journal article·2026-07Open access

Hybrid dry mixing of plastic-modified asphalt mixtures under superpave criteria: Mix design and performance considerations

Waleed Zeiada, Kussai W. Alrini, Osama F.S. Abushaban, Ghazi Al-Khateeb, Fatma Abdulrahman, Helal Ezzat

Abstract

The incorporation of recycled plastics into asphalt mixtures has gained increasing interest as a means to enhance pavement performance while reducing environmental burdens associated with plastic waste. This study examines the use of recycled High-Density Polyethylene (HDPE) and Polyethylene Terephthalate (PET) in asphalt concrete (AC) mixtures produced following the Superpave volumetric mix design. A Hybrid Dry Mixing (HDM) procedure was applied to improve dispersion and prevent clumping, in which aggregates were pre-coated with asphalt binder before introducing finely ground HDPE and PET at dosages of 0.5%, 1.0%, and 1.5% by weight of aggregates. A multi-scale experimental program was conducted to evaluate the thermal, chemical, rheological, volumetric, and compactability responses of plastic-modified mixtures. The thermal and degradation behavior of HDPE and PET were characterized using Differential Scanning Calorimetry (DSC) and Thermogravimetric Analysis (TGA), while chemical features were assessed through Fourier Transform Infrared Spectroscopy (FTIR). Short-term-aged binders were extracted and recovered using a closed-system asphalt analyzer and rotary evaporator, enabling evaluation of rheological properties through Dynamic Shear Rheometer (DSR) and rotational viscosity (RV) testing. Superpave volumetric properties were determined across multiple asphalt contents, and compactability was quantified using gyratory compaction parameters, specifically the Compaction Energy Index (CEI) and densification slope (K id ). Results show that HDPE softens at mixing temperatures and partially interacts with the binder phase, influencing binder availability, mixture stiffness, and compaction resistance. PET remains solid during mixing and acts as a rigid particulate component, affecting internal structure, void distribution, and densification behavior. These mechanisms explain the observed variations in binder demand, volumetric compliance, and compaction trends across all dosages. The HDM procedure produced uniform mixtures without clumping and is compatible with typical plant operations, supporting its practical relevance for integrating recycled plastics into asphalt pavement construction. • HDM achieved uniform dispersion of HDPE and PET without clumping. • HDPE softened in the mix, while PET acted mostly as a filler. • HDPE stiffened with binder; PET Softened the binder. • Both plastics lowered Gmm and increased the required asphalt content. • All plastic mixtures met Superpave volumetric limits.
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Research context

OpenAlex topics: Asphalt Pavement Performance Evaluation · Microplastics and Plastic Pollution · Innovative concrete reinforcement materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (87)

