journal article·2026-07Open access

Performance evaluation of cement mortars incorporating seawater and calcined marl as sustainable alternatives

Shekhar Saxena, Harald Justnes, Mohammad Hajmohammadian Baghban

Abstract

This study presents a cement mortar system that combines seawater and calcareous calcined marl to address freshwater scarcity and cement emissions. The marl used in this study is rich in calcium carbonate and has not been previously studied in combination with seawater for cementitious applications. Cement mortars with 0–40% marl replacement were tested for hydration, strength, durability, and microstructure. At 40% marl, seawater accelerated hydration with peak heat flow about 21% higher and the peak arriving 7% earlier than tap water. Compressive strength improved when marl was combined with seawater, reaching 64.7 MPa at 90 days compared with 60.2 MPa for the tap water mix. Seawater further improved transport related properties in the presence of calcined marl. At the 40% replacement level, bulk resistivity at 90 days was 134 Ω·m with seawater versus 96.5 Ω·m for tap water, while permeable voids decreased to 20.7% with seawater compared with 22.3% with tap water with marl. XRD and SEM-EDS confirmed Friedel’s salt, C-A-S-H and ettringite, supporting the improved performance of seawater cement mortars with marl. The results show that seawater and calcareous marl can work together to produce durable, low-carbon cement mortars while reducing freshwater demand.
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Research context

OpenAlex topics: Concrete and Cement Materials Research · Smart Materials for Construction · Microbial Applications in Construction Materials

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References (100+)

