 ↗
97. Uncharted waters: super-concentrated electrolytes10.1016/j.joule.2019.12.007 ↗
98. Understanding the degradation mechanisms of LiNi0.5Co0.2Mn0.3O2 cathode material in lithium ion batteries10.1002/aenm.201300787 ↗
99. High-voltage performance of Ni-rich NCA cathodes: linking operating voltage with cathode degradation10.1002/celc.201901338 ↗
100. New insight into Ni-rich layered structure for next-generation Li rechargeable batteries10.1002/aenm.201870015 ↗