Combining polymers and additives for sustainable asphalt binder performance
Source abstract
Abstract
The viscoelastic and thermoplastic nature of bituminous materials makes them highly sensitive to factors such as temperature changes, extreme and repeated loading, and UV radiation. To prevent this sensitivity from causing significant structural problems, bitumen must exhibit behavior characterized by desirable properties. The most common method to achieve this is through polymer modification. To date, a wide variety of polymers have been used for bitumen modification, and recent research has increasingly focused on using different polymers together. In this study, 611 elastomer, crumb rubber (CR), and melastol-crumb rubber (MCR) were used both individually and in combination as modifiers. Their physical, rheological, and mechanistic behaviors were thoroughly investigated. The findings indicate that binders modified with 611 and MCR exhibited superior rheological properties, including increased stiffness, elasticity, and resistance to permanent deformation when compared to those modified with SBS and CR. The best performance was obtained from the binder containing 3.5 % 611 additive. It improved the high temperature performance of the pure binders. The findings also highlight the sustainability potential of this approach, since the incorporation of recycled melastol crumb rubber (MCR) reduces waste and the required dosage of virgin elastomer, thereby supporting environmentally and economically sustainable pavement practices. Future research should emphasize field trials and long-term performance evaluations to validate these laboratory findings. • 611 elastomer + MCR enhance bitumen elasticity and high-temperature action. • M4 with 3.5 % 611 offers higher rutting resistance than SBS binders. • 611 elastomer + MCR improve low-temperature cracking resistance. • Modified binders show higher aging resistance than neat binder by FTIR. • 611 elastomer and CR alter binder surface morphology and bonding.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Asphalt Pavement Performance Evaluation · Polymer Nanocomposites and Properties · Enhanced Oil Recovery Techniques
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (67)
Show source-provided references
1. The use of waste tyre rubber in stone mastic asphalt mixtures: a critical review10.1016/j.conbuildmat.2024.135420 ↗
2. Photo-induced ageing processes in bitumen10.1016/j.conbuildmat.2024.137186 ↗
3. Nano-additives in asphalt binder: bridging the gap between traditional materials and modern requirements10.3390/app14103998 ↗
4. Environmental life-cycle impacts of bitumen: systematic review and new Canadian models10.1016/j.trd.2024.104439 ↗
5. Bitumen rheology and the impact of rejuvenators10.1016/j.conbuildmat.2019.06.177 ↗
6. Asphalt concrete mixtures modified with polymeric waste by the wet and dry processes: a literature review10.1016/j.conbuildmat.2021.125408 ↗
7. Applying feasibility analysis and catalytic purifying potential of novel modifying agent used in asphalt pavement materials10.1016/j.conbuildmat.2020.118467 ↗
8. Obtaining and modeling the relaxation modulus of self-healing asphalt mixtures10.5505/fujece.2022.43531 ↗
9. Determination of water sensitivity of nanosilica added hot mix asphalt10.5505/fujece.2022.77486 ↗
10. The performance of asphalt mixtures modified with lignin fiber and glass fiber: a review10.1016/j.conbuildmat.2019.03.126 ↗
11. Advancing asphalt binder performance through nanomaterial and polymer modification: experimental and statistical insights10.1016/j.rineng.2025.104458 ↗
12. Linear viscous approach to predict rut depth in asphalt mixtures10.1016/j.conbuildmat.2017.11.065 ↗
13. Utilisation of activation energy determined from viscosity to assess the rutting performance of asphalt binders containing various warm mix additives10.1016/j.conbuildmat.2025.142534 ↗
14. Experimental evaluation and 3D finite element simulation of creep behaviour of SBS modified asphalt mixture10.1016/j.conbuildmat.2024.139821 ↗
15. Laboratory investigation of the properties of asphalt modified with epoxy resin10.1002/app.30324 ↗
16. Fatigue cracking characteristics of asphalt pavement structure under aging and moisture damage10.3390/su15064815 ↗
17. Rheological investigation and optimization of crumb rubber-modified bitumen production conditions in the plant and laboratory
18. Effect of polymer modification on bitumen rheology: a comparative study of bitumens obtained from different sources
19. Enhancing asphalt performance and its long-term sustainability with nano calcium carbonate and nano hydrated lime10.3390/su16041507 ↗
20. Evaluation of asphalt performance for modification using aramid in different forms10.1016/j.conbuildmat.2025.142901 ↗
21. Modification mechanism of green polyurethane modified asphalt prepared by in-situ polymerization10.1016/j.conbuildmat.2024.138243 ↗
22. The effect of selenice natural bitumen on un-modified and polymer-modified bitumen rheological properties10.1016/j.conbuildmat.2025.142666 ↗
23. Comparative analysis of SBS polymers and their impact on the chemical composition of modified binders10.1016/j.mtcomm.2025.113719 ↗
24. The colloidal structure of bitumen: consequences on the rheology and on the mechanisms of bitumen modification10.1016/j.cis.2008.08.011 ↗
25. Repurposing waste plastics into cleaner asphalt pavement materials: a critical literature review10.1016/j.jclepro.2020.124355 ↗
26. A review of polymer-modified asphalt binder: modification mechanisms and mechanical properties
27. Polymer modification of bitumen: advances and challenges10.1016/j.eurpolymj.2014.02.005 ↗
28. Relation between polymer architecture and nonlinear viscoelastic behavior of modified asphalts10.1016/j.cocis.2006.09.001 ↗
29. Micro-structural and rheological characteristics of SBS-asphalt blends during their manufacturing10.1016/j.conbuildmat.2009.03.008 ↗
30. Analysis of styrene-butadiene-styrene polymer modified bitumen using fluorescent microscopy and conventional test methods10.1016/j.jhazmat.2007.04.122 ↗