Show source-provided references
1. Gourmelon · 2015 · 1
2. Moore · 2020
3. Degradation rates of plastics in the environment10.1021/acssuschemeng.9b06635 ↗
4. OECD · 2022
5. Our plastic age10.1098/rstb.2009.0054 ↗
6. Impacts of future climate change on flexible road pavement economics: a life cycle costs analysis of 24 case studies across the United States10.1016/j.scs.2022.103773 ↗
7. Polymer modified bitumen: review10.23939/chcht10.04si.631 ↗
8. Laboratory and field performance characterization of recycled-plastic-modified asphalt mixtures at the national center for asphalt technology test track10.1177/03611981251318331 ↗
9. Review of recycling waste plastics in asphalt paving materials
10. Incorporation of plastic waste into road pavements: a systematic literature review on the fatigue and rutting performances10.1016/j.conbuildmat.2023.133441 ↗
11. Repurposing waste plastics into cleaner asphalt pavement materials: a critical literature review10.1016/j.jclepro.2020.124355 ↗
12. E-Waste plastic powder modified bitumen: rheological properties and performance study of bituminous concrete10.1080/14680629.2019.1642944 ↗
13. Properties of modified asphalt binders blended with electronic waste powders10.1061/(ASCE)MT.1943-5533.0000504 ↗
14. Investigating the engineering properties of asphalt binder modified with waste plastic polymer10.1016/j.asej.2020.08.035 ↗
15. Role of pyrolysis wax on enhancing the performance of waste plastic modified asphalt prepared with the wet modification process10.1177/03611981251330898 ↗
16. Understanding the storage stability of polyethylene modified binders: a laboratory case study using waste plastics10.1061/JMCEE7.MTENG-17334 ↗
17. Using waste plastics as asphalt modifier: a review10.3390/ma15010110 ↗
18. Preparation and evaluation of waste PET derived polyurethane polymer modified bitumen through in situ polymerization reaction10.1016/j.conbuildmat.2017.09.147 ↗
19. Waste PET chemical processing to terephthalic amides and their effect on asphalt performance10.1021/acssuschemeng.0c00036 ↗
20. Evaluation of pyrolisis PET utilization in asphalt binder
21. Preparation of sustainable asphalt pavements using polyethylene terephthalate waste as a modifier
22. A study on using plastic coated aggregate for evaluation of modified bituminous concrete mix10.1088/1757-899X/955/1/012052 ↗
23. Incorporating waste plastic bottles as an additive in asphalt mixtures through a dry method10.2478/sjce-2024-0024 ↗
24. Enhanced dry process method for modified asphalt containing plastic waste10.3389/fmats.2021.700231 ↗
25. A review on the use of plastic waste as a modifier of asphalt mixtures for road constructions10.3390/civileng6020017 ↗
26. The use of plastic waste in asphalt: A critical review on asphalt mix design and Marshall properties10.1016/j.conbuildmat.2021.125185 ↗
27. US Department of Energy · 2019
28. Enhancement of permanent deformation resistance of modified asphalt concrete mixtures with nano-high density polyethylene10.1016/j.conbuildmat.2019.117604 ↗
29. Learning more about recycled plastics in asphalt pavements
30. Impact of high-density polyethylene recycled from waste milk bottles on asphalt binder’s performance under UAE’s climate conditions10.4028/p-Y6b1ZH ↗
31. Research on the development of a way to modify asphalt mixtures with PET recyclates10.3390/ma16186258 ↗
32. Fracture and mechanical properties of asphalt mixtures containing granular polyethylene terephthalate (PET)10.1016/j.conbuildmat.2020.120410 ↗
33. Evaluation of asphalt mixtures modified with low-density polyethylene and high-density polyethylene using experimental results and machine learning models10.1038/s41598-024-74657-1 ↗
34. Statistical analysis of low-density and high-density polyethylene modified asphalt mixes using the response surface method
35. Investigating the mechanical properties of asphalt concrete containing waste polyethylene terephthalate10.1080/14680629.2017.1395354 ↗
36. Performance evaluation of utilization of waste polyethylene terephthalate (PET) in stone mastic asphalt10.1016/j.conbuildmat.2012.06.015 ↗
37. Study on dynamic modulus of waste plastic modified asphalt mixture using waste plastic bag chips
38. Combined modification of asphalt with polyethylene packaging waste and organophilic montmorillonite10.1016/j.polymertesting.2011.11.008 ↗
39. Rheological evaluation of bitumen modified using antistripping additives synthesised from waste polyethylene terephthalate (PET)10.1080/10298436.2018.1519192 ↗
