journal article·2026-07Open access

Sustained-thermal-regulation composite PCMs using porous waste-derived support and epoxy encapsulation for enhanced thermal resilience of asphalt pavements

Linping Su, Xingchi Zhao, Junyao Hui, Yuepeng Jiao, Ming Liang, Xin Wang, Xue Xin, Zhanyong Yao

Abstract

Polyethylene glycol (PEG) has been widely recognized as a promising phase-change heat storage material for enhancing the high-temperature adaptability of asphalt pavements. However, PEG tends to leak during melting, which compromises pavement performance and long-term functionality. To address this issue, a dual strategy combining vacuum impregnation and epoxy encapsulation was developed to prepare composite phase-change materials (cPCMs) with high latent heat and anti-leakage properties. PEG was first adsorbed into porous carriers via vacuum impregnation and subsequently encapsulated with epoxy resin. Various carrier-supported cPCMs were incorporated into asphalt for comparative evaluation. The composites were characterized using differential scanning calorimetry (DSC), thermogravimetric analysis (TG), scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), and leakage tests, while the modified asphalts were evaluated by DSC, conventional tests, dynamic shear rheometer (DSR), and bending beam rheometer (BBR). Results showed that epoxy encapsulation significantly enhanced integrity and durability. Among all carriers, red-mud-based cPCM exhibited the highest latent heat of 135.54 J/g, zero leakage after 100 thermal cycles, and superior thermal stability with only 0.11% mass loss at 250 °C. The corresponding phase-change asphalt demonstrated excellent temperature-regulating capability and met pavement performance requirements under both high- and low-temperature conditions. Overall, this dual strategy effectively realizes long-term thermal regulation for asphalt pavements and promotes the sustainable reuse of solid waste materials such as red mud, offering a green and durable solution for smart, energy-responsive road systems.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Asphalt Pavement Performance Evaluation · Phase Change Materials Research · Polymer Nanocomposites and Properties

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (55)

