journal article·2026-07Open access

Moisture transport in unsaturated cementitious materials under varying initial saturation and sodium sulfate concentrations

Yong Wen, Junyi Qu, Xiaoyan Sun, Jing Xie, Jindou Hu, Xu-dong Liu

Abstract

Moisture transport in unsaturated cementitious materials exposed to different initial saturation levels (20–80%) and sodium sulfate concentrations (0–10%) was investigated through experiments and numerical modelling.The effects of water-cement ratio (w/c), initial saturation,and sulfate attack on pore structure and capillary water absorption were evaluated by adsorption-desorption tests,mercury intrusion porosimetry (MIP),capillary water absorption tests,and numerical simulation. The results show that pore structure governs moisture transport behavior.A higher w/c leads to higher equilibrium saturation because of improved pore connectivity, whereas lower initial saturation results in a higher capillary water absorption coefficient and a longer unsaturated transport path. Sulfate attack exhibits a clear concentration-dependent effect:low sulfate concentrations (2.5–5%) enhance moisture transport by locally improving pore connectivity,while high concentrations (>7.5%) inhibit transport because excessive reaction products block pores.Findings from this study offer a theoretical foundation for cementitious material durability design and life prediction in sulfate-enriched settings.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Concrete and Cement Materials Research · Concrete Properties and Behavior · Smart Materials for Construction

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (42)

Show source-provided references
1. Behavior of Salt Transport in Concrete Structures Under Temperature and Moisture Gradients
2. A unified pore structure-based model for diffusion coefficient of unsaturated cementitious materials10.1016/j.cemconres.2025.107943 ↗
3. Modelling of capillary water absorption in sound and cracked concrete using a dual-lattice approach: Computational aspects10.1016/j.conbuildmat.2021.125826 ↗
4. Theoretical model for the coupling effect of moisture transport on chloride penetration in concrete10.1016/j.cemconres.2024.107431 ↗
5. Unsaturated ion diffusion in cementitious materials – The effect of slag and silica fume10.1016/j.cemconres.2018.03.007 ↗
6. Prediction of moisture transfer in cement-based materials: Use of a porous network model to access transfer parameters
7. Multi-scale study water and ions transport in the cement-based materials:from molecular dynamics to random walk
8. Dependence of unsaturated chloride diffusion on the pore structure in cementitious materials10.1016/j.cemconres.2019.105919 ↗
9. Existing theories of concrete spalling and test methods relating to moisture migration patterns upon exposure to elevated temperatures – A review
10. Durability performance of an RC beam under real marine all corrosion zones exposure for 7 years
11. Water permeability of unsaturated cementitious materials: A review
12. New insights into long-term chloride transport in unsaturated cementitious materials: Role of degree of water saturation
13. Simulating water penetration in cementitious materials using pore structures from mercury intrusion porosimetry
14. Mechanisms and kinetic model for steel corrosion in unsaturated cementitious materials10.1038/s41529-024-00441-1 ↗
15. Chemomechanical Modeling of Sulfate Attack–Induced Damage Process in Cement-Stabilized Pavements
16. Molecular insights into ion and water transport in cementitious pore structures
17. Assessment of lithium slag as a supplementary cementitious material: Pozzolanic activity and microstructure development
18. Tracking water transport with short-wave infrared: kinetic phase diagrams, dissolution, and drying10.1021/acs.langmuir.4c05057 ↗
19. A multi-method investigation of temperature, moisture and salt dynamics in tafoni (Tafraoute, Morocco)10.1002/esp.3838 ↗
20. Three-dimensional pore structure characterization of cement paste by X-ray computed tomography (XCT) and focused ion beam/scanning electron microscopy (FIB/SEM)10.1016/j.conbuildmat.2023.131379 ↗
21. Moisture Transport in a Solid Waste Column10.1061/(ASCE)0733-9372(1984)110:4(780) ↗
22. Prediction of moisture transfer in cement-based materials: Use of a porous network model to access transfer parameters
23. Numerical Simulation of Water Transport in Unsaturated Recycled Aggregate Concrete10.3389/fmats.2020.560621 ↗
24. Numerical study on the chemical and electrochemical coupling mechanisms for concrete under combined chloride-sulfate attack10.1016/j.cemconres.2023.107368 ↗
25. Advanced modelling of moisture transport process in unsaturated cementitious materials considering multi-modal pore size distributions10.1016/j.cemconres.2025.107973 ↗
26. A Numerical Study of Moisture and Ionic Transport in Unsaturated Concrete by Considering Multi-ions Coupling Effect10.1007/s11242-023-02011-6 ↗
27. Implementation of capillary penetration coefficient on water sorptivity for porous building materials: An experimental study
28. Investigation on sorptivity and capillarity coefficient of mortar and their relationship based on microstructure10.1016/j.conbuildmat.2020.120332 ↗
29. A Closed-form Equation for Predicting the Hydraulic Conductivity of Unsaturated Soils10.2136/sssaj1980.03615995004400050002x ↗
30. Experimental determination on the capillary water absorption coefficient of porous building materials by an automatic absorption device
31. Multiscale lattice Boltzmann-finite element modelling of chloride diffusivity in cementitious materials. Part I: Algorithms and implementation10.1016/j.mechrescom.2013.09.002 ↗
32. Water vapor sorption in cementitious materials—Measurement, modeling and interpretation10.1007/s11242-014-0288-5 ↗
33. Impact of carbonation on unsaturated water transport properties of cement-based materials10.1016/j.cemconres.2015.04.002 ↗
34. V. Baroghel-Bouny, Water vapour sorption experiments on hardened cementitious materials10.1016/j.cemconres.2006.11.019 ↗
35. Inkbottle Pore-Method: Prediction of hygroscopic water content in hardened cement paste at variable climatic conditions10.1016/j.cemconres.2006.06.011 ↗
36. Kinetics and equilibrium isotherms of water vapor adsorption/desorption in cement-based porous materials10.1007/s11242-015-0531-8 ↗
37. Numerical study for a large-volume droplet on the dual-rough surface: Apparent contact angle, contact angle hysteresis, and transition barrier10.1021/acs.langmuir.8b01681 ↗
38. Microstructure and moisture transport in carbonated cement-based materials incorporating cellulose nanofibrils10.1016/j.cemconres.2022.106990 ↗
39. Water Penetration in Underewater Concrete Tunnel
40. Sulfate resistance of concrete with initial damage
41. Pore characteristics and simulation of mechanical behavior of concrete under uniaxial compression with sulfate attack
42. Study on the Micro-Mechanism of Corrosion Deterioration of Concrete Under Sulfate Attack Environment