40. The use of polyethylene in hot asphalt mixtures10.3844/ajassp.2007.390.396 ↗
41. Enhancement of hot mix asphalt ( HMA) properties using waste polymers10.1007/s13369-019-03748-3 ↗
42. SGC tests for influence of material composition on compaction characteristic of asphalt mixtures
43. Compaction characteristics of cold recycled mixtures with asphalt emulsion and their influencing factors
44. AASHTO · 2017
45. ASTM · 2021
46. ASTM · 2021
47. ASTM · 2021
48. AASHTO · 2017
49. FHWA, FHWA-HRT-10-035 - LTPP Computed Parameter: Dynamic Modulus, 2015.
50. AASHTO · 2017
51. AASHTO · 2017 · Group 3
52. Standard Test Method for Flat Particles, Elongated Particles, or Flat and Elongated Particles in Coarse Aggregate
53. AASHTO, AASHTO T85, Standard Method of Test for Specific Gravity and Absorption of Coarse Aggregate, 2017.
54. AASHTO · 2017 · 3 · 1
55. AASHTO T11, Standard Method of Test for Materials Finer Than 75-um (No. 200) Sieve in Mineral Aggregates by Washing
56. AASHTO · 2017
57. Standard method of test for determining the rheological properties of asphalt binder using a dynamic shear rheometer (DSR)
58. Analysis of the properties of modified asphalt binder by FTIR method10.3390/ma15165743 ↗
59. AASHTO · 2015 · 3
60. Standard practice for superpave volumetric design for asphalt mixtures
61. Standard method of test for theoretical maximum specific gravity (Gmm) and density of hot mix asphalt (HMA)
62. Standard method of test for builk specific gravity (GmB) of compacted asphalt mixtures using saturated surface-dry specimens
63. Influence on compaction of cold recycled mixes with emulsions using the superpave gyratory compaction10.1061/(ASCE)MT.1943-5533.0000987 ↗
64. H.U. Bahia, A.F. Faheem, Using the Superpave Gyratory Compactor to Estimate Rutting Resistance of Hot-Mix Asphalt, E-C124: Practical Approaches to Hot-Mix Asphalt Mix Design and Production Quality Control Testing, 2007, pp. 45–61.
65. Estimating results of a proposed simple performance test for hot-mix asphalt from superpave gyratory compactor results10.1177/0361198105192900113 ↗
66. Investigation on the pavement performance of asphalt mixture based on predicted dynamic modulus10.1016/j.conbuildmat.2015.10.178 ↗
67. AASHTO · 2015
68. Prediction of phase angles from dynamic modulus data and implications for cracking performance evaluation10.1080/14680629.2017.1389086 ↗
69. Development of master curve models complying with linear viscoelastic theory for complex moduli of asphalt mixtures with improved accuracy10.1016/j.conbuildmat.2017.06.143 ↗
70. Mechanics of materials
71. The temperature dependence of relaxation mechanisms in amorphous polymers and other glass-forming liquids10.1021/ja01619a008 ↗
72. Comprehensive study on the performance of waste HDPE and LDPE modified asphalt binders for construction of asphalt pavements application10.3390/polym14173673 ↗
73. Polyethylene terephthalate (PET) recycling: a review10.1016/j.cscee.2024.100673 ↗
74. Thermal properties of high density polyethylene-kenaf cellulose composites
75. Chemical upcycling of waste PET into sustainable asphalt pavement containing recycled concrete aggregates: insight into moisture-induced damage10.1016/j.conbuildmat.2022.129632 ↗
76. ASTM D5/D5M: standard test method for penetration of bituminous materials
77. ASTM · 2014
78. ASTM D4402-06 standard test method for viscosity determination of asphalt at elevated temperatures using a rotational viscometer
79. Standard method of test for determining the flexural creep stiffness of asphalt binder using the bending beam rheometer (BBR)
80. AASHTO TP101, standard method of test for estimating fatigue resistance of asphalt binders using the linear amplitude sweep
81. Intermediate- and high-temperature damage of bitumen modified by HDPE from various sources10.1080/14680629.2023.2181017 ↗
82. The impact of HDPE plastic seeds on the performance of asphalt mixtures10.28991/cej-2021-03091744 ↗
83. Zinc oxide (ZnO), magnesium hydroxide [Mg(OH)2] and calcium carbonate (CaCO3) filled HDPE polymer composites: Mechanical, thermal and morphological properties
84. Assessment of binder modification in dry-added waste plastic modified asphalt10.3390/polym16141987 ↗
85. Evaluation of VMA and film thickness requirements in hot-mix asphalt10.5539/mas.v5n4p166 ↗
86. Effect of low VMA in hot mix asphalt on load-related cracking resistance10.1016/j.conbuildmat.2017.05.120 ↗
87. L.A. Cooley, B. Prowell, E.R. Brown, Implementation of Superpave mix design for airfield pavements, 2007.