31. Paving asphalt polymer blends relationship between composition, structure, and properties
32. Polymer modified asphalts as viscoelastic emulsions10.1122/1.550918 ↗
33. Asphaltenes in bitumen, what they are and what they are not10.1080/14680629.2009.9690234 ↗
34. Engineering properties of EVA-modified bitumen binder for paving mixes10.1061/(ASCE)0899-1561(1999)11:2(131) ↗
35. Morphology and image analysis of polymer modified bitumens10.1016/j.conbuildmat.2008.08.020 ↗
36. Thermomechanical properties of several polymer modified asphalts10.1515/arh-2000-0012 ↗
37. M. Stroup-Gardiner, D. Newcomb, Polymer Literature Review, Minnesota, 1995.
38. Testing and appraisal of polymer modified road bitumens—state of the art10.1007/BF02473221 ↗
39. Asphalt modified by styrene-butadiene-styrene triblock copolymer: morphology and model10.1061/(ASCE)0899-1561(2002)14:3(224) ↗
40. The research for high-performance SBR compound modified asphalt10.1016/j.conbuildmat.2009.10.003 ↗
41. Rheological properties of styrene-butadiene copolymer-reinforced asphalt10.1002/(SICI)1097-4628(19960829)61:9<1493::AID-APP9>3.0.CO;2-E ↗
42. Influence of the processing conditions on the rheological behaviour of polymer-modified bitumen✰10.1016/S0016-2361(03)00065-6 ↗
43. Thermodynamics, phase diagrams, and stability of bitumen−polymer blends10.1021/ef0202687 ↗
44. Rheological properties of styrene butadiene styrene polymer modified road bitumens⋆10.1016/S0016-2361(03)00146-7 ↗
45. Rheological properties, storage stability and morphology of CR/SBS composite modified asphalt by high-cured method10.1016/j.conbuildmat.2018.10.158 ↗
46. Stability of straight and polymer-modified asphalts
47. J. Zhu, Storage Stability and Phase Separation Behaviour of Polymer-Modified Bitumen: Characterization and Modelling, KTH Royal Institute of Technology, 2016.10.1080/10298436.2016.1211870 ↗
48. Modification of asphalt by block polymers of butadiene and styrene10.5254/1.3535936 ↗
49. Relationships between rheological properties, morphological characteristics, and composition of bitumen–styrene butadiene styrene copolymers mixes. I. A three-phase system10.1002/(SICI)1097-4628(19970822)65:8<1595::AID-APP16>3.0.CO;2-V ↗
50. Radiation and radical grafting compatibilization of polymers for improved bituminous binders—a review10.3390/ma17071642 ↗
51. PE-g-MA, PP-g-MA and SEBS-g-MA compatibilizers used in material blends10.1016/j.promfg.2017.09.083 ↗
52. Effect of various compatibilizers on the storage stability, thermochemical and rheological properties of recycled plastic-modified bitumen10.1007/s42947-023-00273-3 ↗
53. Towards green pavements with novel class of SBS polymers for enhanced effectiveness in bitumen and pavement performance
54. Effects of modified binders obtained from different polymers on conventional and rheological properties10.1016/j.conbuildmat.2022.129366 ↗
55. Softening point and penetration index of bitumen from parts of Southwestern Nigeria
56. A review on the mullins effect10.1016/j.eurpolymj.2008.11.017 ↗
57. Modification of multiple stress creep and recovery test procedure and usage in specification
58. Revision of the Superpave High Temperature Binder Specification: The Multiple Stress Creep Recovery Test (With Discussion), in
59. A new performance related test method for rutting prediction
60. Comparison by Fourier transform infrared (FTIR) spectroscopy of different ageing techniques: application to road bitumens10.1016/S0016-2361(00)00121-6 ↗
61. Biomass-derived bio-oil for asphalt binder applications: production feasibility and performance enhancement
62. Performance of asphalt binder blended with non-modified and polymer-modified nanoclay10.1016/j.conbuildmat.2012.02.056 ↗
63. Effect of nanoclay on physical and rheological properties of waste cooking oil–modified asphalt binder10.1061/(ASCE)MT.1943-5533.0003598 ↗
64. Characterization of asphalt binders modified with bio-binder from swine manure10.3390/app132011412 ↗
65. A comprehensive review on polyurethane modified asphalt: mechanism, characterization and prospect10.1016/j.jreng.2023.10.001 ↗
66. California Department of Transportation, 2022 Crumb Rubber Report, California, USA, 2022.
67. The use of rubber-polymer composites in bitumen modification for the disposal of rubber and polymer waste10.3390/polym16223177 ↗