Show source-provided references
1. Where water wtress will be highest by 2050
2. Kuzma, S., L. Saccoccia, and M. Chertock, Countries, housing one-quarter of the population, face extremely high water stress. World Resources Institute.
3. Making the invisible visible
4. H. Perlman, 2019, . How much water is there on, in, and above the Earth? 2019; Available from: https://www.usgs.gov/water-science-school/science/how-much-water-there-earth.
5. Suitability of sea water for mixing structural concrete exposed to a marine environment10.1016/0958-9465(95)00015-5 ↗
6. Seawater concrete: a critical review and future prospects
7. An Experimental Investigation on Using Seawater in Sustainable Mortar Mixtures
8. Evaluating mechanical, microstructural and durability performance of seawater sea sand concrete modified with silica fume
9. A review on seawater sea-sand concrete: Mixture proportion, hydration, microstructure and properties10.1016/j.conbuildmat.2021.123602 ↗
10. Durability of cementitious materials in seawater environment: A review on chemical interactions, hardened-state properties and environmental factors10.1016/j.conbuildmat.2022.130224 ↗
11. The role of seawater in interaction of slag and silica fume with cement in low water-to-binder ratio pastes at the early age of hydration10.1016/j.conbuildmat.2018.07.091 ↗
12. Durability deterioration of concrete under marine environment from material to structure: A critical review
13. GCCA · 2022
14. Carbon emission of global construction sector10.1016/j.rser.2017.06.001 ↗
15. Effect of recycled turbine blade powder and fibres on mechanical and life cycle properties of mortar
16. Investigations on the mechanical and life cycle properties of novel marine-based sustainable BFRP composites10.1016/j.conbuildmat.2024.139105 ↗
17. Sustainable development and climate change initiatives10.1016/j.cemconres.2007.09.008 ↗
18. The influence of production parameters on pozzolanic reactivity of calcined clays
19. Performance comparison of cement replacing materials in concrete: Limestone fillers and supplementary cementing materials–A review10.1016/j.conbuildmat.2020.118866 ↗
20. Industrially interesting approaches to “low-CO2” cements10.1016/j.cemconres.2004.01.021 ↗
21. Improved mechanical properties of concrete mix at high temperatures based on the addition of kaolin, bentonite and glauconite10.1007/s41062-025-01952-9 ↗
22. The impact of mechanochemical activation on the physicochemical properties and pozzolanic reactivity of kaolinite, muscovite and montmorillonite10.1016/j.cemconres.2022.106962 ↗
23. Calcareous smectite clay as a pozzolanic alternative to kaolin10.1080/19648189.2019.1590741 ↗
24. The origin of the pozzolanic activity of calcined clay minerals: A comparison between kaolinite, illite and montmorillonite10.1016/j.cemconres.2010.09.013 ↗
25. Suitability of Selected Tanzanian Kaolinite Clays for Producing LC3 Binders
26. Influence of low-to medium-kaolinite clay on the durability of limestone calcined clay cement (LC3) concrete10.3390/ma16010374 ↗
27. Differences in hydration kinetics and phase development of Australian bentonite and kaolinite based limestone calcined clay cements10.1617/s11527-025-02743-5 ↗
28. Incorporating supplementary cementitious materials into ultra-high-performance seawater sea-sand concrete (UHPSSC): Hydration, microstructure, and mechanical performance10.1016/j.conbuildmat.2025.140824 ↗
29. Mechanical properties and chloride resistance of ultra-high-performance seawater sea-sand concrete with limestone and calcined clay cement (UHPSSC-LC3) under various curing conditions
30. Enhancing shrinkage and chloride resistance in seawater-mixed ultra-high-performance concrete through metakaolin incorporation
31. Incorporation of limestone calcined clay cement (LC3), seawater and sea-sand in ultra-high-performance engineered cementitious composites (UHPECC): Mechanical properties, hydration and microstructure
32. Experimental Study on the Mechanical Properties of Limestone Calcined Clay Cement (LC3) Seawater Sea-Sand Concr
33. Calcined clay limestone cements (LC3)10.1016/j.cemconres.2017.08.017 ↗
34. Effects of limestone calcined clay, fly ash and seawater on early hydrating behavior, mechanical properties, microscopic performance and sustainability of eco-friendly cement-based pastes10.1007/s10973-023-12823-9 ↗
35. Synergistic effect of calcined kaolin tailing-limestone and NaCl on the mechanical properties and microstructure of cement-based materials10.1016/j.jobe.2025.113971 ↗
36. Evaluating rotary and static calcination processes for montmorillonite marl: Pozzolanic properties, compressive strength, and cementitious paste characteristics10.1016/j.clay.2024.107501 ↗
37. Feasibility of calcined marl as an alternative pozzolanic material
38. The effect of calcite in the raw clay on the pozzolanic activity of calcined illite and smectite
39. Lahmar · 2025
40. Assessment of hydration, strength, and microstructure of three different grades of calcined marls derived from phosphate by-products
41. Calcined marl and clays as alternative materials for cement substitution
42. Marls as an ecological substitute for cement with lower energy consumption. Mortars Research
43. Properties of Portland cement pastes enriched with addition of calcined marl10.1016/j.jobe.2017.03.007 ↗
44. Behavior of concrete containing alternative pozzolan calcined marl blended cement
45. Durability of mortar with calcined marl as supplementary cementing material10.1680/adcr.13.00040 ↗
46. Comparison of plasticity index of Søvind marl found by use of Casagrande cup, fall cone apparatus and loss on ignition. Department of Civil Engineering
