Study on the workability and mechanical influencing factors of 3D-printed coal gangue-fly ash-based geopolymers
Source abstract
Abstract
Geopolymers have attracted increasing attention as low-carbon materials with good mechanical properties. This study explores the development of geopolymer materials using coal gangue (CG) and fly ash (FA) as primary raw materials, combined with 3D printing technology. The effects of CG content, water-to-binder ratio (W/B), binder-to-sand ratio (B/S) and alkali activators on the workability and mechanical properties of both cast and 3D-printed CG–FA geopolymers are systematically investigated. The results indicate that the flowability reaches a slight peak at 20% CG content, whereas further increases lead to a clear decline. Optimal W/B ratios (0.365–0.38) and B/S ratios (0.9–1.2) were found to enhance both the mechanical properties and workability of the material. Furthermore, the dosage and modulus of the alkali activator substantially influenced paste flowability, setting time, and long–term strength. Compared to cast specimens, 3D–printed specimens exhibited pronounced anisotropy in mechanical performance across different loading directions. This study provides guidance for optimizing mix design and process parameters of 3D–printed geopolymers. • A detailed study was conducted on the workability and mechanical influencing factors of coal gangue-fly ash-based geopolymers for 3D printing. • Optimal coal gangue content, water-to-binder ratio, and binder-to-sand ratio significantly enhance the flowability and compressive strength of the geopolymer paste. • The alkali activator content and modulus notably affect the flowability, setting time, and long-term strength of the geopolymer paste. • Compared to cast specimens, 3D printed specimens exhibit significant anisotropy in mechanical performance under different loading directions.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Innovations in Concrete and Construction Materials · Concrete and Cement Materials Research · Additive Manufacturing and 3D Printing Technologies
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (62)
Show source-provided references
1. Alkali-activated geopolymer materials prepared from coal gangue and municipal solid waste incineration byproducts
2. Manufacturing ultra-high performance geopolymer concrete (UHPGC) with activated coal gangue for both binder and aggregate10.1016/j.compositesb.2024.111723 ↗
3. Reaction mechanism and mechanical properties of geopolymer based on kaolinitic coal tailings10.1016/j.clay.2023.106826 ↗
4. Immobilizatiaon of heavy metals in municipal solid waste incineration fly ash with red mud-coal gangue10.1007/s10163-020-01082-7 ↗
5. Environmental Impact Assessment for Performance-Oriented Geopolymer Concrete Research10.1061/(ASCE)MT.1943-5533.0004526 ↗
6. Influence of supplementary cementitious materials on rheological properties of 3D printed fly ash based geopolymer10.1016/j.cemconcomp.2020.103820 ↗
7. The effect of nano zinc oxide on freeze-thaw resistance of 3D-printed geopolymer mortars
8. 3D concrete printing of eco-friendly geopolymer containing brick waste10.1016/j.cemconcomp.2023.104943 ↗
9. 3D printed mesh reinforced geopolymer: Notched prism bending10.1016/j.cemconcomp.2020.103892 ↗
10. Effect of raw materials on the performance of 3D printing geopolymer: A review
11. Mechanical anisotropy evaluation and bonding properties of 3D-printable construction and demolition waste-based geopolymer mortars10.1016/j.cemconcomp.2022.104814 ↗
12. Preparation and characterization of green lignin modified mineral cementitious firefighting materials based on uncalcined coal gangue and coal fly ash10.1016/j.conbuildmat.2024.136799 ↗
13. Toward understanding the activation and hydration mechanisms of composite activated coal gangue geopolymer10.1016/j.conbuildmat.2021.125999 ↗
14. Effect of hygroscopicity of typical powder solid wastes on their radon exhalation characteristics10.1016/j.scitotenv.2024.173956 ↗
15. Preparation and alkali excitation mechanism of coal gangue-iron ore tailings non-sintering ceramsite10.1016/j.conbuildmat.2024.136209 ↗
16. Immobilization of uranium soils with alkali-activated coal gangue–based geopolymer10.1007/s10967-021-07812-x ↗
17. Effect of alkali activator concentration and curing condition on strength and microstructure of waste clay brick powder-based geopolymer10.1016/j.compositesb.2017.10.013 ↗
18. Experimental study of the feasibility of using anhydrous sodium metasilicate as a geopolymer activator for soil stabilization10.1016/j.enggeo.2019.105316 ↗
19. Geopolymer additive manufacturing: a review
20. Effect of alkali reactions on the rheology of one-part 3D printable geopolymer concrete10.1016/j.cemconcomp.2020.103899 ↗
21. Effect of activator dosage and mass ratio of GGBFS to FA on 3D printing performance of kenaf geopolymer10.1617/s11527-024-02410-1 ↗
22. Role of temperature in 3D printed geopolymers: Evaluating rheology and buildability
23. In-line activation of geopolymer slurry for concrete 3D printing10.1016/j.cemconres.2022.107008 ↗
24. 3D printing of dense and porous alkali-activated refractory wastes via Direct Ink Writing (DIW)10.1016/j.jeurceramsoc.2021.01.019 ↗
25. Rheological Properties of Metakaolin-Based Geopolymers for Three-Dimensional Printing of Structures