Show source-provided references
1. Multiscale evaluation on temperature adjusting performance and road performance of asphalt mixture containing dual phase change materials10.1016/j.conbuildmat.2024.135302 ↗
2. A comprehensive review on the blending condition between virgin and RAP asphalt binders in hot recycled asphalt mixtures: Mechanisms, evaluation methods, and influencing factors10.1016/j.jclepro.2023.136515 ↗
3. Effect of montmorillonite modification on resistance to thermal oxidation aging of asphalt binder
4. Effect of high-temperature-resistant epoxy resin/polyethylene glycol 2000 composite stereotyped phase change material particles on asphalt properties10.1016/j.conbuildmat.2021.124007 ↗
5. Technology method and functional characteristics of road thermoelectric generator system based on Seebeck effect10.1016/j.apenergy.2022.120459 ↗
6. Phase change materials for pavement applications: A review10.1016/j.conbuildmat.2020.118553 ↗
7. Study on effect of various rejuvenators on virgin asphalt binders suffering various aging conditions and the unified evaluation index10.1016/j.conbuildmat.2023.132331 ↗
8. Study on the effect of different environmental factors on the aging gradient of asphalt binder based on field aging test10.1080/10298436.2023.2245950 ↗
9. Cooling optimization of asphalt pavement by topology optimization and cooling mechanism analysis10.1016/j.jclepro.2024.141726 ↗
10. Heat storage enhanced heat induction structure of asphalt pavement for reducing pavement temperature10.1016/j.applthermaleng.2024.124615 ↗
11. Study of Pavement Performance and Temperature Regulation Capacity of Asphalt Binders Modified with Dual-Phase-Change Materials10.3390/buildings13112702 ↗
12. Application of phase change material in asphalt mixture–A review10.1016/j.conbuildmat.2020.120219 ↗
13. Effect of lightweight aggregate gradation on latent heat storage capacity of asphalt mixture for cooling asphalt pavement10.1016/j.conbuildmat.2020.118849 ↗
14. Composite phase change materials coupled with radiative cooling for asphalt pavement thermal management10.1016/j.conbuildmat.2024.139476 ↗
15. Neuron-Inspired Flexible Phase Change Materials for Ambient Energy Harvesting and Respiration Monitoring10.1002/adma.202411820 ↗
16. Cross-linked polyurethane phase change materials based on multiple hydrogen bonds with excellent mechanical, flame retardant and energy storage properties for novel battery jackets10.1021/acssuschemeng.5c06079 ↗
17. Experimental Research and Molecular Dynamics Simulation of Composite Phase Change Materials Based on Functionalized Carbon Nanotubes/Epoxy Resin/n-Docosane10.1016/j.solmat.2025.114088 ↗
18. Thermal performance of nano-architected phase change energetic materials for a next-generation solar harvesting system10.1016/j.enconman.2025.119541 ↗
19. Polypyrrole and Ag Nanoparticles Synergistically Enhances the Photothermal Conversion Performance of Microencapsulated Phase Change Energy Storage Materials in Multiple Way10.1016/j.solmat.2025.113451 ↗
20. Effect of Carbonization Temperature on the Photo-Magnetic-Thermal Properties of Cobalt-Based Metal Organic Framework-Derived Composite Phase Change Materials: Experimental and Molecular Dynamics Simulation
21. Solid-Solid Phase Change Films with Intrinsic Flexibility and Photo-Thermal Conversion Capabilities for Human Thermal Management10.1016/j.solmat.2025.114158 ↗
22. Progress in application of phase-change materials to cooling clothing10.1016/j.est.2023.106606 ↗
23. Thermal performance of novel form-stable disodium hydrogen phosphate dodecahydrate-based composite phase change materials for building thermal energy storage10.1007/s42114-023-00655-y ↗
24. Assessing the feasibility of incorporating phase change material in hot mix asphalt10.1016/j.scs.2015.06.005 ↗
25. Investigating bitumen’s direct interaction with Tetradecane as potential phase change material for low temperature applications10.1080/14680629.2019.1601127 ↗
26. Preventing of rutting and crackings in the bituminous mixtures by monoethylene and diethylene glycol based synthetic polyboron compounds10.1016/j.conbuildmat.2013.09.039 ↗
27. A review of composite phase change materials based on biomass materials10.3390/polym14194089 ↗
28. Chemically crosslinked flexible polymer phase change material with self-healing, self-adaptive, and shape-memory properties for thermal interface applications
29. Highly thermal conductive phase change materials enabled by CNTs-modified PVA aerogel for solar energy storage and thermal management of electronic components10.1016/j.est.2024.111583 ↗
30. The use of lightweight aggregate saturated with PCM as a temperature stabilizing material for road surfaces10.1016/j.applthermaleng.2015.02.036 ↗
31. Effects of microencapsulated phase change materials on the performance of asphalt binders10.1016/j.renene.2018.08.062 ↗
32. Development and properties of n-octadecane/kaolinite composites as form-stabilized phase change materials for energy storage10.1016/j.jclepro.2023.137304 ↗
33. Study on preparation and properties of phase change modified asphalt for the functional pavement10.1016/j.conbuildmat.2024.137248 ↗
34. Phase change materials for pavement applications: A review10.1016/j.conbuildmat.2020.118553 ↗
35. A review of exfoliated graphite10.1007/s10853-015-9284-6 ↗
36. Shape-stabilized phase change materials based on fatty acid eutectics/expanded graphite composites for thermal storage10.1016/j.enbuild.2015.09.074 ↗
37. Variation of physico-chemical and textural properties of laboratory prepared red mud through acid and thermal activations. Advances in
38. Expanded vermiculite/D-mannitol as shape-stable phase change material for medium temperature heat storage10.3390/ma16186101 ↗
39. A novel method to improve anti-aging properties of SBS modified bitumen by zinc oxide/expanded vermiculite composite: Influence of zinc oxide particle loadings10.1016/j.conbuildmat.2023.133790 ↗
40. Heavy metal adsorption with zeolites: The role of hierarchical pore architecture10.1016/j.cej.2018.11.087 ↗
41. The modification of aluminium content of natural zeolites with different composition10.1016/j.powtec.2018.12.018 ↗
42. Effects of Polyethylene Glycol/Porous Silica Form-Stabilized Phase Change Materials on the Performance of Asphalt Binders
43. Thermal and Rheological Performance of Asphalt Binders Modified with Expanded Graphite/Polyethylene Glycol Composite Phase Change Material (EP-CPCM)
44. Laboratory Investigation of Phase Change Effect of Polyethylene Glycolon on Asphalt Binder and Mixture Performance10.1016/j.conbuildmat.2019.03.308 ↗
45. New Progress in the Research of Vermiculite Functionalization Application
46. Micro-and Mesoporous Structural Effects of Beta Zeolites for Volatile Organic Compound Sorption10.1021/acs.langmuir.4c01074 ↗
47. Preparation and characterization of red mud based porous materials
48. Effects of cold storage temperature on thermoreversible aging in heavily oxidized asphalt binders10.1016/j.conbuildmat.2023.131792 ↗
49. Tahami · 2020
50. Enhanced stability of curcumin and polyethylene glycol composites in the presence of flavonoids and whey protein concentrate: synthesis, structural evaluation and thermal analysis
51. Developing a solid–solid phase change heat storage asphalt pavement material and its application as functional filler for cooling asphalt pavement10.1016/j.enbuild.2023.112935 ↗
52. Ye · 2018
53. Effects of polyethylene glycol/porous silica form-stabilized phase change materials on the performance of asphalt binders10.3390/ma16155293 ↗
54. Evaluating the effect of hydrophobic nanosilica on the viscoelasticity property of asphalt and asphalt mixture10.3390/ma11112328 ↗
55. Study on the rheological properties and phase-change temperature regulation of asphalt modified by high/low-temperature phase change material particles10.1016/j.est.2022.105970 ↗