47. NS-EN 197-1 · 2011
48. Characterisation of calcined raw clays suitable as supplementary cementitious materials10.1016/j.clay.2018.06.030 ↗
49. Mackenzie, F.T., R.H. Byrne, and A.C. Duxbury. seawater. Encyclopedia Britannica. Accessed 18 November 2025; Available from: 〈https://www.britannica.com/science/seawater〉.
50. ASTM D1141 · 2021
51. NS-EN 12620 · 2016
52. NS-EN 933-1 · 2012
53. NS-EN 934-2 · 2012
54. Baseline studies of the clay minerals society source clays: infrared methods10.1346/CCMN.2001.0490508 ↗
55. NS-EN 196-11 · 2019
56. NS-EN 196-1 · 2016
57. ASTM C642 · 2021
58. ASTM C1876 · 2025
59. RCON User Manual · 2023
60. The role of concrete maturity in resistivity-based performance specifications
61. ASTM C1723 · 2025
62. Winter · 2012
63. The influence of the filler effect on the sulfate requirement of blended cements10.1016/j.cemconres.2019.105918 ↗
64. Synergistic effects of supplementary cementitious materials in limestone and calcined clay-replaced slag cement10.1016/j.conbuildmat.2021.122648 ↗
65. Influence of cement, aggregates and chlorides on zeta potential of cement-based materials10.1680/adcr.11.00031 ↗
66. Electrokinetic properties and mechanism of chloride binding in 42-month cured cement pastes with fly ash and ground granulated blast furnace slag exposed to seawater10.1016/j.conbuildmat.2019.117944 ↗
67. Determination of free chloride in seawater cement paste with low water-binder ratio10.1016/j.cemconcomp.2021.104217 ↗
68. Investigation on early-age hydration, mechanical properties and microstructure of seawater sea sand cement mortar10.1016/j.conbuildmat.2020.118776 ↗
69. Dissolution theory applied to the induction period in alite hydration10.1016/j.cemconres.2010.01.012 ↗
70. Modelling early age hydration kinetics of alite10.1016/j.cemconres.2012.03.003 ↗
71. Study on the effect of chloride ion on the early age hydration process of concrete by a non-contact monitoring method10.1016/j.conbuildmat.2018.03.206 ↗
72. Impact of admixtures on the hydration kinetics of Portland cement10.1016/j.cemconres.2011.03.005 ↗
73. Seawater-mixed alkali-activated materials: A state-of-the-art review10.1007/s10853-025-10605-2 ↗
74. Mimicking the cementation mechanism of ancient Roman seawater concrete using calcined clays10.1016/j.clay.2022.106696 ↗
75. Microstructure, hydration, and chloride binding behavior of limestone calcined clay cement prepared using seawater10.1061/JMCEE7.MTENG-15838 ↗
76. A review of recent advances in the science and technology of seawater-mixed concrete10.1016/j.cemconres.2021.106666 ↗
77. Assessment of Cement Paste Properties Using Seawater: Early-Age Behavior, Mechanical and Microstructural Analysis10.1016/j.clwas.2025.100407 ↗
78. Suitability of seawater for mixing and curing of cementitious materials: a step towards sustainability
79. Influence of accelerator type and dosage on the durability of wet-mixed sprayed concrete against external sulfate attack10.1016/j.conbuildmat.2019.117883 ↗
80. Coal fly ash activation—Comparison of isothermal calorimetric data and mortar strength10.1016/j.tca.2017.12.002 ↗
81. Combined effect of metakaolin and sea water on performance and microstructures of concrete10.1016/j.conbuildmat.2014.10.023 ↗
82. Assessment of the durability and environmental impact of seawater-activated portlandite-calcined clay binder
83. ASTM C618 · 2025
84. Effects of w/b ratio, fly ash, limestone calcined clay, seawater and sea-sand on workability, mechanical properties, drying shrinkage behavior and micro-structural characteristics of concrete10.1016/j.conbuildmat.2022.126333 ↗
85. Effect of seawater for mixing and curing on structural concrete10.1080/19373260.2010.521048 ↗
86. Effect of maintenance environment on the mechanical property and pore structure of cement paste mixed by seawater10.1016/j.conbuildmat.2024.135280 ↗
87. Engineering properties of limestone calcined clay concrete10.3151/jact.16.343 ↗
88. Valorization of pozzolanicity of Algerian clay: optimization of the heat treatment and mechanical characteristics of the involved cement mortars10.1016/j.clay.2016.08.027 ↗
89. The effect of heat-curing on transport properties of low-calcium fly ash-based geopolymer concrete10.1016/j.conbuildmat.2016.02.210 ↗
90. Correlation between the compressive strength and ultrasonic pulse velocity of cement mortars blended with silica fume: An analysis of microstructure and hydration kinetics10.3390/ma14102476 ↗
91. Evaluation of relationship between water absorption and durability of concrete materials
92. Hydration, pore solution, and porosity of cementitious pastes made with seawater10.1061/(ASCE)MT.1943-5533.0002818 ↗
93. 4-year monitoring of degradation mechanisms of seawater sea-sand concrete exposed to tidal conditions: development of chemical composition and micro-performance10.1016/j.conbuildmat.2023.133475 ↗
94. The mechanical, transport and chloride binding characteristics of ultra-high-performance concrete utilising seawater, sea sand and SCMs10.1016/j.conbuildmat.2023.130815 ↗
95. Electrical resistivity of unsaturated concrete using different types of cement10.1016/j.conbuildmat.2015.12.168 ↗
96. Electrical resistivity as a durability parameter for concrete design: Experimental data versus estimation by mathematical model10.1016/j.conbuildmat.2018.10.145 ↗
97. The resistivity of mortars immersed in sea-water10.1016/0008-8846(86)90089-X ↗
98. Development of admixtures on seawater sea sand concrete: A critical review on Concrete hardening, chloride ion penetration and steel corrosion10.1016/j.conbuildmat.2023.134219 ↗
99. AASHTO TP 119 · 2022
100. ASTM C1202 · 2025