26. Construction and demolition waste-based geopolymers suited for use in 3-dimensional additive manufacturing10.1016/j.cemconcomp.2021.104088 ↗
27. Effect of partial replacement of geopolymer binder materials on the fresh and mechanical properties: a review10.1016/j.ceramint.2021.02.127 ↗
28. Preparation of coal gangue-slag-fly ash geopolymer grouting materials10.1016/j.conbuildmat.2022.126997 ↗
29. Study on mechanical properties, freeze–thaw and chlorides penetration resistance of alkali activated granulated blast furnace slag-coal gangue concrete and its mechanism10.1016/j.conbuildmat.2022.130218 ↗
30. Preparation and microstructure of fly ash geopolymer paste backfill material10.1016/j.jclepro.2019.03.310 ↗
31. The effect of Na+ and H2O on structural and mechanical properties of coal gangue-based geopolymer: Molecular dynamics simulation and experimental study10.1016/j.conbuildmat.2020.121081 ↗
32. Green synthesis of high porosity waste gangue microsphere/geopolymer composite foams via hydrogen peroxide modification10.1016/j.jclepro.2019.04.185 ↗
33. Improving stabilization/solidification of MSWI fly ash with coal gangue based geopolymer via increasing active calcium content10.1016/j.scitotenv.2022.158594 ↗
34. Characteristics of eco-friendly ultra-high-performance geopolymer concrete incorporating waste materials10.1016/j.ceramint.2022.03.103 ↗
35. Systematical investigation of rheological performance regarding 3D printing process for alkali-activated materials: effect of precursor nature10.1016/j.cemconcomp.2022.104450 ↗
36. WFT-based assessment of the rheological characteristics, particle packing, and buildability of Pcc-FA-GGBFS composite materials for 3D printing
37. Synergistic effects of the use of metakaolin, sand and water on the properties of cementitious composites for 3D printing10.1016/j.conbuildmat.2022.130277 ↗
38. Layer-interface properties in 3D printed concrete: Dual hierarchical structure and micromechanical characterization10.1016/j.cemconres.2020.106220 ↗
39. A state of the art on effect of alkali activator, precursor, and fibers on properties of geopolymer composites
40. Nano-scale study on molecular structure, thermal stability, and mechanical properties of geopolymer10.1007/s43207-022-00276-z ↗
41. 3D printed geopolymer composites: A review
42. Tensile strength and durability performances-based evaluation of 3D-printed and mold-cast fibrous geopolymer composites produced at various alkaline activator combinations
43. 3D-printable alkali-activated concretes for building applications: A critical review10.1016/j.conbuildmat.2021.126126 ↗
44. Alkali-activated and geopolymer materials developed using innovative manufacturing techniques: A critical review10.1016/j.conbuildmat.2021.124483 ↗
45. 3D printable earth-based alkali activated “ink”: effect of alkali concentration and binder-to-aggregate ratio10.1016/j.jobe.2024.111208 ↗
46. Mechanical properties of alkali activated flyash/Kaolin based geopolymer concrete10.1016/j.conbuildmat.2015.08.009 ↗
47. Effects of combined usage of GGBS and fly ash on workability and mechanical properties of alkali activated geopolymer concrete with recycled aggregate10.1016/j.compositesb.2018.11.067 ↗
48. The evolution of interfacial transition zone in alkali-activated fly ash-slag concrete10.1016/j.cemconres.2019.105963 ↗
49. Mix design and mechanical properties of geopolymer and alkali activated concrete: Review of the state-of-the-art and the development of a new unified approach10.1016/j.conbuildmat.2020.119380 ↗
50. Review of the materials composition and performance evolution of green alkali-activated cementitious materials10.1007/s10098-023-02478-3 ↗
51. Strength formation mechanism and curing system optimization of low-carbon cementitious materials prepared by synergistic activation of multiple alkaline solid wastes10.1016/j.conbuildmat.2023.132931 ↗
52. Microstructure and mechanical properties of interlayer regions in extrusion-based 3D printed concrete: A critical review10.1016/j.cemconcomp.2023.105154 ↗
53. The effect of interlayer adhesion on stress distribution in 3D printed beam elements
54. Durability and pore structure of metakaolin-based 3D printed geopolymer concrete10.1016/j.conbuildmat.2024.135847 ↗
55. Interlayer adhesion strength of 3D-printed cement-based materials exposed to varying curing conditions
56. Evolution mechanism of permeability of hot dry rock under coupled effect of thermal fatigue and seawater interaction during coastal geothermal development10.1016/j.rser.2023.114061 ↗
57. Influence of print paths on mechanical properties and fracture propagation of 3D printed concrete10.1016/j.conbuildmat.2024.137019 ↗
58. Intricacies of various printing parameters on mechanical behaviour of additively constructed concrete10.1007/s43452-023-00853-x ↗
59. Acoustic emission response and rupture evolution analysis of triaxial compression damage of hot dry rock under seawater fatigue dissolution10.1007/s11771-025-6029-9 ↗
60. 3D-printed red mud/metakaolin-based geopolymers as water pollutant sorbents of methylene blue10.1016/j.jclepro.2022.135315 ↗
61. Slag-modified metakaolin-based 3D printed geopolymer: Mechanical characterisation, microstructural properties, and nitrogen physisorption pore analysis
62. Pore Structure Characteristics and Reaction Mechanism of Fly Ash Geopolymer10.1061/JMCEE7.MTENG-17624 ↗